The effects of surface applications of poultry manure on pH, exchangeable AI, exchangeable Al saturation and levels of available macronutrients in the surface and subsurface layers were investigated in some acid soils from the KwaZulu-Natal Midlands. Three field sites with a history of long-term applications of poultry manure were compared with adjacent fields where no manure had been applied. Results generally showed an increase in pHwater, pHKCI, exchangeable Ca, Mg, and K and extractable P and a decrease in exchangeable Al and exchangeable Al saturation in the surface soil to the depth to which the manure had been incorporated. Results also provided evidence for substantial downward movement of Ca and Mg into the subsoil layers (i.e. 30-60 cm) and their accumulation in exchangeable forms. There was a concomitant general increase in pHKcl and pHwater and decrease in exchangeable Al and exchangeable AI saturation in the subsoil layers. These results demonstrate that, under field conditions, surface applications of poultry manure can cause the amelioration of subsoil acidity. This is an extremely important finding since subsoil acidity is characteristically extremely difficult and costly to ameliorate. A leaching column study was subsequently conducted to investigate the mechanisms by which surface applications of poultry manure ameliorate both top- and subsoil acidity. The soil used, originating from one of the field sites, had not previously been treated with poultry manure and had a subsoil pHKCI of 4.25 and an exchangeable acidity concentration of 1.79 cmolJkg. Three forms of poultry manure (layer, broiler and free range) were incorporated into the surface 5 cm of soil columns at rates equivalent to 5, 10 and 30 Mg/ha. Columns were maintained in glasshouse conditions for a period of 108 days and over that period they were leached on four separate occasions (receiving a total of 825 mm of simulated rainfall). At the conclusion of the experiment, the soil columns were cut into sections for chemical analysis. Applications of poultry manure to the surface soil markedly increased pHwater, pHKcl, exchangeable Ca, Mg, K and Na concentrations and decreased exchangeable Al levels in the surface 5 cm layer. They also increased the concentrations of soluble C, soluble salts, total Al and organically-complexed Al in soil solution. These effects were most pronounced with layer manure and greater at the higher rate of application. The manure-induced decrease in exchangeable AI, but increase in total AI, in soil solution was attributed to soluble salts, originating from the manure, displacing exchangeable Al into solution where it was subsequently complexed by soluble organic matter. Analysis of subsoil layers (5-15, 15-25, 25-35 and 35-45 cm) at the conclusion of the experiment showed that surface applications of poultry manure decreased concentrations of exchangeable Al in the subsoil but had no effect on pHKCl and depressed values for pHwater. It was suggested that manure-derived urea leached into the subsoil and was then hydrolysed causing an increase in pH and precipitation of exchangeable Al as insoluble hydroxy-AI oxides. Towards the conclusion of the experiment nitrification began to proceed, causing subsoil pHKCl values to decrease back to their original values. Analysis of the inorganic-N content of leachates and soil layers provided circumstantial evidence for this mechanism. High concentrations of soluble salts in the subsoil layers (caused by leaching from the manure) resulted in displacement of exchangeable A13+ and W into soil solution so that the electrical conductivity and concentrations of total and monomeric Al were elevated and pHwater was depressed in the subsoil (15-45 cm) of poultry manure-treated columns. It was concluded that the results underline the opposing effects that poultry manure applications have on (i) raising soil pH and lowering exchangeable Al but at the same time (ii) greatly increasing soluble salt concentrations and thus displacing At3+ and H+ back into soil solution. They also have suggested the importance of the release of N during manure decomposition in influencing soil pH (through the processes of ammonification, urea hydrolysis and nitrification) and therefore other soil chemical properties. It is, however, clear that the long-term effect of surface applications of poultry manure is generally to ameliorate subsoil acidity by raising subsoil pH and lowering exchangeable Al concentrations. / Thesis (M.Sc.)-University of Natal, Pietermaritzburg, 2001.

No description available.

