The study of shock-waves in supersonic plasma jets is essential to understanding the complex dynamics involved in many physical systems. Specifically, ion-species separation caused by a shock wave propagating through a plasma is an important but not yet well understood phenomenon. In inertial confinement fusion implosions, a shock wave precedes the rapid compression of a fuel pellet to ignition conditions that theory and computational studies suggest may be separating the fuel and reducing the neutron yield. In astrophysics, the shock wave produced when a supernovae explodes has been shown to have an effect on nucleosynthesis as a result of shock heating. In both these cases the time and length scales make them difficult to study experimentally, but experiments on more reasonable scales can shed light on these phenomena. This body of work provides the basis for doing just that. The work begins by describing the development of a small, linear, plasma-armature railgun designed to accelerate plasma jets in vacuum to high-Mach-number. This is followed by discussion of an experimental campaign to establish a plasma parameter space for the jets, in order to predict how effectively the accelerator can be used to study centimeter-scale shock structures in jet collisions. The final section presents an experimental campaign in which jet collisions are induced, and the resultant structures that appear during the collision are diagnosed to assess how conducive the experiment is to the future study of shock-wave induced species separation in laboratory plasmas. This work is a foundation for future experimental studies of ion-separation mechanisms in a multi-ion-species plasma. This research was supported in part by the National Science Foundation under grant number PHY-1903442. / Doctor of Philosophy / Plasma, the so-called fourth state of matter, is an ionized gas that often behaves like a fluid but can also become magnetized and carry an electric current. This combination leads to a lot of interesting yet often un-intuitive physics, the study of which is very important for understanding a wide array of topics. One subset of this field is the study of shock-wave induced species separation. Just like the shock-wave a jet aircraft produces when it moves through the air at a speed greater than the speed of sound, a plasma shock is characterized by a large change in parameters like density, temperature, and pressure across a very small region. A shock-wave propagating through a plasma can cause different ion species present to separate out, a phenomenon that is driven by the gradients that are present across a shock front. Understanding how these mechanisms work is important to a number of applications, including fusion energy research and astrophysical events. The first section of this work discusses the design and development of a plasma-armature railgun, a device that can produce and accelerate jets of plasma to high-Mach-number within a vacuum chamber. The next and most substantive section of the work presents results from experimental campaigns to characterize the accelerated plasma jets and then to induce plasma-jet collisions with the hope of producing shock-waves that exist on time and spatial scales that can be readily measured in a laboratory setting. This work is a foundation for future experimental attempts to measure separation induced by a shock-wave in order to better understand these complex phenomena.

No description available.

published_or_final_version / Physics / Master / Master of Philosophy

Computational simulations of air glow discharge plasma in the presence of supersonic flow are presented. The glow discharge model is based on a self-consistent, multi-species, continuum description of the plasma with finite-rate chemistry effects. The glow discharge model is coupled to a compressible Navier-Stokes solver to study the effect of the plasma on the flow and the counter-effect of the flow on the plasma. A finite-rate air chemistry model is presented and validated against experiments from the literature at a pressure of 600 mTorr. Computational results are compared with experimentally measured V-I characteristics, axial positive ion densities and electron temperature, and reasonably good qualitative and quantitative agreement is observed. The validated air plasma model is then used to study the effect of the surface plasma discharge on M=3 supersonic flow at freestream pressure 18 Torr and the corresponding effects of the flow on the discharge structure in two dimensions. The species concentrations and the gas temperature are examined in the absence and presence of bulk supersonic flow. The peak gas temperature from the computations is found to be 1180 K with the surface plasma alone in the absence of flow, and 830 K in the presence of supersonic flow. Results indicate that O- ions can have comparable densities to electrons in the pressure range 1-20 Torr, and that O2- ion densities are at least two orders of magnitude smaller over the pressure range considered. Different ion species are found to be dominant in the absence and presence of supersonic flow, highlighting the importance of including finite-rate chemistry effects in discharge models for understanding plasma actuator physical phenomena. Electrode polarity effects are investigated, and the cathode upstream actuation is found to be stronger than the actuation strength with the cathode downstream, which is consistent with experimental findings of several groups. A parallel computing implementation of the plasma and flow simulation tools has been developed and is used to study the three-dimensional plasma actuator configuration with circular pin electrodes. / text

Spectroscopic investigations have been carried out on an argon inductively coupled plasma operating at non-atmospheric pressure. The relationship between torch pressure and a number of plasma operating characteristics was explored for torch pressures between 100 and 3000 torr. The plasma operating characteristics examined include observed analyte emission intensities, electron densities, ion to atom ratios, and the deviation of plasma conditions from local thermodynamic equilibrium. The effect of pressure on the observed analyte emission intensities was found to include factors in addition to the change in density of species within the torch. Emission lines originating from ions and atoms with high ionization potentials (greater than 7 eV) increased in intensity with increasing torch pressure, in excess of that predicted by the increase in density of species present. Conversely, emission lines originating from atoms of low ionization potential decreased in intensity with increasing torch pressure despite the increase in density. The results of the spatial determination of electron densities and ion to atom ratios indicate that excitation conditions within the central channel of the plasma are shifted towards conditions of local thermodynamic equilibrium as the pressure within the torch is increased. In addition, it is possible to obtain improved limits of detection by optimizing the torch pressure for the analyte element of interest.

