Spent caustic liquors (SCL) generated from crude oil refineries have characteristics of high COD (chemical oxygen demand) contents and relatively small generation rates as compared with general wastewater ones. The odorous naphthenates, phenolates, and sulfides in the liquors adversely affect the normal operation of the related wastewater treatment plants and effluent water qualities.
This study aims at the reduction of COD in a naphthenic spent caustic liquor generated from a domestic refinery with crude processing and naphtha cracking units. Primary tests indicated that around 50% of the COD in the SCL could be biodegraded. Chemical oxidation methods were tried to possibly upgrade the COD removal. Experiments indicated that acidification of the SCL sample to pH 2-3 could reduce the COD from an average of 51,600 to 20,800 mg/L by removing the separated naphthenic acids. Fenton¡¦s method with oxidants of 20 mL/L 35% H2O2 and FeSO4.7H2O 5 g/L, oxidation time of 1 hour at conditions of pH 2-3 and 80-100oC, could reduce the COD of the acidified SCL from an average of 20,800 to 11,100 mg/L. The overall COD removal was around 78% and the efficiency is comparable to that of a traditional Wet Air Oxidation (WAO) process of around 75%.
Economic analysis indicated that for treating the SCL of 80 m3/day by the traditional WAO process, an initial equipment cost of 10 millions USD and annual operating cost of around 1.5 millions USD are required. By the developed acidification-Fenton¡¦s process, an initial equipment cost of 0.7 million USD and annual operating cost of around 0.5 million USD are expected. The developed process can be superior to the WAO one.
| Identifer | oai:union.ndltd.org:NSYSU/oai:NSYSU:etd-0621112-175704 |
| Date | 21 June 2012 |
| Creators | LI , Sin-Jia |
| Contributors | Kang-Shin Chen, Mei-Jyuan syu, Ming-Shean Chou |
| Publisher | NSYSU |
| Source Sets | NSYSU Electronic Thesis and Dissertation Archive |
| Language | Cholon |
| Detected Language | English |
| Type | text |
| Format | application/pdf |
| Source | http://etd.lib.nsysu.edu.tw/ETD-db/ETD-search/view_etd?URN=etd-0621112-175704 |
| Rights | user_define, Copyright information available at source archive |
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