To investigate the tropical Atlantic response to the remote El Nino-Southern Oscillation (ENSO) forcing, a Reduced Physics – Coupled Global Circulation Model (RP-CGCM) is developed, and four experiments are carried out. The results show that the RP-CGCM is capable of capturing the major features of Tropical Atlantic Variability (TAV) and its response to ENSO forcing. The SST response to the remote influence of ENSO may be divided into two stages. In stage one, the ENSO influences the tropical Atlantic SST primarily through the Troposphere Temperature (TT) mechanism, which predicts a uniform warming in the tropical Atlantic following the mature phase of El Nino. In the north tropical Atlantic (NTA), the Walker mechanism and the Pacific-North-American (PNA) mechanism work in concert with the TT-induced warming, giving rise to a robust SST response during the boreal spring in this region. In the south tropical Atlantic (STA), the southeasterly wind anomaly and increased stratus clouds work against the TT-induced warming, resulting in a much weaker SST response in this region. At this stage, the response can be largely explained by the ocean mixed layer response to changes in surface heat fluxes induced by ENSO. In stage two, ocean dynamics play a more active role in determining the evolution of SST. The cross-equatorial wind anomaly in the western to central equatorial Atlantic can change the SST in the eastern equatorial Atlantic through Bjerknes feedback and the SST in the central equatorial Atlantic through Ekman feedback. These feedback result in a cooling of SST in the equatorial south Atlantic (ESA) region which is so overwhelming that it cancels the warming effect induced by the TT mechanism and reverses the sign of the warm SST anomaly that is formed during stage one in this region. In general, the horizontal advection of heat plays a secondary role in the SST response to the remote influence of ENSO, except in the regions where the North Equatorial Countercurrent (NECC) dominates and the SST variability is strong. Entrainment is particularly important in maintaining the correct SST structure during boreal summer.

Le continuum sol-zone non saturée-aquifère est rarement abordé en modélisation des pesticides car il requiert des outils et une méthodologie élaborés. Ces outils peuvent avoir des niveaux de complexités variables, le plus simple étant le modèle global et le plus complexe, le modèle hydrogéologique de transport en 3 dimensions prenant en compte chacun des compartiments dans le détail. Dans ce contexte une modélisation associant de manière dynamique des outils ou des méthodes propres à chaque compartiment propose une solution intermédiaire intéressante. Une approche progressive de la modélisation hydrodynamique ainsi que de la modélisation des transferts de pesticides, appliqué au cas du bassin versant hydrogéologique de la source des Brévilles à Montreuil-sur-Epte (Val d’Oise) a pu être réalisée et fournir un modèle couplé 1D / 2D prenant en compte l’écoulement et le transport dans le sol, la zone non saturée et la zone saturée / The continuum ground-vadose zone-aquifer is rarely studied in the modeling of pesticides because it requires elaborate tools and methodology. These tools may have variable levels of complexity, the simplest being the global model and most complex, the hydrogeological model of transport in 3D taking into account each compartment in detail. In this context, a modeling associating in a dynamic way, tools or specific methods to each compartment will be an interesting intermediate solution. A progressive approach of hydrodynamic modeling and transfer modeling of pesticides applied to the case of the Brévilles spring catchment in Montreuil-sur-Epte (Val d'Oise) has been carried out and provided a coupled model 1D / 2D taking into account the flow and transport in the ground, the unsaturated zone and the saturated zone

A systematic procedure is designed to evaluate the role of stochastic forcing (SF) in El Nino ? Southern Oscillation (ENSO) exhibited by coupled ocean-atmosphere general circulation models (CGCMs). The procedure is applied on a 163-year run of a CGCM which has realistic representation of ENSO and SF. The realism of ENSO in the CGCM is determined by statistical comparison with a 29-year global reanalysis product. SF is extracted from both the CGCM and reanalysis as residual atmospheric variability uncoupled to the ocean. Further, the Madden-Julian Oscillation (MJO) and non-MJO components are isolated from SF. The CGCM stochastic components are compared to those from the reanalysis to validate their representation. A coupled ocean-atmosphere model of intermediate complexity is first forced with stochastic components from the reanalysis. The resulting ENSO is examined for realism to evaluate the strengths and weaknesses of the intermediate coupled model, which is then forced with the stochastic components from the CGCM. Results are diagnosed to investigate the role of SF. It is found that the SF can play an important role in ENSO in the CGCM, especially in its warm events. The role is similar to reanalysis SF in generating ENSO period and spring predictability barrier. However, unlike in case of the reanalysis, the seasonal dependence of ENSO variance in the CGCM does not seem to be originating from its SF. The contribution to statistics appears to be higher from the MJO component of SF compared to the non-MJO component. The intermediate model simulations also suggest that both in CGCM and nature, the SF operates on a weakly stable coupled system to produce ENSO variability.

