Thesis (M. Tech. Engineering: Electrical--Vaal University of Technology) / The air-breathing Direct Methanol Fuel Cell (DMFC) and Zinc Air Fuel Cell (ZAFC)were experimentally studied in a climate chamber in order to investigate the impact of
climatic environmental parameters such as varying temperature and relative humidity
conditions on their performance. The experimental results presented in the form of
polarization curves and discharge characteristic curves indicated that these parameters have a significant effect on the performance of these fuel cells. The results showed that temperature levels below 0ºc are not suitable for the operation of these fuel cells.
Instead, it was found that air-breathing DMFC is favored by high temperature conditions
while both positive and negative effects were noticed for the air-breathing ZAFC. The
results of the varying humidity conditions showed a negative impact on the air-breathing
DMFC at a lower temperature level but a performance increase was noticed at a higher
temperature level. For air-breathing ZAFC, the effect of humidity on the performance
was also found to be influence by the operating temperature.
Furthermore, common atmospheric air pollutants such as N20, S02, CO and N02 were
experimentally investigated on the air-breathing DMFC and ZAFC. At the concentration
of 20 ppm, these air contaminants showed to have a negative effect on the performance of
both air-breathing DMFC and ZAFC. For both air-breathing DMFC and ZAFC, performance degradations were found to be irreversible. It is therefore evident from this research that the performance of the air-breathing fuel cell will be affected in an
application situated in a highly air-polluted area such as Vaal Triangle or Southern
Durban. It is recommended the air-breathing fuel cell design include air filters to counter the day-to-day variations in concentration of air pollutants.
| Identifer | oai:union.ndltd.org:netd.ac.za/oai:union.ndltd.org:vut/oai:digiresearch.vut.ac.za:10352/142 |
| Date | 04 1900 |
| Creators | Sibiya, Petros Mandla |
| Contributors | Pienaar, H. C. v Z |
| Source Sets | South African National ETD Portal |
| Language | English |
| Detected Language | English |
| Type | Thesis |
| Format | xv, 103 leaves |
| Relation | Pdf. Adobe Acrobat |
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