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Previous issue date: 2015-02-27 / Ferritas de estrutura espin?lio (MFe2O4; M= metal alcalino terroso ou metal de transi??o) desempenham um papel importante na ci?ncia fundamental e na tecnologia moderna. A ferrita de magn?sio (MgFe2O4) e seus compostos dopados tem recebido especial aten??o devido a sua vasta ?rea de atua??o, que inclui aplica??es em m?dia de alta grava??o, cat?lise heterog?nea, adsor??o, sensores e tecnologias magn?ticas, de um modo geral. Suas propriedades estruturais, el?tricas e magn?ticas dependem da composi??o qu?mica, estrutura, tamanho de part?culas, al?m da substitui??o de c?tions nos s?tios A e/ou B que s?o diretamente influenciados pelo m?todo de s?ntese, as condi??es empregadas no processamento desses materiais (temperatura, taxa de aquecimento e tempo). Neste trabalho, ferritas do tipo Mg1-xBxFe2O4 (B= Ni; Cu; x= 0; 0,25; 0,50; 0,75 e 1) foram preparadas pelo m?todo de combust?o assistido por micro-ondas com a finalidade de avaliar tanto o efeito da substitui??o parcial do magn?sio por n?quel e cobre quanto o tratamento t?rmico sobre as propriedades magn?ticas. Os p?s precursores foram tratados termicamente a 600?C, 800?C e 1000?C/2h e caracterizados por An?lise Termogravim?trica (ATG), Difra??o de Raios X (DRX) em conjunto com o Refinamento pelo m?todo Rietveld, Microscopia eletr?nica de varredura (MEV) e Medidas de histerese magn?ticas realizadas ? temperatura ambiente. De acordo com as curvas termogravim?tricas dos p?s precursores, um comportamento semelhante foi observado para ambos os sistemas de amostras, onde o processo de perda total de massa aconteceu basicamente em duas etapas e na faixa de temperatura entre 30 e 500?C para o sistema Mg1-xNixFe2O4 e entre 30 e 400?C para o sistema Mg1-xCuxFe2O4. Os difratogramas de raios X revelaram a forma??o da fase espin?lio MgFe2O4 (ICSD 76176) de estrutura c?bica, e de fases secund?rias como Fe2O3 (ICSD 88418), NiO (ICSD 9866) e CuO (ICSD 87125) para os sistemas estudados. Em rela??o ?s curvas de histerese, verificou-se uma depend?ncia da magnetiza??o em fun??o do teor de dopante e da temperatura de tratamento t?rmico adotada. / The magnesium ferrite (MgFe2O4) and their doped compounds has received special attention due to its wide area of use, including applications in high recording media, heterogeneous catalysis, adsorption, sensors and magnetic technologies. Its structural, electrical and magnetic properties depend on the chemical composition, structure, particle size, and the replacement of cations in the sites A and/or B, which are directly influenced by the synthesis method, the conditions employed in processing these materials. In this work, ferrites of the type Mg1-xBxFe2O4 (B = Ni, Cu; x = 0, 0.25, 0.50, 0.75 and 1) were prepared by combustion method assisted by microwave in order to evaluate both the effect of partial substitution of Mg2+ for Ni2+ and/or Cu2+ as thermal treatment on the magnetic properties. Precursor powders were treated at the temperatures of 600 ?C, 800 ?C and 1000 ?C with 2h level and characterized by Thermogravimetric Analysis (TGA), X-Ray Diffraction (XRD) and refinement by the Rietveld method, Scanning Electron Microscopy (SEM) and magnetic hysteresis measurements at room temperature. According to the TG curves of the precursor powders, a similar behavior was observed for both systems where the total mass loss process occurred in two stages and in the temperature range between 30 and 500 ?C for Mg1-xNixFe2O4 system (x = 0, 0.25, 0.50 and 0.75) and between 30 and 450 ?C for Mg1-xCuxFe2O4 system (x = 0, 0.25, 0.50 and 0.75). The X-ray diffraction revealed the formation of the spinel phase MgFe2O4 (ICSD 76176) of cubic symmetry, and secondary phases such as ?-Fe2O3 (ICSD 88418), NiO (ICSD 9866) and CuO (ICSD 87125), for the studied systems. Regarding the hysteresis curves, there was a dependence of the magnetization as a function of the dopant content and the heat treatment temperature adopted. For Mg0,25Ni0,75Fe2O4 Mg0,75Cu0,25Fe2O4 and samples treated at 1000 ?C showed the highest saturation magnetization values of 41.9 emu/g and 35.76 emu/g, respectively.
| Identifer | oai:union.ndltd.org:IBICT/oai:repositorio.ufrn.br:123456789/21540 |
| Date | 27 February 2015 |
| Creators | Costa, Antonio Carlos Silva da |
| Contributors | 50580396720, Lima, Andreia Cavalcante de, 02677227452, Sousa, Clawsio Rogerio Cruz de, 05328256409, Ramalho, Eduardo Galv?o, 03605359418, Silva, Vamberto Monteiro da, 67456863415, Acchar, Wilson |
| Publisher | PROGRAMA DE P?S-GRADUA??O EM CI?NCIA E ENGENHARIA DE MATERIAIS, UFRN, Brasil |
| Source Sets | IBICT Brazilian ETDs |
| Language | Portuguese |
| Detected Language | English |
| Type | info:eu-repo/semantics/publishedVersion, info:eu-repo/semantics/doctoralThesis |
| Source | reponame:Repositório Institucional da UFRN, instname:Universidade Federal do Rio Grande do Norte, instacron:UFRN |
| Rights | info:eu-repo/semantics/openAccess |
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