A key engineering challenge is a transition to cleaner sustainable energy supply that is derived from renewable resources. Furthermore, affordable access to this modern sustainable energy services for communities in particular poor rural and urban communities is crucial. Microbial fuel cell (MFCs) is an emerging renewable alternative technology with potential to be self-sustaining that could alleviate the energy crisis and reduce environmental pollution. The use of the MFC as a dual system for electricity generation and wastewater treatment is been well reported in literature.
Manganese dioxide (MnO2) is an effective electro-catalyst that have been used for alkaline fuel cells and battery application. MnO2 have a high conductivity and high structural porosity for ion and gas transport. In addition, MnO2 have a favourable crystal morphology, which makes it particularly useful for improving oxygen reduction reaction in the fuel cell. Graphene (GO) will be loaded on MnO2 surface as an effective support material. GO is a material good for electrical conductivity and their mechanical strength is applicable in electro-catalytic activities and is cost effective.
In this work, a constructed dual chamber MFC configuration with graphite rod electrodes, MnO2-GO electrocatalyst and proton exchange membrane (PEM) using municipal sewage wastewater to generate electricity. The MnO2 as an alternative electro catalyst used for oxygen reduction reaction (ORR) in the MFC while using reduced graphene (rGO) as a support to enhance electrode surface area. Also addressing the effect of graphene material loading on MnOx catalyst for electrochemistry. The characterization of the MnO2-GO electrocatalyst have been analysed using X-Ray diffraction (XRD), Brunau-Emmett-Teller (BET) surface area and Fourier transform infrared spectroscopy (FTIR) for structural properties. Electrochemical techniques such as cyclic voltammetry (CV) for MnO2-GO electrocatalyst. Thermal gravimetric analysis (TGA) for the thermal properties, and the morphological properties probed by Scanning Electron Microscopy (SEM).
The dual chamber MFC design functioned successfully and tested for energy generation from municipality sewage wastewater. The maximum voltage of 586 mV reached during MFC operation with various sewage municipal wastewater COD of 100-300mg/L. The maximum power density of 248 mW/m2 with resistance of 16.98 Ω and highest current density of 1.72mA/m2 was observed at the first cycle as compare to other cycle. The lowest value of 0.002159 mA/m2 obtained at the end of 10 days. The content of municipality sewage wastewater is capable of generating electricity.
The physico-chemical properties of α-MnO2 exhibits excellent cycling stability on the electrochemical. This excellent cycling stability of α-MnO2 as a super capacitor electrode material. In addition, the graphene material loading on α-MnO2 has improved the electro catalytic activity, which influences the kinetics of the reduction reaction. The α-MnO2 synthesized BET analysis specific surface area of 134.61m2 g-1 reported. MFC technology has the potential to finds its own niche in the energy industry as it is becoming more and more sustainable due to the lower cost of electro catalyst materials. Power densities of 248 mW/m2 using wastewater with COD of 291mg/l were much higher than those previously obtained using low strength wastewater. These results have opened doors for further investigation of improving electro catalysis, utilized high concentration wastewater with high COD and improved MFC design including electrode materials. / Civil and Chemical Engineering / M. Tech. (Chemical Engineering)
| Identifer | oai:union.ndltd.org:netd.ac.za/oai:union.ndltd.org:unisa/oai:uir.unisa.ac.za:10500/24742 |
| Date | 10 1900 |
| Creators | Ledwaba, Kabelo Mike |
| Contributors | Patel, Bilal, Mokrani, Touhami |
| Source Sets | South African National ETD Portal |
| Language | English |
| Detected Language | English |
| Type | Dissertation |
| Format | 1 online resource (xvi, 79 leaves) : illustrations (some color), graphs (some color) |
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