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Geochemical and isotope investigations of carbonate sinter – 2000 years of water supply management in Palestine

Over thousands of years, the eastern part of the Mediterranean has developed ways to supply and manage its water resources. The most important evidence of this is the water networks that are distributed in the area. Case studies involving a literature review, fieldwork, sample collection and analysis were conducted that focused on two areas in the West Bank: Nablus city and the northern part of Jordan Valley. These locations were chosen because Nablus city and its vicinity have many of Roman tunnels and aqueducts while the Jordan Valley has many watermills.
This study aims to examine the changes in water quality over time in various ways; in an attempt to explain environmental degradation, to understand archeological aspects relating to the water management system, and to piece together what sustained the past environmental development.
Throughout centuries carbonate deposits have accumulated along the sidewalls of the water system, containing and archiving geochemical and hydraulic information. These carbonate deposits were sampled from the walls of tunnels together with water samples from the tunnel and surrounding springs in the area. In addition, carbonate sinter has accumulated at the outlet of the watermill on the water shaft. This sinter was also sampled along with water samples from the springs and the water in the Wadi in the area. Water and carbonate samples were analyzed. Water analysis included major cations and anions, trace elements, rare earth elements, 18O/16O isotope ratio, and 87Sr/86Sr isotope ratio. Results indicate the presence of different underground water bodies and Sr resources.
Furthermore, thin sections were made from the carbonate samples for SEM–EDX analyses and microscopic investigations. The microscope analysis showed that the distribution of minerals precipitated differs within one sample. Likewise, SEM–EDX results show a variation in element distribution along the growth axis.
After finishing the analysis of water samples and thin sections, the layers of the carbonate samples were acidified and trace elements and rare earth elements were measured by means of ICP–MS. Then selected layers were prepared for isotope analyses (18O, 13C, and 87Sr/86Sr) and subsequently measured. The carbonate samples were dated using the U–Th method.
Rare earth elements and trace elements measurements provide clear evidence that urbanization has an adverse effect on groundwater quality. Different groundwater bodies were identified by means of geochemical analysis. In the same way, the water sources used to feed the ancient water system were also identified. Through petrological and geochemical analysis, the sustainability of the watermill concept could be demonstrated.
This study recommends a more controlled regulation of urbanization expansion. It will only be possible to continue living in this region with sufficient amounts of groundwater and innovative techniques for water supply and management that are environmentally sustainable, as it used to be centuries ago.

Identiferoai:union.ndltd.org:DRESDEN/oai:qucosa.de:bsz:105-qucosa-215797
Date12 December 2016
CreatorsSabri, Raghid N. R.
ContributorsTechnische Universität Bergakademie Freiberg, Geowissenschaften, Geotechnik und Bergbau, Prof. Dr Broder Merkel, Prof. Dr Broder Merkel, Dr. Edwige Pons-Branchu, Prof. Dr. Marion Tichomirowa
PublisherTechnische Universitaet Bergakademie Freiberg Universitaetsbibliothek "Georgius Agricola"
Source SetsHochschulschriftenserver (HSSS) der SLUB Dresden
LanguageEnglish
Detected LanguageEnglish
Typedoc-type:doctoralThesis
Formatapplication/pdf

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