<p>Total synthesis of massarinolin A, purpurlides B, D, E, 2,3-deoxypurpurolide C, phleghenrines A and B were finished. A halogen bond promoted michael addiation was discovered during mechanism study toward diamination of allenes. Computational chemsitry study conducted toward the selectivity of 2+2 reaction supported the proposed key reaction during total synthesis of gibberellic acid 18.</p>
| Identifer | oai:union.ndltd.org:purdue.edu/oai:figshare.com:article/21397566 |
| Date | 27 October 2022 |
| Creators | Ye-Cheng Wang (14009903) |
| Source Sets | Purdue University |
| Detected Language | English |
| Type | Text, Thesis |
| Rights | CC BY 4.0 |
| Relation | https://figshare.com/articles/thesis/TOTAL_SYNTHESES_OF_BERGAMOTANE_SESQUITERPENES_AND_LYCOPODIUM_ALKALOIDS_AND_COMPUTATIONAL_STUDY_TOWARD_DIAMINATION_OF_ALLENES_AND_2_2_SELECTIVITY/21397566 |
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