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Experimentos de RPE em diferentes concentrações de oxigênio do supercondutor y Ba2 Cu3 07-X e dos compostos Ba Cu 02+X e Y2 Ba Cu 05

Orientador: Gaston Eduardo Barberis / Dissertação (mestrado) - Universidade Estadual de Campinas, Instituto de Fisica Gleb Wataghin / Made available in DSpace on 2018-07-14T01:16:39Z (GMT). No. of bitstreams: 1
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Previous issue date: 1991 / Resumo: Não informado / Abstract: Room-temperature X- and Q- band ESR spectra of the high-Tc superconductor Yba2Cu3O7-x and the semiconductors Y2baCuO5 and BaCuO2+x are studied experimentally and theoretically by measuring, calculating, and fitting the powder spectra corresponding to an anisotropic Zeeman Hamiltonian for CU2+ in orthorhombic and tetragonal local symmetries ESR and x-ray studies in their corresponding oxygen-deficient stoichiometries, obtained by heat treatment under vacuum, were also done. Our results support those of Bowdeen et al. and Vier et al. in Rba2Cu3O7-x (R = Y, Eu), indicating that the Cu(1) and Cu(2) atoms in the pure Yba2Cu3O7-x phase are not ESR active and the small resonance observed in these compounds comes from other residual phases. The purest Yba2Cu3O7-x samples that we were able to prepare still have 0.1-0.5% mass fraction of other residual copper compounds which are responsible for the observed resonance / Mestrado / Física / Mestre em Física

Identiferoai:union.ndltd.org:IBICT/oai:repositorio.unicamp.br:REPOSIP/277804
Date14 November 1991
CreatorsMesquita, Roberto Navarro de
ContributorsUNIVERSIDADE ESTADUAL DE CAMPINAS, Barberis, Gaston Eduardo, 1941-
Publisher[s.n.], Universidade Estadual de Campinas. Instituto de Física Gleb Wataghin, Programa de Pós-Graduação em Física
Source SetsIBICT Brazilian ETDs
LanguagePortuguese
Detected LanguageEnglish
Typeinfo:eu-repo/semantics/publishedVersion, info:eu-repo/semantics/masterThesis
Format[125]f. : il., application/pdf
Sourcereponame:Repositório Institucional da Unicamp, instname:Universidade Estadual de Campinas, instacron:UNICAMP
Rightsinfo:eu-repo/semantics/openAccess

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