Waveguide architectures were inscribed within two different stimuli-responsive hydrogels capable of actuation. An electroactive hydrogel, which deforms when placed within an electric field, is demonstrated as a method for remote actuation and steering of light outputs. Lattices of waveguide with diameters on the microscale were embedded within hydrogel prisms, achieved through a nonlinear light propagation process known as self-trapping. This process is a result of balance between the natural divergence of light and self-focusing effects caused by an irreversible positive refractive index change during photopolymerization. Waveguiding structures are inscribed in the material because of this process. Square (2D) and near-cubic (3D) lattices were inscribed in hydrogel prisms, demonstrating the ability to remotely steer one or two light outputs simultaneously using an electric field. The overall optical effect is reminiscent of camouflaging techniques observed in marine creatures (ie. cephalopods).
Additionally, a novel volumetric 3D printing technique previously demonstrated by the Saravanamuttu group was implemented to fabricate hydrogel cylinders capable of photothermal actuation. Coupling a thermoresponsive hydrogel material with a photoabsorber, areas irradiated by a light source are observed to contract. These contractions lead to the deflection of waveguiding cylinders towards the light source, reminiscent of the phototropic behaviours observed in particular plants (ie. sunflowers). The results of these studies provide insight for the fabrication of functional materials through nonlinear light propagation. Understanding these systems could provide knowledge for the fabrication of other stimuli-responsive materials with light-guiding properties. / Thesis / Master of Science (MSc)
| Identifer | oai:union.ndltd.org:mcmaster.ca/oai:macsphere.mcmaster.ca:11375/29421 |
| Date | January 2024 |
| Creators | Vaughan, Kevin |
| Contributors | Saravanamuttu, Kalaichelvi, Chemistry |
| Source Sets | McMaster University |
| Language | English |
| Detected Language | English |
| Type | Thesis |
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