Many studies have been undertaken to determine the effects of soil and soil properties on migrating metal pollutants. Organic pollutants, however, in addition to their interactions with soil components , are also susceptible to degradation (catabolism) by microorganisms. Soil-microorganism-pollutant interactions have, traditionally, been studied in soil columns (microcosms). One of the shortcomings of column and in situ studies is that the identity and specific effect(s) of the soil component(s) affecting or influencing attenuation are not known and cannot readily be determined. Attenuation effects of the soil components are, therefore, difficult to interpret. ("Attenuation" in this context is the combined effects of both soil adsorption and microbial catabolism). Attenuation studies often only consider the physical conditions such as aeration, permeability, flow rate, temperature, etc. This approach assumes the soil to be a homogeneous matrix with no specific physico-chemical properties attributable to different components within the matrix. Soil physical factors suspected of influencing pollutant attenuation could be misleading without consideration of the physico-chemical interactions between soil components, microorganisms and pollutants. Adhesion of pollutants and microorganisms seems to be most important in this regard. The initial phase of this study was undertaken to examine the effects of three different soil materials on attenuation of key landfill leachate molecules. Examination of the effects of soil surface type on attenuation focused on adsorption / desorption of the pollutant molecules and microorganisms. These experiments sought to investigate the physico-chemical effects of soil, microorganism, pollutant interactions and were done as batch slurry experiments as well as in soil columns. Two soil horizons from the Inanda soil form (humic A and red apedal B) and the topsoil (vertic A) from a Rensburg soil form were used. The Inanda topsoil had a high organic matter content and both the topsoil and subsoil had a kaolinitic clay mineralogy; the Rensburg topsoil clay mineralogy was predominantly smectitic with a relatively low organic matter content. From the batch experiments, the adsorption of a hydrophobic molecule (naphthalene) and a heavy metal (cadmium) were found to be influenced to a significant extent by soil characteristics. Adsorption of naphthalene was due to the soil organic matter (SOM) content whereas cadmium adsorption was due to the cation exchange capacity (CEC) of the soil. Soil characteristics did not seem to have a significant influence on the adsorption of a water soluble compound such as phenol at the concentrations used. Attenuation of naphthalene was found to be affected by adsorption of the pollutant molecule (related to SOM) as well as the CEC of the soil. The attenuation of hydrophobic molecules can possibly be ascribed to the influence of CEC on the microbial population responsible for attenuation. This would seem to indicate interaction between the soil surfaces and the catabolizing microbial population. Desorption of the pollutant (and possibly also of the microbial population) was achieved by the addition of acetonitrile and methanol both of which reduced the polarity of the water. These solvents were also found to be toxic to the catabolizing microbial population at high concentrations. The toxicity thresholds of both solvents for catabolizing microorganisms differed significantly between soil- (> 15 %, v/v) and soil free (< 5 %, v/v) treatments. This discrepancy cannot be accounted for by adsorption and is ascribed to physico-chemical interaction between microorganisms and the soil surfaces. This interaction probably affords protection from, otherwise, toxic concentrations of solvents or metals. The important effects of soil surfaces on attenuation processes were thought to be due to the strong adsorption of naphthalene. Surface attachment of microorganisms was, however, also inferred from results obtained with phenol. This seemed to indicate that microbial attachment to soil surfaces was an important aspect in attenuation and did not occur only because of pollutant adsorption. Soil column experiments were made with both naphthalene and phenol. The naphthalene, which was adsorbed to the soil, did not leach from the columns to any appreciable extent. This was despite the addition of acetonitrile to some columns. This was probably due to greater microbial catabolism caused by desorption and, subsequent, increased soluble concentrations of the molecule. After extraction from the soil at the end of the experiment it was clear that the sterile controls held much higher concentrations of naphthalene than the experimental columns. The