Mixed-linker approach in designing porous zirconium-based metal–organic frameworks with high hydrogen storage capacity

Description

Yes / Three highly porous Zr(IV)-based metal–organic frameworks, UBMOF-8, UBMOF-9, and UBMOF-31, were synthesized by using 2,2′-diamino-4,4′-stilbenedicarboxylic acid, 4,4′-stilbenedicarboxylic acid, and combination of both linkers, respectively. The mixed-linker UBMOF-31 showed excellent hydrogen uptake of 4.9 wt% and high selectivity for adsorption of CO2 over N2 with high thermal stability and moderate water stability with permanent porosity and surface area of 2552 m2 g−1. / University of Bath; Royal Society of Chemistry; Engineering and Physical Sciences Research Council

Links & Downloads

1. Naeem A, Ting VP, Hintermair U, Tian M, Telford R, Halim S, Nowell H, Holynska M, Teat SJ, Scowen IJ and Nayak S (2016) Mixed-linker approach in designing porous zirconium-based metal – organic frameworks with high hydrogen storage capacity. Chemical Communications. 52(50): 7826-7829.
2. http://hdl.handle.net/10454/8493
3. https://doi.org/10.1039/c6cc03787a

Tags

Mixed-linker

Hydrogen

Additional Fields

Identifer	oai:union.ndltd.org:BRADFORD/oai:bradscholars.brad.ac.uk:10454/8493
Date	17 May 2016
Creators	Naeem, Ayesha, Ting, V.P., Hintermair, U., Tian, M., Telford, Richard, Halim, Saaiba, Nowell, H., Holynska, M., Teat, S.J., Scowen, Ian J., Nayak, Sanjit
Source Sets	Bradford Scholars
Language	English
Detected Language	English
Type	Article, Published version
Rights	© 2016 The Royal Society of Chemistry. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.