The fate and distribution of copper-based crop protectants, applied to tomato fields to protect against disease, were investigated in a greenhouse-scale simulation of farming conditions in a coastal environment. Following rainfall, 99% of the applied copper was found to remain on the fields sorbed to the soil and plants; most of the soil-bound copper was found sorbed to the top 2.5 centimeters of soil. Of the copper leaving the agricultural fields, 82% was found in the runoff with the majority, 74%, sorbed to the suspended solids. The remaining copper, 18%, leached through the soil and entered the groundwater with 10% in the dissolved phase and 8% sorbed to suspended solids. Although only one-percent of the copper was found to leave the field, this was sufficient to cause high copper concentrations (average 2102 ± 433 mg/L total copper and 189 ± 139 mg/L dissolved copper) in the runoff. Copper concentrations in groundwater samples were also high (average 312 ± 198 mg/L total copper and 216 ± 99 mg/L dissolved copper). Sedimentation, a best management practice for reducing copper loadings, was found to reduce the total copper concentrations in runoff by 90% to a concentration of 245 ± 127 mg/L; however, dissolved copper concentrations remained stable, averaging 139 ± 55 mg/L. Total copper concentrations were significantly reduced by the effective removal of suspended solids with sorbed copper.
This research was supported by a grant from the Virginia Department of Agriculture and Consumer Services. Funding was also provided by Sea Grant. / Master of Science
| Identifer | oai:union.ndltd.org:VTETD/oai:vtechworks.lib.vt.edu:10919/32347 |
| Date | 12 May 1999 |
| Creators | Stall, Karen Marie |
| Contributors | Environmental Engineering, Dillaha, Theo A. III, Gallagher, Daniel L., Dietrich, Andrea M. |
| Publisher | Virginia Tech |
| Source Sets | Virginia Tech Theses and Dissertation |
| Detected Language | English |
| Type | Thesis |
| Format | application/pdf, application/pdf, application/pdf, application/pdf, application/pdf, application/pdf, application/pdf, application/pdf, application/pdf |
| Rights | In Copyright, http://rightsstatements.org/vocab/InC/1.0/ |
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