A point defect model is developed in hyperstoichiometric uranium dioxide, UO2+x,in order to explain some experimental results of deviation from stoichiometry and electrical conductivity existing in the literature. This model takes into account both singly charged uranium vacancy, V'U , and two types of Willis clusters, characterized by two kinds of interstitial oxygen atoms that are located on two different sites and two oxygen vacancies, namely 2(Oi"Oi'Vȯ)4' and . The electron holes, ḣ , are also introcued to ensure the crystal global electroneutrality. An adjustment procedure of the most convincing experimental data of the literature, corresponding to the temperature and oxygen partial pressure dependencies of departure from stoichiometry,x, and electrical conductivity, [sigma] , has been undertaken. The fit model/experience obtained has been found fairly good, justifying, a posteriori, the relevance of the nature of the selected defects in the model.
| Identifer | oai:union.ndltd.org:DRESDEN/oai:qucosa.de:bsz:15-qucosa-191474 |
| Date | 11 December 2015 |
| Creators | Riahi, Fatma, Laouar, Sofiane, Mekki, Djamel Eddine |
| Contributors | Birine Nuclear Research Centre,, Badji Mokhtar University, Faculty of Science / Department of physics, LESIMS, Universität Leipzig, Fakultät für Physik und Geowissenschaften |
| Publisher | Universitätsbibliothek Leipzig |
| Source Sets | Hochschulschriftenserver (HSSS) der SLUB Dresden |
| Language | English |
| Detected Language | English |
| Type | doc-type:article |
| Format | application/pdf |
| Source | Diffusion fundamentals 11 (2009) 98, S. 1-15 |
Page generated in 0.0019 seconds