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The Global ETD Search service is a free service for researchers
to find electronic theses and dissertations. This service is
provided by the
Networked Digital Library of Theses and Dissertations.
Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
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Crystal structure of ruthenocenecarbonitrileStrehler, Frank, Korb, Marcus, Lang, Heinrich 07 May 2015 (has links) (PDF)
The molecular structure of ruthenocenecarbonitrile, [Ru([eta]5-C5H4C[triple bond]N)([eta]5-C5H5)], exhibits point group symmetry m, with the mirror plane bisecting the molecule through the C[triple bond]N substituent. The RuII atom is slightly shifted from the [eta]5-C5H4 centroid towards the C[triple bond]N substituent. In the crystal, molecules are arranged in columns parallel to [100]. One-dimensional intermolecular [pi]-[pi] interactions [3.363 (3) Å] between the C[triple bond]N carbon atom and one carbon of the cyclopentadienyl ring of the overlaying molecule are present.
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Crystal structure of ruthenocenecarbonitrileStrehler, Frank, Korb, Marcus, Lang, Heinrich 07 May 2015 (has links)
The molecular structure of ruthenocenecarbonitrile, [Ru([eta]5-C5H4C[triple bond]N)([eta]5-C5H5)], exhibits point group symmetry m, with the mirror plane bisecting the molecule through the C[triple bond]N substituent. The RuII atom is slightly shifted from the [eta]5-C5H4 centroid towards the C[triple bond]N substituent. In the crystal, molecules are arranged in columns parallel to [100]. One-dimensional intermolecular [pi]-[pi] interactions [3.363 (3) Å] between the C[triple bond]N carbon atom and one carbon of the cyclopentadienyl ring of the overlaying molecule are present.
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