La doped HoMn2O5 in studying the influence of the local structure distortion on the magnetic transition has been investigated systematically. It is found that by doping of La ions in a proper percentage, 0.1≤x≤0.2, the formation of the possible impurity RMnO3 (113) phase could be suppressed; single phases of LaxHo1-xMn2O5 (0.1≤x≤0.2) can be formed in one atmosphere of flowing oxygen. For x=0.2, an weak ferromagnetic transition on top of the paramagnetic background appears at 150K and saturated at 75K, which implies that the compound undergoes a ferromagnetic to antiferromagnetic transition. In addition, the lattice didn¡¦t appear a huge phase transition at low temperature, it¡¦s observed local distortion behavior within 100~150K, and back to normal structure as high temperature ones. It¡¦s convinced that will be associated with the magnetic properties, which need further examination and experiment.
| Identifer | oai:union.ndltd.org:NSYSU/oai:NSYSU:etd-0213109-112553 |
| Date | 13 February 2009 |
| Creators | Yu, Chun-cheng |
| Contributors | Shih-Jye Sun, Hsiung Chou, Hung-Duen Yang |
| Publisher | NSYSU |
| Source Sets | NSYSU Electronic Thesis and Dissertation Archive |
| Language | Cholon |
| Detected Language | English |
| Type | text |
| Format | application/pdf |
| Source | http://etd.lib.nsysu.edu.tw/ETD-db/ETD-search/view_etd?URN=etd-0213109-112553 |
| Rights | withheld, Copyright information available at source archive |
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