Includes bibliographical references. / 1 v. : / Title page, contents and abstract only. The complete thesis in print form is available from the University Library. / This thesis investigates the nature and origins of minerals of a group known as layer (sheet) silicates or phyllosilicates. It consists of a collection of research papers grouped into 3 categories: modulated layer silicates, clay silicates and the weathering of rocks and minerals, including the formation of clay minerals. Central to the research has been the use of X-ray diffraction (XRD) and high resolution transmission electron microscopy (HRTEM). All three research categories were carried out simultaneously. / Thesis (D.Sc.)--University of Adelaide, Dept. of Geology and Geophysics, 1999

A study has been carried out on the Becher and Summit Processes with the aim of understanding the mechanism and critical parameters required for the production of a range of pure iron oxide pigments, as well as high quality synthetic rutile from reduced ilmenite . The Becher Process currently produces a large quantity of worthless mixed phase iron oxides. However, this study has shown that the range of iron oxides formed are all derived from the transformation of lepidocrocite (y-FeOOH) through the solution phase in iron(II) solutions. The results of a kinetic study of the transformation of lepidocrocite found that the rate exhibited an induction period at low pH, was dependent on temperature and was linearly related to log [H+] and log [Fe2+]. The rate determining step was found to be the formation of suitable product nuclei, following dissolution of the initial oxide at the surface of the crystal lattice. An electrochemical study of these reactions showed that the product formed from the transformation of lepidocrocite was a function of the solution potential and an experimental Eh-pH diagram was constructed to predict the iron oxide phase produced from hydrolysis and transformation reactions. The results from this fundamental study were then applied on both a laboratory and plant scale to produce pure iron oxide phases. A modified Summit Process, involving the removal of metallic iron from the porous reduced ilmenite matrix using FeCl 3, regeneration of iron(III) and the production of pure iron oxide pigments from the waste iron(II) chloride solution, was also investigated in detail. A kinetic study of pure iron dissolution in iron(III) solutions, comparing three electrochemical techniques and a standard solution sampling method, gave consistent rate constants provided allowance was made for the reaction with the proton. The iron dissolution mechanism was found to be iron(III) diffusion controlled, while the dissolution in HC1 was under mixed control. A study using both pure iron and pressed reduced ilmenite discs found that acid consumption could be minimised by the addition of citrate or by the addition of A1 3+ or Fe 2+ , which are believed to block the adsorption of the proton. It was found that iron(III)-citrate complexes inhibited iron(II1) hydrolysis in the reduced ilmenite pores and enhanced the purity of the synthetic rutile product. A study of the oxidation of iron(II) by atmospheric oxygen using copper(II) and activated carbon catalysts found that these catalysts were inefficient for complete iron(III) regeneration. The heating of carbon in the presence of cu2+ was found to enhance the initial rate of iron(II) oxidation, however it is believed that surface oxide redox couples formed on the carbon control the iron(II)/ iron(III) ratio in solution, and prevent complete iron(I1) oxidation. The production of iron oxide pigments under the controlled conditions afforded by the Summit Process, resulted in superior quality pigments than are presently attainable from the Becher Process. However, controlled ageing and crystal growth using waste lepidocrocite from the Becher Process would result in similar quality pigments being produced.

Thesis (M.Sc.) --University of Adelaide, 1958.

Thesis (M.S.)--University of Missouri, School of Mines and Metallurgy, 1912. / The entire thesis text is included in file. Typescript. Illustrated by author. Title from title screen of thesis/dissertation PDF file (viewed April 20, 2009) Includes bibliographical references.

Thesis (Ph. D.)--Open University. BLDSC no. DX227301.

Thesis (doctoral)--University of Tartu, 1998. / Includes bibliographical references.

Thesis (Master)--İzmir Institute of Technology,İzmir, 2005 / Includes bibliographical references (leaves. 84-89).

Thesis (Ph. D.)--University of Wisconsin--Madison, 1940. / Typescript. Vita. eContent provider-neutral record in process. Description based on print version record. Includes bibliographical references (leaves 68-73).

Thesis (Ph. D.)--University of Washington, 2002. / Vita. Includes bibliographical references (p. 72-78).

Thesis (M.Sc.)--Memorial University of Newfoundland, 1991. / Typescript. Bibliography: leaves 227-239. Also available online.