Crystal structure of ruthenocenecarbo­nitrile

Description

The mol­ecular structure of ruthenocenecarbo­nitrile, [Ru([eta]5-C5H4C[triple bond]N)([eta]5-C5H5)], exhibits point group symmetry m, with the mirror plane bis­ecting the mol­ecule through the C[triple bond]N substituent. The RuII atom is slightly shifted from the [eta]5-C5H4 centroid towards the C[triple bond]N substituent. In the crystal, mol­ecules are arranged in columns parallel to [100]. One-dimensional inter­molecular [pi]-[pi] inter­actions [3.363 (3) Å] between the C[triple bond]N carbon atom and one carbon of the cyclo­penta­dienyl ring of the overlaying mol­ecule are present.

Links & Downloads

1. urn:nbn:de:bsz:ch1-qucosa-166700
2. https://monarch.qucosa.de/id/qucosa%3A20242
3. https://monarch.qucosa.de/api/qucosa%3A20242/attachment/ATT-0/
4. https://monarch.qucosa.de/api/qucosa%3A20242/attachment/ATT-1/
5. https://monarch.qucosa.de/api/qucosa%3A20242/attachment/ATT-2/

Tags

info:eu-repo/classification/ddc/546

ddc:546

Kristallstruktur; Nitrile

Additional Fields

Identifer	oai:union.ndltd.org:DRESDEN/oai:qucosa:de:qucosa:20242
Date	07 May 2015
Creators	Strehler, Frank, Korb, Marcus, Lang, Heinrich
Contributors	Technische Universität Chemnitz
Publisher	International Union of Crystallography IUCR
Source Sets	Hochschulschriftenserver (HSSS) der SLUB Dresden
Language	English
Detected Language	English
Type	doc-type:article, info:eu-repo/semantics/article, doc-type:Text
Source	Acta Cryst. (2015). E71, 398-401
Rights	info:eu-repo/semantics/openAccess
Relation	10.1107/S205698901500540X, 1600-5368/2056-9890