<p>Since their discovery by Burg and Schlesinger in 1937, amine-boranes have enjoyed a rich preparative history and have experienced reinvigorated interest as valuable reagents for organic syntheses. Previously, the Herbert C. Brown Center for Borane Research has reported their synthesis from NaBH<sub>4</sub> and amines via the intermediacy of (NH<sub>4</sub>)<sub>2</sub>SO4 or NaHCO<sub>3</sub>. Described herein is a CO<sub>2</sub>-mediated amine-borane synthesis that accommodates all classes of amines, particularly long-chain trialkyl- and pyridine-like heteroarylamines.</p>
| Identifer | oai:union.ndltd.org:purdue.edu/oai:figshare.com:article/12374933 |
| Date | 15 June 2020 |
| Creators | Daniel O'Neal Reddy (8893829) |
| Source Sets | Purdue University |
| Detected Language | English |
| Type | Text, Thesis |
| Rights | CC BY 4.0 |
| Relation | https://figshare.com/articles/Carbon_Dioxide-Mediated_Preparation_of_Amine-Boranes/12374933 |
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