Fundamental investigations have been carried out on an Inductively Coupled Plasma (ICP) operated at 148 MHz, a frequency which is nearly three times higher than any previously reported for analytical ICPs used in spectrochemical analysis. High frequency operation is expected to provide easier sample introduction into the discharge, with a consequence of less energetic conditions in the central channel. Several plasma diagnostic techniques were employed in order to determine the conditions experienced by the analyte species in this source for spectrochemical analysis. Three different torch systems were investigated at 148 MHz and compared to the "standard" 27 MHz configuration. The highest excitation temperatures and electron densities were obtained in the 27 MHz configuration, and the lowest values in the largest torch at 148 MHz. Intermediate values were obtained in the intermediate-size torches at 148 MHz. These observations correlate reasonably well with the ratio of the plasma radius to the skin depth (r/s). The skin depth defines the region in which the majority of the electrical energy is deposited into the discharge, and is smaller at 148 MHz than at 27 MHz. The measurement of electron densities also allows the estimation of how closely a particular discharge approaches Local Thermal Equilibrium (LTE). As may be expected, LTE is most closely approached in the 27 MHz arrangement. The less energetic conditions characterized by lower temperatures and electron densities result in less intense analyte emission from the high frequency ICPs. Signal-to-Background ratios and detection limits reflect this trend, but the linearity of the calibration curves and freedom from vaporization interferences are not degraded. Finally, the introduction of organic solvents is much easier, and better detection limits in an organic matrix are obtained at 148 MHz. These investigations have shown the utility of classifying the effects of changing torch sizes and operating frequencies by means of the r/s ratio. This provides the analyst with a means of selecting the general range of conditions to be employed in a particular analysis.

No description available.

The dissertation examines topics related to the formation of supercapacitors using plasma technology and their analysis. Plasma spray technology was used to form supercapacitors electrodes. Carbon was deposited on stainless steel surface using the atmospheric pressure argon-acetylene plasma. The deposition of nickel oxide on the surface of carbon electrodes was made using magnetron sputtering method. The influence of acetylene amount to the supercapacitors electrodes and the electrical characteristics of the structure were estimated. The nickel oxide influence to the electrical parameters of supercapacitor carbon electrodes, structure and microrelief was assessed too. The etching of carbon electrodes surface with oxygen plasma was performed and its impact on the capacitors electrical parameters and carbon electrode structure was evaluated. Mathematical modeling was used to theoretically estimate the influence of oxygen plasma to the supercapacitor carbon electrode surface microrelief. The anisotropic growth of carbon surface relief and isotropic surface erosion mechanism was theoretically explained. The impact mechanism of the acetylene content and plasmatron power to the carbon electrode structure and electrical parameters was qualitatively explained. The mechanism for understanding the influence of NiO content on the carbon electrodes to the supercapacitor electrical parameters and electrode structure was proposed. / Disertacijoje nagrinėjama tematika yra susijusi su superkondensatorių formavimu ir jų tyrimais naudojant plazmines technologijas. Superkondensatorių elektrodams formuoti panaudota plazminio purškimo technologija. Anglis ant nerūdijančio plieno paviršiaus užnešta panaudojant atmosferinio slėgio argono-acetileno plazmą. Nikelio oksidui nusodinti ant anglies elektrodų paviršiaus panaudotas magnetroninio garinimo metodas. Įvertinta acetileno kiekio įtaka superkondensatorių elektrinėms charakteristikoms ir elektrodų struktūrai. Tai pat įvertinta nikelio oksido kiekio įtaka superkondensatorių anglies elektrodų elektriniams parametrams, struktūrai bei mikroreljefui. Atliktas anglies elektrodų paviršiaus ėsdinimas deguonies plazma ir įvertintas jo poveikis kondensatorių elektriniams parametrams ir anglies elektrodų struktūrai. Matematiniu modeliavimu teoriškai įvertinta deguonies plazmos įtaka superkondensatorių anglies elektrodų paviršiaus mikroreljefui. Teoriškai pagrįstas anglies dangos reljefo anizotropinis augimas ir izotropinės paviršiaus erozijos mechanizmas. Kokybiškai paaiškintas acetileno kiekio ir plazmotrono galios įtakos mechanizmas anglies elektrodų struktūrai ir elektriniams parametrams. Pasiūlytas mechanizmas, aiškinantis NiO kiekio, esančio ant anglies elektrodų, įtaką superkondensatorių elektriniams parametrams ir elektrodų struktūrai.

Criteria for the confinement of plasmas consisting of a positive and negative component in Penning type traps with nested electric potential wells are presented. Computational techniques for the self-consistent calculation of potential and plasma density distributions are developed. Analyses are presented of the use of nested well Penning traps for several applications. The analyses include: calculations of timescales relevant to the applications, e.g. reaction, confinement and relaxation timescales, self-consistent computations, and consideration of other physical phenomenon important to the applications. Possible applications of a nested well penning trap include production of high charge state ions, studies of high charge state ions, and production of antihydrogen. In addition the properties of a modified Penning trap consisting of an electric potential well applied along a radial magnetic field are explored.

No description available.