soil type and treatments showed little difference in the naphthalen concentration extracted from the soil columns. This did not reflect the differences found between soil materials in the batch experiments and was probably due to the masking effect of the soil physical factors on attenuation processes. Unlike naphthalene, phenol, because of its high solubility, was detected in the column leachates at relatively high concentrations. The phenol concentrations were much higher for the Inanda subsoil (approximately 4 mM) than the Inanda topsoil (approximately 2 mM) and Rensburg topsoil (< 1 mM). The Rensburg topsoil produced the lowest phenol concentrations in the leachate and this can probably be ascribed to the larger quantity of micropores in this soil. Thus, it seems that the soil physical features had a pronounced influence on attenuation. Whether this effect was directly on the studied molecule or indirectly, because of the effects on the microbial population, is not known. Inoculation of the columns with a phenol catabolizing population had only a slight increased effect on leachate phenol concentrations from all columns. This increased effect was, however, only prolonged in the case of the Inanda subsoil. The flow rate through the columns affected leachate phenol concentration which was lower with a slower flow rate and, thus, longer retention time. From the column experiments soil physical parameters were suspected of influencing, and possibly overriding, the soil surface effects on microbial activity (capacity to catabolize a organic molecule of interest). Soil porosity, as caused by different soil materials, was suspected of being the most important soil physical parameter influencing microbial activity. To investigate the potential effect of soil porosity, relatively homogeneous porous media i.e. chromatography packing material and acid washed sand were used. These materials had more defined and distinct porosities and were considered to be suitable for investigating the fundamental influence of porosity on microbial activity. Saturated continuous flow columns were used and three types of packing configurations were tested: chromatography packing (CHROM) material (porous particles); acid washed sand (non-porous) (AWS); and a 1: 1 (w/w) mixture of chromatography packing and acid washed sand (MIX). Only a single water soluble molecule, phenol, was used in this phase of the investigation. Bacterial filtration ("filtration" as a component of "attenuation'') was found to be highest for the CHROM and lowest for the AWS materials. This difference in microbial retention affected the phenol catabolism in response to increased column dilution rates. The CHROM and MIX materials had distinctly different porosities than that of the AWS, due to the internal porosity of the chromatography packing. This greater pore size distribution in the MIX and CHROM packing materials created pores with different effective pore dilution rates within the microcosms at similar overall flow rates. The greater pore size distribution in the MIX and CHROM packing materials facilitated pore colonization since some pores did not participate, or conduct, mass flow as occurred in macropores. This led to different microcolonization effects in the macro- vs micropores. Since the MIX and CHROM packing materials had more micropore colonization sites these packing materials showed a greater range of substrate affinities (i.e. Ks values) for the phenol substrate. The extent to which micropore colonization occurred could be detected by the effect it had on phenol breakthrough curves. In the MIX and CHROM materials, microbial colonization caused blocking of micropores with a subsequent effect on the phenol breakthrough curves. The AWS material, however, which had a low inherent microporosity, showed microbially induced microporosity probably due to biofilm development. The fact that the MIX and CHROM packing materials facilitated micropore colonization was also responsible for the greater resistance to, and the recovery from , potentially inhibitory cadmium concentrations. This effect was also apparent in the presence of acetonitrile, although this effect was not identical to that observed with cadmium. Finally, column pressure build up as a function of pore clogging was determined and was found to occur in the order AWS > MIX > CHROM. This was most likely due to fewer potential liquid flow paths with a higher blocking potential in the AWS. Extrapolation of the fundamentals of the above findings led to the conclusion that soil surface- and soil porosity effects are extremely important factors in determining the behavior of soils as bioreactors. / Thesis (Ph.D.)-University of Natal, Pietermaritzburg, 1995.

