The F19 NMR spectrum of SF4 at - 101° C has been
assigned as an A2B2 type spectrum, rather than A2X2 as previously
reported. Sulphur and boron isotope effects on F19 NMR spectra
have been observed for the first time and a new silicon isotope
effect has been measured. An expression has been derived for the shape of the
spectrum of a nucleus of spin I = 1/2 spin-spin coupled to a
nucleus of spin I = 3/2 which is undergoing quadrupole relaxation.
The derived expression is used to interpret the F19 spectra of
BF3 and Cl03F over a wide temperature range. A new compound, IOF5, has been prepared, and identified by means of its F19 NMR spectrum. / Thesis / Doctor of Philosophy (PhD)
| Identifer | oai:union.ndltd.org:mcmaster.ca/oai:macsphere.mcmaster.ca:11375/19943 |
| Date | 08 1900 |
| Creators | Quail, John |
| Contributors | Gillespie, R. J., Chemistry |
| Source Sets | McMaster University |
| Language | English |
| Detected Language | English |
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