No description available.

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Refractory materials must, in their everyday environment, withstand high stress levels which are a result of mechanical and thermal loadings. Any failure which results from these applied stresses can have serious financial and human consequences and therefore should be avoided. One key aspect to understanding the thermal shock behaviour of refractories is the mechanical behaviour at low temperatures. In this thesis the mechanical behaviour of a small range of multiphase refractories is explored. In particular the stress-strain response and its influence on the fracture behaviour is investigated. Experiments, performed on magnesia and magnesia spinel composites, indicate that non-linear stress-strain behaviour accompanied by permanent deformation upon unloading is a result of the release of microscale residual stresses by microcracking. A micromechanical constitutive model combining these features was developed using linear elastic composite theory and isotropic continuum damage mechanics. This non-linear stress-strain behaviour also gives rise to increasing toughness as crack propagation occurs. This increase in toughness results from an expansion which occurs when microscale residual stresses in front of the crack tip are relaxed by microcracking. A micromechanical model has been developed based upon the specifically developed constitutive model and previous work on transformation toughening. These models are capable not only of simulating experimental results, but can also indicate the microstructures which are most likely to exhibit extensive non-linear stress-strain behaviour and strongly rising toughness curves.

Thesis (Ph.D.)--University of Wollongong, 2004. / Typescript. Includes bibliographical references: leaf 192-205.

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In the continuous casting of steels, clogging of the submerged entry nozzle has long been a persistent and costly issue. Previous modelling attempts have assumed that inclusions of different types exhibit the same degree of adhesion when colliding with the nozzle wall - an assumption not borne out by evidence in the literature. In this thesis, a dynamic clogging model is proposed which accounts for the effects of different degrees of inclusion-wall and inclusion-clog adhesion on clog formation and growth. The overall clogging model consists of several sub-models in order to account for the different physics. The melt flow and inclusion motion are modelled using an Eulerian-Lagrangian approach. The inclusion adhesion behavior is determined by the use of a stochastic model activated when an inclusion collides with a surface. A user defined sticking probability is used to determine if an inclusion sticks to a surface (Swall for wall collision or Sclog for clog collision) or instead bounces off. A macroscopic model is used to determine clog growth, where the volume of clog in a cell is tracked and used to determine when the clog grows into adjacent cells. Finally, a modified Kozeny-Carmen equation is used as a porosity model so that the presence of the clog affects and diverts the melt flow. The modified melt flow then alters subsequent inclusion deposition and clog growth. The model is used to investigate the effects of different degrees of inclusion adhesion on inclusion deposition and clog growth. Three scenarios are examined - 1) Inclusion deposition in a pilot scale nozzle, 2) Inclusion deposition in an industrial scale slide-gate controlled nozzle and 3) Clog formation and growth in a pilot scale nozzle. The deposition studies indicate that in a pilot scale nozzle, only a minority of inclusions ever collide with the nozzle (≈ 10%). In contrast, in the industrial scale nozzle there are far more inclusion collisions with the nozzle wall, ranging from 80% when the slide-gate is 20% open to 30% when the slide-gate is 100% open. Despite the differences in nozzle geometry and flow conditions, a similar effect on inclusion deposition is seen when Swall is varied. The effects of Swall can be divided into two regimes. When 0 ≥ Swall < 0.05 there is a sharp increase in the deposition ratio as Swall increases. When Swall > 0.05 there is a small and linear increase in the deposition ratio as Swall increases. This pattern is also seen in the study of clog formation and growth in a pilot scale nozzle. The effects of Swall or Sclog on clog volume can be divided into two regimes. As Swall or Sclog increases, there is a large increase in clog volume, until the sticking probability increases above 1E-2, then any further increase results in only a small increase in clog volume. In comparison to literature data the model successfully simulates the location of clog formation, the initial jump in clogging factor and the clogging factor growth rate in the later stages of clogging. However, the model underestimates the overall increase in clogging factor, resulting in a clogging factor at the end of the simulation which is half of that seen in the experiment. / Thesis / Doctor of Philosophy (PhD) / One of the ongoing challenges in the continuous casting industry is the occurrence of nozzle clogging. Over time, a buildup of material occurs within the submerged entry nozzle, called a clog. The clog leads to the partial or complete blockage of the nozzle, resulting in increased production costs. Since studying this phenomena experimentally is difficult due to the high temperature and opacity of the molten steel, modelling provides a useful alternative approach. However, previous modelling efforts regarding nozzle clogging have treated all inclusions as exhibiting the same adhesion behavior. This thesis aims to address this issue by presenting a dynamic nozzle clogging model which accounts for the effects of different degrees of inclusion adhesion. The model is used to study both inclusion deposition and clog formation. Results indicate that even a small amount of sticking probability results in a significant degree of inclusion deposition and clogging. The effect of sticking probability on clogging can be divided into two regimes, one where the clogging is very sensitive to the sticking probability and one where it is insensitive. Finally, the model was shown to run adequately even on coarser meshes (meshes with a smaller number of larger cells), indicating its utility in industrial applications, where it can be used to predict the location of clog formation and the clog growth rate.

