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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
1

Publication of Undergraduate Experiments, Development of Additional X-ray Crystallography Experiments, and Proof-of-Concept Cyclopropanation Reactions

Beauparlant, Alain 01 December 2023 (has links) (PDF)
Single crystal X-ray crystallography instructional materials were developed using a variety of compounds including sugar, Epsom salt, pyrite, copper(II) acetate, and rhodium(II) acetate. Rhodium(II) acetate was reacted with a variety of functionalized benzonitriles, and when crystals were obtained, characterized using single crystal X-ray crystallography. Rhodium(II) acetate with adducts of 4-nitrobenzonitrile and 4-(dimethylamino)benzonitrile were also characterized using proton NMR spectroscopy and Fourier Transform Infrared Spectroscopy. Rhodium(II) acetate with adducts of 4-(dimethylamino)benzonitrile was used as a catalyst in a proof-ofconcept reaction to determine if it acts as a catalyst in cyclopropanation reactions. Further, the new rhodium(II) acetate dinitrile compounds were investigated to determine if they would yield a different product ratio of cyclopropanes than that from the model Rh=CRR' mediated reaction between ethyl diazoacetate and styrene. The resulting cyclopropanation products were characterized using Gas Chromatography Mass Spectrometry. Preliminary experimental results yielded a trans- to cis-2-phenylcyclopropanecarboxylate ratio of 40:60.
2

Carbenoid Insertion Chemistry on Furanose Platforms as a Route to Natural Product Frameworks

Patton, Jennie L. 27 August 2008 (has links)
No description available.

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