No description available.

Volcanogenic massive sulphide (VMS) deposits have a characteristic geochemical suite of enriched metals, mineralization and related hydrothermal alteration minerals; however, very little research has been carried out to determine which of these minerals may be useful for exploration in glaciated terrains and there are very few case studies in the public realm that document down-ice dispersal of these from known volcanogenic massive sulphide (VMS) deposits. In response to these needs and to refine and optimize surficial exploration methods in northern Canada, this study was conducted to examine the mineralogical signature of the Izok Lake Zn-Cu-Pb-Ag VMS deposit, Nunavut and its glacial till dispersal. Glacial sediments were deposited in the Izok Lake region by the Laurentide Ice Sheet. Detailed ice flow mapping indicates four stages of ice flow (oldest to youngest): 1) southwest (255 ̊); 2) weak flow to the northwest (315 ̊); a dominant ice flow and landform trend to the west-northwest (292 ̊), and 4) northwest (318 ̊) that was only observed east of the Iznogoudh Lake area (Hicken et al., 2011). The till geochemical signature (aqua regia digestion ICP-MS analysis) for the <0.063 mm fraction of the till matrix is defined by elevated (above the 95th percentile) contents of Zn, Cu, Pb, Fe, Ag, Cd, Bi, Hg, Se, In and Tl. These element signatures in till can be detected up to 8 km down-ice from the deposit. Till geochemical data is used to evaluate which till samples are metal-rich and may contain indicator minerals. Indicator minerals for the amphibolite metamorphic grade Izok Lake VMS deposit includes: gahnite, staurolite, axinite, chalcopyrite, sphalerite and pyrite. Sulphide minerals are present at lower abundances than gahnite and staurolite as they are not physically and chemically as robust/resistant during postglacial weathering. Gahnite is the most useful VMS indicator mineral in the postglaciated Izok Lake area, as it was readily identified in till heavy mineral concentrates, it is abundant (100 of grains), its chemically stable in the surficial weathering environment, and can be detected up to 40 km down-ice. This study is one of the first to document indicator minerals down-ice from a VMS deposit in a postglaciated terrain. / Thesis (Master, Geological Sciences & Geological Engineering) -- Queen's University, 2012-01-31 18:24:19.909

No description available.

Rutile, although not a major component of detrital heavy mineral deposits, is a valuable source of titanium oxide. Theoretically rutile is pure titanium dioxide (TiO2) and should form white or colourless tetragonal crystals with a density of 4.25gm/ml. However, natural rutile although tetragonal, displays a variety of colours ranging from red through brown to black, yellow or blue, variable density between 4.23 to 5.50g/ml as well as a range in the magnetic susceptibility and electrical conductivity. In addition to these variations exhibited by natural rutile, samples from detrital heavy mineral deposits normally contain, in addition to homogenous grains, composite grains, in which rutile is intergrown with one or more mineral species, commonly quartz, feldspar and ilmenite. The Sibaya Formation, like most detrital heavy mineral deposits, has a polymictic source, and as such contains rutile grains formed in many different chemical environments. Homogenous rutile grains display a chemical variation with a preference for the select few elements, which are compatible with the rutile cyrstallographic structure. The ions that substitute for titanium (Ti4+) in the crystal lattice are a reflection of chemical environment in which the crystal formed. The size and charge of the Ti4 + ion greatly restricts the species that may enter the rutile crystal lattice, with Sb3 +, V3 +, Fe3 +, Cr3 +, Sn4 +, M04+, W4+, Mn4+, 8i5+, Nb5+, Ta5 +, Sb5 +, V5 +, being theoretically compatible with the size and charge of the Ti4+ ion. Electron microprobe analysis of detrital rutile grains from the Sibaya Formation, KwaZulu-Natal show that elements, Nb5 +, Ta5+, A13+, Zr4+, Si4+, Fe3+, Cr3 +, and V5 +, commonly substitute for the Ti4 + ion. However, Sb3+, Sn4+, M04+, W4 + and 8i5 + were not present at detectable levels implying that the provenance area is not enriched in these elements. Although the high Fe3+ values were expected in the rutile grains, as Fe3 + is common in many rocks, the high Si4+ values encountered were not expected, as Si4 + is not normally compatible with Ti4 + ion, as noted by their distinct separation in rutilated quartz. The anomalous Si4 + content of certain grains suggests that within the provenance area rutile bearing rocks formed under unusual conditions, such as high pressure, temperature and silicon activity where the high charge density of the Si4 + ion would favour the inclusion of Si4 + into the rutile lattice. The chemical variation of the rutile grains causes significant variation in the magnetic susceptibility and electrical conductivity, and thus has marked effects on mineral processing, which relies heavily on magnetic and electrostatic separation techniques. The data presented indicates that individual homogenous rutile grains displays significant range of chemical composition, commonly containing other oxides from a fraction of a weight percent to well over 10wt%. Data plots of TiO2, FeO and 'other' oxides (Nb2O5, Ta2O5, A12O3, ZrO2, SiO2, Cr2O3 and V2O3), showed that many of the more magnetic rutile grains appeared to be FeO enriched and contained a higher proportion of 'other' oxides. However, some grains that just had higher proportions of 'other' oxides and a lower FeO content were also magnetic. Thus magnetic susceptibility although strongly influenced by the presence of FeO, can also be enhanced by the substitutions of other oxides. The vast majority of rutile grains from the electrostatic fractions were relatively TiO2 pure, and contained low concentrations of 'other' oxides. However, some grains did have slightly enhanced SiO2 and V2O3 concentrations, which appear to enhance the conductivity of the grains. Four main colour groups were differentiated from the population of rutile grains from the Sibaya Formation, these being, reddish brown, black, blue and yellow. No single oxide seemed solely responsible for the colour of rutile grains. However, the red rutile grains had a slightly but significantly higher Cr2O3 and Nb2O5 content, whereas black rutile grains appeared to be V2O3 and Nb2O5 enriched. The blue colour of rutile grains appears to be influenced by a combination of SiO2, Al2O3 and Nb2O5 substitutions. The yellow rutile grains had slightly enhanced FeO and Nb2O5 concentrations. Although these differences are very small, trace quantities of certain elements and different combinations of elements can have a strong effect on colour. Apart from Fe3+, no single element; appears to be solely responsible for variations noted in the physical characteristics (magnetic susceptibility, electrostatic conductivity and colour) of homogenous rutile grains from the Sibaya Formation. However a combination of substituting elements appears to influence magnetic susceptibility and electrical conductivity. An enhanced Fe3+ content normally increases the magnetic susceptibility although combinations of other elements may have the same effect on Fe3+ poor grains. In general terms, the purer the rutile grain, the more likely it is, to be non-magnetic and conductive. Substitutions of 'other' oxides appear to decrease the conductivity of rutile grains. The relationship between grain colour and chemistry is also not very clear, verifying the widely held view that grain colour is often the result of more than just mineral chemistry. / Thesis (M.Sc.)-University of Durban-Westville, 2002.

