The molecular structure of ruthenocenecarbonitrile, [Ru([eta]5-C5H4C[triple bond]N)([eta]5-C5H5)], exhibits point group symmetry m, with the mirror plane bisecting the molecule through the C[triple bond]N substituent. The RuII atom is slightly shifted from the [eta]5-C5H4 centroid towards the C[triple bond]N substituent. In the crystal, molecules are arranged in columns parallel to [100]. One-dimensional intermolecular [pi]-[pi] interactions [3.363 (3) Å] between the C[triple bond]N carbon atom and one carbon of the cyclopentadienyl ring of the overlaying molecule are present.
| Identifer | oai:union.ndltd.org:DRESDEN/oai:qucosa.de:bsz:ch1-qucosa-166700 |
| Date | 07 May 2015 |
| Creators | Strehler, Frank, Korb, Marcus, Lang, Heinrich |
| Contributors | International Union of Crystallography IUCR,, Technische Universität Chemnitz, Fakultät für Naturwissenschaften |
| Publisher | Universitätsbibliothek Chemnitz |
| Source Sets | Hochschulschriftenserver (HSSS) der SLUB Dresden |
| Language | English |
| Detected Language | English |
| Type | doc-type:article |
| Format | application/pdf, text/plain, application/zip |
| Source | Acta Cryst. (2015). E71, 398-401 |
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