Biological soil inoculants are products that contain beneficial microorganisms with the ability to increase plant-available nutrients. Soil inoculants are claimed to serve as a supplement for fertilizer N, improve germination and tilth, improve root systems, and increase crop quality and yield. The inoculant evaluated in this study was Effective Microorganisms (EM) produced by Nature Farm Foundation of Lompoc, California. A field trial with corn (Zea mays, L.) was conducted at Oakwood Organic Farm in East Central Indiana in 1992. Two soil types were used in the study, a Genesee silt loam (Fluventic Eutorchrept) and a Sloan silt loam (Fluventic Haplaquoll). Soil nitrate level measured through the growing season was not significantly affected by the addition of EM. Neither foliar nutrient content nor grain dry matter yield were significantly greater with use of EM compared to the control. / Department of Natural Resources

The purpose of this study was to determinate what requirements there should be on refilling material used as soil remediation based on the soil environment, i.e. soil processes and factors important to soil-dwelling organisms. The study was conducted by investigating which parameters that is important for the soil environment and by comparing them with each other. To exemplify how the parameters may change in different locations, data for total organic carbon, dry matter (i.e. water content), and pH were analyzed from different locations before and after soil remediation. Dry matter, organic matter, pH, compaction, grain size, porosity and soil composition were found to have a significant impact on various soil processes and soil organisms. Field investigations were made to examine dry- and organic matter and pH. The results were indicating that dry matter increased and that the organic matter decreased when the area was refilled with a coarse material. This study showed that there should be requirements on the characteristics of refilling material such as; organic matter content, good water holding capacity, a pH that is as neutral as possible and that the soil should not be too compact. A conclusion from this study was that crushed rock may not be the optimal refilling material after soil remediation.

The quantitative effects of increasing the organic matter contents of three soils upon their susceptibility to compaction, the recovery of tilth after compaction and the fertility of the soils were investigated. These effects were further studied on the production of bush bean (Phaseolus vulgaris). / Soil consistency limits, soil water status, applied pressure and organic matter contents were used to predict shear strength, penetration resistance and water retention characteristics of compacted soils, with the aim of meeting the widespread demand for possible techniques of soil compaction prediction. / Soil compaction increased the ability of the soils to retain moisture, increased penetration resistance, shear strength and decreased the available water capacity of soils. On the other hand, organic matter increased the ability of the soils to retain moisture, expanded the available water capacity and decreased the penetration resistance and shear strength of compacted soils. / Although soil compaction increased the stem diameter of bush bean; the height, yields and root dry matter of the crop decreased with higher compaction levels. On the contrary, higher organic matter levels increased the plant and yield parameters of the crop.

Soil erosion has been recognised as a global threat against the sustainability of natural ecosystem. The work in this thesis has been undertaken to assist in combating this threat, and addresses the soil erosion issues associated with urban construction activities. The Revised Universal Soil Loss Equation (RUSLE) was employed in this research work and the parameters associated with the model were calibrated. This model was chosen for calibration, as it has been proven to be an easy to use tool yet providing reasonable results. Large scale rainfall simulators developed at UWS were used for rainfall simulation at two sites with diverse soil types: dispersive clayey soils at Penrith and highly permeable sandy soil at Somersby (Both in New South Wales, Australia). It is concluded that RUSLE can be successfully used in single storms for erosion prediction. Calibrated values of RUSLE parameters are useful in predicting soil erosion from the construction sites in NSW. It is also identified that in rolled smooth land condition, clayey soils are more erodible than sandy soil. Specific support practices such as short grass strips, gravel bags and silt fences are identified as very effective erosion control measures in reducing soil erosion from 45% to 85%. These results will be very useful in soil erosion prediction planning and conservation management in NSW. / Master of Engineering (Hons)

Thesis (Ph. D.)--University of Missouri--Rolla, 2007. / Vita. The entire thesis text is included in file. Title from title screen of thesis/dissertation PDF file (viewed March 24, 2008) Includes bibliographical references (p. 145-155).

Thesis (Ph.D.) -- University of Adelaide, Dept. of Agronomy and Farming Systems, 2002. / "September 2001" Includes bibliographical references (leaves 206-230).

Thesis (Ph.D.)--University of Western Australia, 2006.