Europium and samarium doped fluorochlorozirconate (FCZ) glasses for optoelectronics applications: thermal and optical properties

Description

<p>Fluorochlorozirconate (FCZ) glasses are a member of heavy metal fluoride glasses, and are derived from a well known ZBLAN glass. In this work, halogen salts of europium (Eu²⁺) and samarium (Sm³⁺) are used as dopants in FCZ glasses. FCZ glasses doped with Eu²⁺ and Sm³⁺ can be used in high resolution x-ray imaging for tissue scanning, and have been shown to behave as storage phosphors and/or x-ray scintillators.</p>
<p>Glass transition (T_g), heat capacity (C_p) and glass crystallization (T_c) properties of Eu²⁺ and Sm³⁺ doped and undoped FCZ glasses with different amounts of relative Cl concentration, that is, with respect to the total Cl and F concentration have been investigated by conventional differential scanning calorimetry (DSC) and modulated differential scanning calorimetry (MDSC) techniques. MDSC experiments were performed at different heating rates to analyze the complex transitions and to get a better resolution of any overlapping transitions. The crystallization kinetics have also been studied by applying the Kissinger technique to multiple DSC scans in order to determine the thermal stability of FCZ glass samples used in this work. The apparent activation energy for the crystallization process was obtained by the crystallization peak temperature shift method in the conventional DSC mode. The specific heat capacity (C_p) has been measured as a function of composition, and the glass transition temperature (T_g) is evaluated from the smooth change in the heat capacity curve during the glass transformation. The observation of two possible glass transitions points to the presence of two phases in these FCZ glasses with higher relative Cl content.</p>
<p>Optical transmission spectra of both doped and undoped FCZ glass samples have been measured by infrared spectroscopy and optical band gaps corresponding to an absorption coefficient of 10³ cm^-1 have been determined. A good correlation between X-ray luminescence and the glass structure is observed. While the integrated photoluminescence intensity increases linearly with the Sm³⁺ concentration, the integrated X-ray luminescence increases sublinearly. The importance of appropriate annealing conditions, such as temperature, time and ambient atmosphere, and their effect on the X-ray luminescence of rare earth (RE) doped FCZ glass samples have been investigated. Annealing conditions influence the formation of BaCl₂ nanocrystals in the glass and the properties of the resulting FCZ glass ceramics.</p>

Tags

RE doped FCZ.

DSC

infrared spectroscopy

FCZ glass

MDSC

Additional Fields

Identifer	oai:union.ndltd.org:LACETR/oai:collectionscanada.gc.ca:SSU.etd-08112011-230800
Date	23 August 2011
Creators	Panigrahi, Sujata
Contributors	Oguocha, Ikechukwuka N., Johanson, Robert, Chen, Li, Kasap, Safa O.
Publisher	University of Saskatchewan
Source Sets	Library and Archives Canada ETDs Repository / Centre d'archives des thèses électroniques de Bibliothèque et Archives Canada
Language	English
Detected Language	English
Type	text
Format	application/pdf
Source	http://library.usask.ca/theses/available/etd-08112011-230800/
Rights	unrestricted, I hereby certify that, if appropriate, I have obtained and attached hereto a written permission statement from the owner(s) of each third party copyrighted matter to be included in my thesis, dissertation, or project report, allowing distribution as specified below. I certify that the version I submitted is the same as that approved by my advisory committee. I hereby grant to University of Saskatchewan or its agents the non-exclusive license to archive and make accessible, under the conditions specified below, my thesis, dissertation, or project report in whole or in part in all forms of media, now or hereafter known. I retain all other ownership rights to the copyright of the thesis, dissertation or project report. I also retain the right to use in future works (such as articles or books) all or part of this thesis, dissertation, or project report.