No description available.

All the warm deserts of the world exhibit gypsum crusts in favourable localities, generally areas with a source of gypsum and less than 250 mm of rainfall annually. The features, comprising loose powdery or cemented crystalline accumulations of calcium sulphate dihydrate, are found at the surface or within the uppermost 10 m of regolith. Thicknesses vary from a few millimetres to several metres and purities range from about 15% to nearly 100% gypsum. A review of the literature on gypsum soils and crusts reveals that the classification of types requires both standardizing and simplifying. A preliminary classification of crusts into three types can be made on the basis of structural and stratigraphic characteristics of examples from southern Tunisia and the Central Namib Desert. The types consist of subaerial aqueous evaporites, two subsurface and three surface forms. Detailed physical and chemical analyses justify a broadly similar genetic classification though one subsurface form is believed to be a primary pedogenic type of which the surface forms represent relics at various stages of solutional deterioration. Examples of subaerial aqueous evaporites are all products of shallow-water sedimentation in seasonally flooded chotts and sabkhas. The non-pedogenic subsurface type, croûte de nappe, is produced by displacive crystallization at the surface of a fluctuating water table. Gypsum precipitation results from either evaporation or mixing of saline waters causing saturation with respect to gypsum. Surface gypsum crusts are subsurface illuvial accretions exposed by erosion of overlying material. The gypsum is derived from solution of surface aeolian, atmospheric, colluvial or alluvial deposits by meteoric waters which percolate into the upper soil zone replenishing the antecedent soil moisture deficit. Subsurface accumulation results from displacive crystallization at host sediment grain contacts when gypsum saturated soil moisture evaporates.

Typescript. / Thesis (Ph. D.)--University of Hawaii at Manoa, 1984. / Bibliography: leaves 219-236. / Microfiche. / xviii, 236 leaves, bound ill. 29 cm

In this study the unique Magotteaux Mill® system was used to control the grinding chemical conditions, which may be adjusted by varying grinding media, purging gas and pH, during grinding. An electrochemical apparatus was used to investigate oxidation-reduction behaviour of grinding media and sulphide mineral electrodes, as well as their galvanic interaction in-situ of the Magotteaux Mill®. Galvanic interaction between the grinding media (mild steel, 15% chromium, 21% chromium and 30% chromium media) and the sulphide minerals (bornite, arsenopyrite and pyrite) was initially quantified in-situ of the mill by electrochemical techniques under different grinding atmospheres (nitrogen, air and oxygen). An innovative mathematical theoretical model was developed to describe the effect of galvanic interaction on oxidation rates of the grinding media during grinding, which was verified by the experimental data. Galvanic interaction enhanced the oxidation of the grinding media and produced more oxidized iron species in the mill discharge. It was observed that oxidized iron species (EDTA extractable iron) was linear with galvanic current between the grinding media and the sulphide minerals, in agreement with the prediction of the theoretical model. The effect of grinding conditions on pulp chemistry, surface properties and floatability was investigated by the measurement of dissolved oxygen (DO), pH, pulp potential (Eh), ethylene diamine-tetra acetic acid (EDTA) extraction, X-ray photoelectron spectroscopy (XPS) and floatation recovery. / Thesis (PhDAppliedScience)--University of South Australia, 2005.

No description available.

The chemistry during regrinding is critical to flotation. It has significant effects on mineral surface properties and can lead to different mineral floatabilities. This research seeks to quantify contributing factors to changes in mineral flotation behavior with grinding and regrinding. The influence of the particle breakage mechanism on mineral floatability is also investigated. In this research, sulphide mineral surface species and hydrophobicity were analyzed by a range of techniques, including X-ray photoelectron spectroscopy (XPS), surface area measurement (BET), ethylene diamine-tetra acid (EDTA) extraction and contact angle measurements. / Thesis (PhD)--University of South Australia, 2010