PhD Thesis / In this thesis, experiments are described which study the elastocapillary interactions between liquids and taut solid films. The research employs contact angle measurements to elucidate how capillary forces deform compliant solid structures, but also to attain fundamental insight into the energy of interfaces involving amorphous solids.
The majority of the work focuses on how capillary deformations of compliant elastic membranes introduce modifications to descriptions of common wetting phenomena. Particular focus is given to studying partial wetting in the presence of compliant membranes in various geometries: droplet on a free-standing membrane, droplet capped by a membrane but sessile on a rigid substrate, and droplet pressed between two free-standing membranes. The mechanical tension in these membranes is found to play an equivalent role as the interfacial tensions. As such, the mechanical tension is incorporated into Young-Dupre's law (capped droplet on a rigid substrate) or Neumann's triangle (droplet on free-standing membrane), leading to departures from the classical wetting descriptions. In addition, one study is conducted investigating how viscous dewetting is affected by the liquid film being capped by an elastic film. The results of this study show that the dewetting rate and rim morphology are dictated by the elastic tension.
Another important aspect of the work is demonstrating the utility of anisotropic membrane tension for liquid patterning. A biaxial tension is shown to produce droplets and dewetting holes which are elongated along the high tension direction. The compliant membrane geometry can also be designed to produce droplets and holes with square morphology.
In the final project, the surface energy of strained glassy and elastomeric solids is studied. Glassy solids are shown to have strain-dependent surface energies, which implies that surface energy (energy per unit area) and surface stress (force per unit length) are not equivalent for this class of materials by virtue of the Shuttleworth equation. On the other hand, this study provides strong evidence that surface energy and surface stress are equivalent for elastomeric interfaces. / Thesis / Doctor of Philosophy (PhD)
| Identifer | oai:union.ndltd.org:mcmaster.ca/oai:macsphere.mcmaster.ca:11375/23405 |
| Date | January 2018 |
| Creators | Schulman, Rafael D |
| Contributors | Dalnoki-Veress, Kari, Physics and Astronomy |
| Source Sets | McMaster University |
| Language | English |
| Detected Language | English |
| Type | Thesis |
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