1. Strontium does not easily react with n-butyl bromide in ether or benzene to produce an organostrontium compound. Strontium amalgam reacts to give a trace of the butyl mercury compound, perhaps through the formation of an organostrontium compound as intermediate.
2. The conversion, 2BuLi + SrCl₂ = 2LiCl + Bu₂Sr, seems to proceed predominantly to the left, perhaps because of relative solubilities of the lithium and strontium halides in the solvents used.
3. The conversion, Bu₂Hg + Sr = Hg + Bu₂Sr, appears to proceed to a slight extent to the right. So far, this reaction seems to offer the most promise in synthesizing an organostrontium compound. / M.S.
| Identifer | oai:union.ndltd.org:VTETD/oai:vtechworks.lib.vt.edu:10919/110220 |
| Date | January 1940 |
| Creators | Kuck, John F. R. |
| Contributors | Chemistry |
| Publisher | Virginia Agricultural and Mechanical College and Polytechnic Institute |
| Source Sets | Virginia Tech Theses and Dissertation |
| Language | English |
| Detected Language | English |
| Type | Thesis, Text |
| Format | 5 unnumbered pages, 19 pages, 2 unnumbered leaves, application/pdf, application/pdf |
| Rights | In Copyright, http://rightsstatements.org/vocab/InC/1.0/ |
| Relation | OCLC# 30053413 |
Page generated in 0.0015 seconds