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Structure and Properties of Twin Boundaries in Ni-Mn-Ga Alloys

Ni-Mn-Ga alloys close to the stoichiometric composition Ni2MnGa belong to the quite new family of ferromagnetic shape memory alloys. These alloys are characterized by the magnetic field induced strain (MFIS) based on the comparably easy motion of twin boundaries under a magnetic field. They are mostly chosen as a potential candidate for practical application especially promising for actuators and sensors because they are showing the largest MFIS so far. Depending on the chemical composition and heat treatment, at least three martensitic structures can be distinguished in the Ni-Mn-Ga system. However, the effect mentioned above only exists in two modulated structures. Since for the intended application of MFIS in technology polycrystalline materials seem to be more appropriate in contrast to single crystals, the specific polycrystalline aspects are considered. Factors important for decreasing the twinning stress and increasing the twinning strain of polycrystalline Ni-Mn-Ga alloys are texturing, adjusting the structure by annealing and training by thermomechanical treatments.
To achieve pronounced MFIS in polycrystals, fabrication processes are needed to produce specific strong textures. The material texturing has been obtained by directional solidification and plastic deformation by hot rolling and hot extrusion as well as high pressure torsion (HPT). To examine the texture of coarse-grained Ni-Mn-Ga alloys (due to a solidification process or dynamic recrystallization), diffraction of synchrotron radiation and neutrons was applied. The texture results show that the texture of Ni-Mn-Ga subjected to directional solidification, hot rolling and hot extrusion is a fibre or weak biaxial texture. However, local synchrotron measurements reveal that the global fibre texture of the hot extruded sample is a ”cyclic” fibre texture, i.e. it is composed of components related to the radial direction rotating around the extrusion axis. This allows finding regions with a strong texture component. The texture after HPT is characterized by a strong cube with the cube favourably oriented.
The initial microstructure of the Ni-Mn-Ga alloys is a typical self-accommodated microstructure of martensite. High resolution EBSD mappings show macro, micro twins and two types of microstructure. The twin plane is determined to be {110). In a typical martensitic transformation the high-temperature phase has a higher crystallographic symmetry than the low-temperature phase. Consequently, austenite may transform to several martensitic variants, the number of which depends on the change of symmetry during transformation. Generally, in a cubic-to-tetragonal transformation (5M case) three variants can form with the c-axis oriented close to the three main cubic axes of austenite. However, close examination of the high resolution EBSD mapping reveals that more than just three orientations, as expected from the Bain model, exist in Ni50Mn29Ga21. Each of three Bain variants may be split in some twin relations in different regions of the sample which differ from each other by about few degrees creating a much higher number of variants.
The training process, as the last step in the preparation procedure of Ni-Mn-Ga alloys, consists of multi-axis compression finally leading to a single-variant state. Compression of polycrystalline samples leads to motion of those twin boundaries changing the volume fraction of particular martensitic variants in such a way that the shortest axis (c-axis) becomes preferentially aligned parallel to the compression axis. It allows reducing the twinning stress and maximizing the twinning strain. To understand the training process in more detail, the interaction of the twin variants with the neighbourhood of parent austenite grains was investigated.

Identiferoai:union.ndltd.org:DRESDEN/oai:qucosa.de:bsz:14-qucosa-70998
Date19 July 2011
CreatorsChulist, Robert
ContributorsTechnische Universität Dresden, Fakultät Mathematik und Naturwissenschaften, Prof. Dr. Werner Skrotzki, Prof. Dr. Werner Skrotzki, Prof. Dr. Heinz-Günter Brokmeier
PublisherSaechsische Landesbibliothek- Staats- und Universitaetsbibliothek Dresden
Source SetsHochschulschriftenserver (HSSS) der SLUB Dresden
LanguageEnglish
Detected LanguageEnglish
Typedoc-type:doctoralThesis
Formatapplication/pdf

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