Vibrofluidized microreactor systems have been developed for studies of unsteady-state Fischer-Tropsch synthesis. This development is aimed at preventing carbon deposition on a fused-iron catalyst in a novel reactor called the “heat-tray.” This reactor involves a supernatant gas flowing over a shallow fluidized bed of catalyst particles. Three systems were built: (1) a vibrofluidized-bed microreactor system for obtaining baseline carbon deposition infonnation under industrially important reaction conditions; (2) a sliding-plug vibrofluidized-bed microreactor system for rapid switching of feed gases in the F-T synthesis; and (3) a cold-flow microreactor model for studying the gas mixing characteristics of the sliding-plug vibrofluidized-bed microreactor.
The results show that catalyst defluidization occurred under steady-state synthesis conditions below 395°C using a feed gas of H₂/CO ratio of 2:1 or less. Above 395°C, the probability of hydrocarbon chain growth (α) on the fused-iron catalyst was low enough (α < 0.50) to prevent accumulation of high-molecular-weight species that cause defluidization. Carbon deposition was rapid above 395°C when a feed gas of H₂/CO ratio of 2:1 or less was used.
Spent catalyst fractions in the form of free-flowing catalyst and "bugdust" were quantitatively analyzed for carbon and iron. Mössbauer spectroscopic analysis of free-flowing catalyst showed mainly Hägg carbide (x-Fe₅C₂) and magnetite (Fe₃O₄) with a smaller fraction present as α-Fe. Scanning electron microscopic analysis of the bugdust revealed a mass of highly porous, fine particles with a high carbon content (18-30 wt%).
Cold-flow microreactor model studies show that rapid (on the order of seconds), quantitative switching of feed gases over a vibrofluidized-bed of catalyst could be achieved. Vibrofluidization of the catalyst bed induced little backmixing of feed gas over the investigated flow-rate range of 417 to 1650 actual mm³/s. Further, cold-flow microreactor model studies showed intense solid mixing when a -150+300 µ bed of fused-iron catalyst was vibrofluidized at 24 cycles per second with a peak-to-peak amplitude of 4 mm.
The development of this microreactor system has provided an easy way of accurately determining integral fluid-bed kinetics in a laboratory reactor. Further, the unique ability of the microreactor system to rapidly switch feed gases over an intensely-mixed solid has important applications in chemical kinetics and reaction engineering. / Ph. D.
| Identifer | oai:union.ndltd.org:VTETD/oai:vtechworks.lib.vt.edu:10919/76086 |
| Date | January 1985 |
| Creators | Whiting, Gary Ken |
| Contributors | Chemical Engineering, Beyer, Gerhard H., Davis, Mark E., Konrad, Kenneth, Squires, Arthur M., Liu, Y.A. |
| Publisher | Virginia Polytechnic Institute and State University |
| Source Sets | Virginia Tech Theses and Dissertation |
| Language | en_US |
| Detected Language | English |
| Type | Dissertation, Text |
| Format | xxviii, 434 leaves, application/pdf, application/pdf |
| Rights | In Copyright, http://rightsstatements.org/vocab/InC/1.0/ |
| Relation | OCLC# 12442608 |
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