The molecular structure of ruthenocenecarbonitrile, [Ru([eta]5-C5H4C[triple bond]N)([eta]5-C5H5)], exhibits point group symmetry m, with the mirror plane bisecting the molecule through the C[triple bond]N substituent. The RuII atom is slightly shifted from the [eta]5-C5H4 centroid towards the C[triple bond]N substituent. In the crystal, molecules are arranged in columns parallel to [100]. One-dimensional intermolecular [pi]-[pi] interactions [3.363 (3) Å] between the C[triple bond]N carbon atom and one carbon of the cyclopentadienyl ring of the overlaying molecule are present.
Identifer | oai:union.ndltd.org:DRESDEN/oai:qucosa.de:bsz:ch1-qucosa-166700 |
Date | 07 May 2015 |
Creators | Strehler, Frank, Korb, Marcus, Lang, Heinrich |
Contributors | International Union of Crystallography IUCR,, Technische Universität Chemnitz, Fakultät für Naturwissenschaften |
Publisher | Universitätsbibliothek Chemnitz |
Source Sets | Hochschulschriftenserver (HSSS) der SLUB Dresden |
Language | English |
Detected Language | English |
Type | doc-type:article |
Format | application/pdf, text/plain, application/zip |
Source | Acta Cryst. (2015). E71, 398-401 |
Page generated in 0.0024 seconds