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ContribuiÃÃo ao conhecimento quÃmico de plantas do Nordeste do Brasil: Cordia piauhiensis Fresen e Triphsia trifolia (Burm. f.) P.Wils / Contribution to Northeast the chemical Knowledge of plants of Brazil: Cordia piauhiensis Fresen e Triphasia trifolia (Burm. f.) P. Wils

Conselho Nacional de Desenvolvimento CientÃfico e TecnolÃgico / A composiÃÃo quÃmica do Ãleo essencial das folhas e frutos de Triphasia trifolia
(Rutaceae) foi analisada por CG- DIC e CG-MS. Os constituintes majoritÃrios identificados para os Ãleos obtidos das folhas foram sabineno (39,2 e 33,8%) e mirceno (21,9 e 33,6%), enquanto os compostos majoritÃrios para o Ãleo dos frutos foram sabineno (35,5 e 22,8%), -pineno (21,2 e 29,9%) e -terpineno (18,4 e 12,9%). Os Ãleos das folhas apresentaram moderada atividade antimicrobiana. O decocto dos frutos tambÃm foi investigado levando ao isolamento das cumarinas isopimpinelina, (R)-biakangelicina e (S)-mexoticina. Das folhas foram isoladas as cumarinas (R)-biakangelicina, aurapteno, (S)-mexoticina, isosibiricina, isomerazina e coumurraina e, o flavonÃide vitexina. Todas cumarinas em CCD, mostraram atividade frente à enzima acetilcolinesterase. De Cordia piauhiensis Fresen (Boraginaceae), cinco saponinas triterpÃnicas foram isoladas. Suas estruturas foram caracterizadas como Ãcido 3-O-[-L-ramnopiranosil- (12)--D-glicopiranosil] pomÃlico, pomolato de 3-O-[-L-ramnopiranosil-(12)--Dglicopiranosil] 28-O--D-glicopiranosil-(16)--D-glicopiranosila, ursolato de 3-O-[- L-ramnopiranosil-(12)--D-glicopiranosil] 28-O--D-xilopiranosil-(12)- -Dglicopiranosil-( 16)--D-glicopiranosila, pomolato de 3-O-[-L-ramnopiranosil-(12)- -D-glicopiranosil] 28-O--D-glicopiranosila e oleanolato de 3-O-[-L-ramnopiranosil- (12)--D-glicopiranosil] 28-O--D-glicopiranosil-(16)--D-glicopiranosila. As estruturas foram estabelecidas usando uma combinaÃÃo das tÃcnicas de RMN 1D e 2D (1H- 1H-COSY, HMQC, HMBC, TOCSY e NOESY), ESIMS, alÃm de evidÃncias quÃmicas. / The chemical composition of the essential oils from leaves and fruits of Triphasia trifolia were analyzed by GC-FID and GC-MS. The major constituents identified for oils obtained from leaves were sabinene (39.2 and 33.8%) and myrcene (21.9 and 33.6%), while the prevalent compounds detected in fruit oils were sabinene (35.5 and 22.8%), -pinene (21.2 and 29.9) and -terpinene (18.4 and 12.9%). The leaf oils showed moderate antimicrobial activity. The fruit decoction was also investigated leading to the isolation of the coumarins isopimpinelin, (R)-byakangelicin and (S)-mexoticin. From the leaves the coumarins (R)-byakangelicin, aurapten, (S)-mexoticin, isosibiricin, isomerazin and coumurrayin and, the flavonoid vitexina were isolated. All coumarins showed cholinesterase inhibition on TLC test. From Cordia piauhiensis Fresen (Boraginaceae), five triterpenoid saponins were isolated. Their structures were characterized as 3-O--L-rhamnopyranosyl-(1_2)--Dglucopyranosyl pomolic acid, 3-O-[-L-rhamnopyranosyl-(12)--D-glucopyranosyl] pomolic acid 28-O-[-D-glucopyanosyl-(16)--D-glucopyranosyl] ester, 3-O-[-Lrhamnopyranosyl-( 12)--D-glucopyranosyl] ursolic acid 28-O-[-D-xilopyranosyl- (1_2)--D-glucopyanosyl-(16)--D-glucopyranosyl] ester, 3-O--L-rhamnopyranosyl- (12)--D-glucopyranosyl pomolic acid 28-O--D-glucopyranosyl ester and 3-O--Lrhamnopyranosyl-( 12)--D-glucopyranosyl oleanolic acid 28-O--D-glucopyranosyl- (16)--D-glucopyranosyl ester. The structures were established using a combination of 1D and 2D (1H-1H-COSY, HMQC, HMBC, TOCSY and NOESY) NMR techniques, ESIMS and chemical evidences.

Identiferoai:union.ndltd.org:IBICT/oai:www.teses.ufc.br:1430
Date04 September 2007
CreatorsRenata Paiva dos Santos
ContributorsOtÃlia DeusdÃnia Loiola Pessoa
PublisherUniversidade Federal do CearÃ, Programa de PÃs-GraduaÃÃo em QuÃmica OrgÃnica, UFC, BR
Source SetsIBICT Brazilian ETDs
LanguagePortuguese
Detected LanguageUnknown
Typeinfo:eu-repo/semantics/publishedVersion, info:eu-repo/semantics/doctoralThesis
Formatapplication/pdf
Sourcereponame:Biblioteca Digital de Teses e Dissertações da UFC, instname:Universidade Federal do Ceará, instacron:UFC
Rightsinfo:eu-repo/semantics/openAccess

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