Single crystal X-ray crystallography instructional materials were developed using a variety of compounds including sugar, Epsom salt, pyrite, copper(II) acetate, and rhodium(II) acetate. Rhodium(II) acetate was reacted with a variety of functionalized benzonitriles, and when crystals were obtained, characterized using single crystal X-ray crystallography. Rhodium(II) acetate with adducts of 4-nitrobenzonitrile and 4-(dimethylamino)benzonitrile were also characterized using proton NMR spectroscopy and Fourier Transform Infrared Spectroscopy. Rhodium(II) acetate with adducts of 4-(dimethylamino)benzonitrile was used as a catalyst in a proof-ofconcept reaction to determine if it acts as a catalyst in cyclopropanation reactions. Further, the new rhodium(II) acetate dinitrile compounds were investigated to determine if they would yield a different product ratio of cyclopropanes than that from the model Rh=CRR' mediated reaction between ethyl diazoacetate and styrene. The resulting cyclopropanation products were characterized using Gas Chromatography Mass Spectrometry. Preliminary experimental results yielded a trans- to cis-2-phenylcyclopropanecarboxylate ratio of 40:60.
| Identifer | oai:union.ndltd.org:ETSU/oai:dc.etsu.edu:etd-5798 |
| Date | 01 December 2023 |
| Creators | Beauparlant, Alain |
| Publisher | Digital Commons @ East Tennessee State University |
| Source Sets | East Tennessee State University |
| Language | English |
| Detected Language | English |
| Type | text |
| Format | application/pdf |
| Source | Electronic Theses and Dissertations |
| Rights | Copyright by the authors. |
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