For the first time, successful synthesis of an unknown class of compounds, 3-azido-2H-azirines, which are implicated as highly reactive intermediates in the thermolysis of the corresponding 1,1-diazidoethenes, has been performed. These elusive heterocycles have been detected and characterised by low-temperature NMR and in situ IR spectroscopy. Even the parent compound, 3-azido-2H-azirine, has been observed via low-temperature photolysis of 1,1-diazidoethene, as a highly reactive species with a half-life period of only 12 min at −40 °C. / Dieser Beitrag ist aufgrund einer (DFG-geförderten) Allianz- bzw. Nationallizenz frei zugänglich.
Identifer | oai:union.ndltd.org:DRESDEN/oai:qucosa:de:qucosa:20675 |
Date | 29 March 2017 |
Creators | Weigand, Kevin, Singh, Neeraj, Hagedorn, Manfred, Banert, Klaus |
Publisher | Royal Society of Chemistry |
Source Sets | Hochschulschriftenserver (HSSS) der SLUB Dresden |
Language | English |
Detected Language | English |
Type | doc-type:article, info:eu-repo/semantics/article, doc-type:Text |
Source | Org. Chem. Front., 2017,4, 191-195 |
Rights | info:eu-repo/semantics/openAccess |
Relation | 10.1039/C6QO00625F, 2052-4129 |
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