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Gram quantities of silver and alloy nanoparticles: synthesis through digestive ripening and the solvated metal atom dispersion (SMAD) method: antimicrobial properties, superlatteic[i.e. super lattice] selfassembly, and optical properties

Doctor of Philosophy / Department of Chemistry / Kenneth J. Klabunde / This is an account of the synthesis of several drastically different forms of silver
nanoparticles: Bare metal nanoparticles, dry nanoparticulate powders, aqueous soluble particles, and organic ligand coated monodisperse silver nanoparticles were all produced. The synthetic method was adapted from previous studies on gold nanoparticles and investigated to understand the optimal conditions for silver nanoparticle synthesis. Also the procedure for refinement of the nanoparticles was studied and applied to the formation of alloy nanoparticles. This extraordinary procedure produces beautifully colored colloids of spherical metal nanoparticles of the highest quality which under suitable conditions self-assemble into extensive three dimensional
superlattice structures. The silver nanoparticle products were later tested against several biological pathogens to find dramatic increases in antimicrobial potency in comparison to commercially available silver preparations.

  1. http://hdl.handle.net/2097/160
Identiferoai:union.ndltd.org:KSU/oai:krex.k-state.edu:2097/160
Date January 1900
CreatorsSmetana, Alexander B.
PublisherKansas State University
Source SetsK-State Research Exchange
Languageen_US
Detected LanguageEnglish
TypeDissertation
Format31229681 bytes, application/pdf

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