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A surface force apparatus study of the mercury/water interface with and without self-assembled monolayers

The surface force apparatus (SFA) has been an important technique for making direct force measurements and has contributed enormously to our understanding of colloidal interactions. The conventional SFA has been limited to measuring forces between solid surfaces, until recently when a modified SFA was developed at the Ian Wark Research Institute [1]. A fluid drop (mercury) is introduced into the apparatus which allows a range of deformable surfaces to be studied in the SFA. This project is an extension of this technique. Interactions between a mica sheet and a mercury drop are studied, including the modification of mercury with self-assembled monolayers (SAMs) of thiol surfactants, and the drop deformation due to non-equilibrium adsorption effects and hydrodynamic forces.

Identiferoai:union.ndltd.org:ADTP/201908
Date January 2005
CreatorsClasohm, Lucy Y
Source SetsAustraliasian Digital Theses Program
LanguageEN-AUS
Detected LanguageEnglish
RightsCopyright Lucy Y Clasohm 2005

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