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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
1

Estudo do efeito do ?xido de b?rio no comportamento de massas para porcelanato

Cavalcanti, Daniel Jatoba de Holanda 23 February 2012 (has links)
Made available in DSpace on 2014-12-17T14:57:52Z (GMT). No. of bitstreams: 1 DanielJHC_TESE.pdf: 5059546 bytes, checksum: d026fcca3b608eb8f8318d620f8e0f29 (MD5) Previous issue date: 2012-02-23 / In this work, it is proposed the study of the effect of barium oxide acting as synthetic flow in the behavior of masses for stoneware from the use of raw materials found in the deposits of minerals of the Rio Grande do Norte that it makes use of a great natural potential for the industrialization of the product. The porcelanato is a sophisticated product with excellent final properties being applied as ceramic coating in buildings of high standard of engineering. The raw materials selected for the development of the study had been two types of argilas, two types of feldspatos, dolomita, talco, barium carbonate and silica, being characterized by X-ray fluorescence, X-ray diffraction, granulometric analysis, dilatometric analysis and thermal analysis. Thus, it is intended to define four formulations using the cited raw materials that will be processed, conformed and sintered in the temperatures of 1150 ?C, 1175 ?C, 1200 ?C, 1225 ?C e 1250 ?C. From the physical characterizations, chemical and morphologic of the formed formulations, the effect of barium oxide is determined in the physical and mechanical properties of the studied system carrying water absorption tests, linear retraction, apparent porosity, apparent specific mass, compacting curve, flexural strength and microstructural analysis by XRD and SEM. After analyzing the results, indicated that barium oxide acts as a flux of high temperature and as the ordering of structure, where the embedded glass phase has the nucleating effect phase potassium silico-aluminum reacting with free silica which together with the high content of potassium concentrated form a new crystalline phase called microcline. The masses studied with the addition of barium oxide present physical-mechanical properties highly satisfactory in reduced firing temperatures, which implies a saving in energy given off in the production and increased productivity / Neste trabalho, prop?e-se o estudo do efeito do ?xido de b?rio atuando como fluxo sint?tico no comportamento de massas para porcelanato a partir da utiliza??o de mat?rias-primas encontradas no estado do Rio Grande do Norte que disp?e de um grande potencial natural para industrializa??o do produto. O porcelanato ? um produto com excelentes propriedades finais, sendo aplicado como revestimento cer?mico em diversos empreendimentos da constru??o civil. As mat?rias-primas selecionadas para o desenvolvimento do estudo foram dois tipos de argilas, dois tipos de feldspatos, dolomita, talco, carbonato de b?rio e s?lica, sendo caracterizadas por an?lises de fluoresc?ncia de raios X, difra??o de raios X, an?lise granulom?trica e an?lises t?rmicas. Assim sendo, procede-se o processamento, conforma??o e sinteriza??o de quatro formula??es utilizando as mat?rias-primas citadas nas temperaturas de 1150 ?C, 1175 ?C, 1200 ?C, 1225 ?C e 1250 ?C. A partir das caracteriza??es f?sicas, qu?micas e morfol?gicas das formula??es, determina-se o efeito do ?xido de b?rio nas propriedades f?sicas e mec?nicas do sistema estudado realizando ensaios de absor??o de ?gua, retra??o linear, porosidade aparente, massa espec?fica aparente, curva de compacta??o, tens?o de ruptura a flex?o, difra??o de raios X e microscopia eletr?nica de varredura com a microan?lise por EDS. Ap?s a an?lise dos resultados, verifica-se que o ?xido de b?rio atua como fundente de alta temperatura e como ordenador de estrutura, onde incorporado ? fase v?trea, possui efeito nucleante da fase sil?cio-alum?nio-pot?ssio reagindo com a s?lica livre que juntamente com o alto teor de pot?ssio concentrado forma uma nova fase cristalina denominada microcl?nio. As massas estudadas com o acr?scimo do ?xido de b?rio apresentam propriedades f?sico-mec?nicas extremamente satisfat?rias em temperaturas de queima reduzidas, o que implica em uma economia na energia desprendida para a produ??o e aumento de produtividade / 2020-01-01

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