Solidification during horizontal continuous casting of low carbon steel billets with cyclic withdrawal was simulated and the wavy profile of the solidifying shell characteristic of this process was reproduced. Effects of rate of withdrawal cycle, superheat and casting speed were determined. In order to carry out this simulation in a personal computer, efficient numerical techniques had to be developed for mesh refinement by coordinate transformation, interfaces with temperature discontinuities and re-entrant corners. A flexible means of mesh generation involving polynomials was also developed. From the transient heat transfer model finite difference equations peculiar to each gridpoint in the solution field were derived and solved by the Alternating Direction Implicit (ADI) method. Graphics software were developed to view the results with 3-D as well as contour plots. The heat transfer model was verified with published results of vertical continuous casting of Mg alloys and steel. Due to its ability to deal with interfaces, unlike previous work, the present model could solve temperature at both casting and mold simultaneously. A model for the shell growth, rupture and healing at the break-ring of horizontal continuous casting molds was incorporated into the heat transfer model. An interesting result of this simulation was the presence of transient hot spots in the hot face of the mold. Elimination of such hot spots should aid shell strength and hence the casting rate. A semi-quantitative dependence of the depth of the primary witness mark on cycle rate was also established.

No description available.

As curvas limite de conformação (CLC) são utilizadas há mais de 50 anos. Propostas inicialmente para o desenvolvimento de produtos provenientes da indústria automobilista em função das necessidades apresentadas pela área, são atualmente aplicadas de maneira geral para a indústria da estampagem na produção de inúmeros tipos de peças, oferecendo previsões de possíveis falhas e/ou defeitos durante as etapas do processo de estampagem. As CLC´s permitem prever o afinamento excessivo, enrugamento, estiramento e é claro, a fratura da peça. As diferenças metalúrgicas existentes entre os dois processos iniciais - fundição contínua (F.C.) e fundição semicontínua (F.S.C.) - resultam em diferenças nas propriedades finais obtidas para uma mesma rota de laminação a frio e recozimentos intermediários do material especificado. Desta forma, torna-se indispensável um estudo sobre a influência dos processos de fabricação iniciais F.C. e F.S.C. com relação à estampabilidade da liga, sendo esta avaliação efetuada através das CLC´s obtidas por ensaios de tração uniaxiais, propostos pelo IRSID (\"Institut de Recherches de La Sidérurgie\"), (lado esquerdo da curva ?2 < 0) e ensaio Erichsen (lado direito da curva ?2 > 0) e do ensaio de Nakazima reduzido em 60%, ou seja, todo o ferramental e os corpos de prova utilizados nos ensaios foram reduzidos em 60% das dimensões mencionadas pela norma ISSO 12004-2. A diferença microestrutural apresentada entre as etapas de fabricação dos dois processos avaliada através de ensaios de determinação do tamanho de grão, limites de resistência à tração, escoamento (0,2%), alongamento (em 50,80 mm), coeficientes de encruamento n, resistência K, ensaios de \"orelha\", levantamento da CLC0, Erichsen e textura, auxiliaram nas conclusões finais do levantamento das CLC´s para os dois processos do material acabado e metodologias. O processo de fundição semicontínua nas condições processadas apresentou melhores combinações entre as propriedades, exceto na formação de \"orelha\" apresentada na etapa intermediaria de processamento do material. Principalmente o parâmetro CLC0 no plano da chapa, resultou em uma deformação ?1 19% (?2 = 0), superior à apresentada pelo processo F.C., deformação muito importante para a fabricação de peças estampadas. Evidenciou-se também uma diferença de aproximadamente 37% entre as metodologias IRSID x Nakazima reduzido na obtenção da deformação plana para o processo F.C. e 31% para o processo de F.S.C.. Nas condições de deformação; estiramento biaxial, tração uniaxial e embutimento profundo, a chapa produzida pelo processo de fundição contínua apresenta melhor desempenho. / Forming limits curves (FLC) are used for more than 50 years. Initially proposed for the development of products from the automobile industry in terms of the needs of the area. It is currently being applied in general to the metal forming industry in the production of numerous types of parts, providing predictions of possible faults and / or defects during the stages of the stamping process. The FLC\'s can predict excessive thinning, wrinkling, stretching and of course, the fracture of the part. The existing metallurgical differences between the two initial processes - continuous casting (C.C.) and semi-continuous casting (S.C.C.) - result in differences in the final properties obtained for the same route of cold rolling and intermediate annealing of the specified material. Thus, it is essential to study the influence of the initial manufacturing processes CC and SCC with respect to the formability of the sheets. This investigation is based on the, assessment of the FLC\'s obtained by uniaxial tensile tests proposed by IRSID (\"Institut de Recherches de Sidérurgie\"), (?2 < 0, left side of the curve) and Erichsen test (right side of curve. ?2> 0) and the Nakazima test reduced by 60%. The difference between the sheets obtained in both processing routes was evaluated by the following parameters: grain size, tensile strength limits, yield strength (0.2%), elongation (at 50.80 mm), strain hardening coefficient n, resistance K, \"earing\" test, lifting of the CLC0, Erichsen test and texture where discussed in view of the obtained FLC\'s for both the two processes of the finished material. The semi-continuous casting process in processed conditions showed better combinations of properties except the formation of \"earing\" presented at the intermediate stage of processing of the material. Particularly the evaluation of the FLC0 parameter resulted in a strain in the plate plane ?1 19% (?2 = 0) superior to the sheet obtained by the continuous casting process. A difference of approximately 37% between the IRSID x Nakazima methodologies was also reduced in obtaining the flat deformation for the F.C. process and 31% for the F.S.C. process. However, for other deformation paths; biaxial stretching, uniaxial traction and deep drawing of the results for the continuous casting sheet were superior.

As curvas limite de conformação (CLC) são utilizadas há mais de 50 anos. Propostas inicialmente para o desenvolvimento de produtos provenientes da indústria automobilista em função das necessidades apresentadas pela área, são atualmente aplicadas de maneira geral para a indústria da estampagem na produção de inúmeros tipos de peças, oferecendo previsões de possíveis falhas e/ou defeitos durante as etapas do processo de estampagem. As CLC´s permitem prever o afinamento excessivo, enrugamento, estiramento e é claro, a fratura da peça. As diferenças metalúrgicas existentes entre os dois processos iniciais - fundição contínua (F.C.) e fundição semicontínua (F.S.C.) - resultam em diferenças nas propriedades finais obtidas para uma mesma rota de laminação a frio e recozimentos intermediários do material especificado. Desta forma, torna-se indispensável um estudo sobre a influência dos processos de fabricação iniciais F.C. e F.S.C. com relação à estampabilidade da liga, sendo esta avaliação efetuada através das CLC´s obtidas por ensaios de tração uniaxiais, propostos pelo IRSID (\"Institut de Recherches de La Sidérurgie\"), (lado esquerdo da curva ?2 < 0) e ensaio Erichsen (lado direito da curva ?2 > 0) e do ensaio de Nakazima reduzido em 60%, ou seja, todo o ferramental e os corpos de prova utilizados nos ensaios foram reduzidos em 60% das dimensões mencionadas pela norma ISSO 12004-2. A diferença microestrutural apresentada entre as etapas de fabricação dos dois processos avaliada através de ensaios de determinação do tamanho de grão, limites de resistência à tração, escoamento (0,2%), alongamento (em 50,80 mm), coeficientes de encruamento n, resistência K, ensaios de \"orelha\", levantamento da CLC0, Erichsen e textura, auxiliaram nas conclusões finais do levantamento das CLC´s para os dois processos do material acabado e metodologias. O processo de fundição semicontínua nas condições processadas apresentou melhores combinações entre as propriedades, exceto na formação de \"orelha\" apresentada na etapa intermediaria de processamento do material. Principalmente o parâmetro CLC0 no plano da chapa, resultou em uma deformação ?1 19% (?2 = 0), superior à apresentada pelo processo F.C., deformação muito importante para a fabricação de peças estampadas. Evidenciou-se também uma diferença de aproximadamente 37% entre as metodologias IRSID x Nakazima reduzido na obtenção da deformação plana para o processo F.C. e 31% para o processo de F.S.C.. Nas condições de deformação; estiramento biaxial, tração uniaxial e embutimento profundo, a chapa produzida pelo processo de fundição contínua apresenta melhor desempenho. / Forming limits curves (FLC) are used for more than 50 years. Initially proposed for the development of products from the automobile industry in terms of the needs of the area. It is currently being applied in general to the metal forming industry in the production of numerous types of parts, providing predictions of possible faults and / or defects during the stages of the stamping process. The FLC\'s can predict excessive thinning, wrinkling, stretching and of course, the fracture of the part. The existing metallurgical differences between the two initial processes - continuous casting (C.C.) and semi-continuous casting (S.C.C.) - result in differences in the final properties obtained for the same route of cold rolling and intermediate annealing of the specified material. Thus, it is essential to study the influence of the initial manufacturing processes CC and SCC with respect to the formability of the sheets. This investigation is based on the, assessment of the FLC\'s obtained by uniaxial tensile tests proposed by IRSID (\"Institut de Recherches de Sidérurgie\"), (?2 < 0, left side of the curve) and Erichsen test (right side of curve. ?2> 0) and the Nakazima test reduced by 60%. The difference between the sheets obtained in both processing routes was evaluated by the following parameters: grain size, tensile strength limits, yield strength (0.2%), elongation (at 50.80 mm), strain hardening coefficient n, resistance K, \"earing\" test, lifting of the CLC0, Erichsen test and texture where discussed in view of the obtained FLC\'s for both the two processes of the finished material. The semi-continuous casting process in processed conditions showed better combinations of properties except the formation of \"earing\" presented at the intermediate stage of processing of the material. Particularly the evaluation of the FLC0 parameter resulted in a strain in the plate plane ?1 19% (?2 = 0) superior to the sheet obtained by the continuous casting process. A difference of approximately 37% between the IRSID x Nakazima methodologies was also reduced in obtaining the flat deformation for the F.C. process and 31% for the F.S.C. process. However, for other deformation paths; biaxial stretching, uniaxial traction and deep drawing of the results for the continuous casting sheet were superior.