This paper presents modifications to two widely used numerical groundwater flow models in an effort to improve upon the interaction between a well of finite length and conductivity with the surrounding formation. The first objective is to discard the common assumptions about flux- or head-based boundary conditions along the well screen by coupling pipe flow hydraulics and groundwater flow. The second objective is to avoid restricting the wellbore hydraulics to a single flow regime. Five flow regimes (laminar through rough-turbulent), based on Reynolds number and pipe roughness, are considered. The modifications are integrated into the highly versatile, well-documented and well-tested models HydroGeoSphere (finite-element/finite-difference) and USGS MODFLOW (finite-difference). Verification of the algorithm and code and is performed by comparing results to: 1) the idealized, analytical Theis solution; 2) the original, unmodified code; and 3) the results of a third party numerical solution that also accounts for variable frictional wellbore losses. Results highlight the inadequacy of either a uniform flux or a uniform head assumption along the wellbore. The solution also tends to produce much steeper hydraulic gradients in those portions of the aquifer nearest the pump intake than have previously been predicted. Systems most affected by in-well hydraulic losses include those for which well screen is long, pumping rate is large, pipe diameter is small, pipe roughness is large (either through design or aging) and aquifer conductivity is high. Improved modeling of the non-linear hydraulic conditions within the well screen can particularly influence the interpretation of wellbore flowmeter and tracer tests, leading to more precise knowledge of the variation of local aquifer hydraulic conductivity along well screens. Aquifer drawdown curves, solute transport and inflow velocities will also be influenced, which can impact capture zones and remediation costs. Given that the solution is incorporated within the HydroGeoSphere and MODFLOW models, it presents the additional advantage over existing approaches of offering a wide range of modeling capabilities, such as three-dimensional flow, arbitrary well inclination and surface-subsurface flow integration. / Thesis (Master, Civil Engineering) -- Queen's University, 2008-01-04 17:27:50.629

Orientador: Antonio Vidiella Barranco / Dissertação (mestrado) - Universidade Estadual de Campinas, Instituto de Física Gleb Wataghin / Made available in DSpace on 2018-08-18T11:57:02Z (GMT). No. of bitstreams: 1 Decordi_GustavoLazero_M.pdf: 2336423 bytes, checksum: d0ac4b8793e91906cabc7f57fd39f8e7 (MD5) Previous issue date: 2011 / Resumo: Nesta dissertação estudamos um modelo da interação radiação-matéria, mais conhecido como modelo Raman acoplado, consistindo de um átomo de três níveis na configuração ? (lambda) acoplado a dois modos do campo quantizado em regime de alta dessintonia átomo-campo. De início, apresentamos uma revisão dos assuntos que formam a base para o entendimento do trabalho. A partir daí, deduzimos o Hamiltoniano efetivo do modelo através do método de transformação unitária mantendo os termos de segunda ordem nas constantes de acoplamento e eliminando o nível intermediário. Na sequência, comparamos a dinâmica atômica sob duas preparações distintas: na primeira delas consideramos os dois modos em estados puros (estados coerentes), enquanto que na segunda alteramos a preparação do modo 2, mudando o estado coerente para um estado de máxima entropia (estado térmico). Finalizamos esta tese apresentando um estudo do emaranhamento na partição átomomodo 1 sob in uência do modo 2, considerado um subsistema externo. Adotando a Negatividade como principal medida de emaranhamento átomo-campo, vericamos em que circunstâncias do modelo (tempo, preparações iniciais) temos o máximo emaranhamento. / Abstract: In this work we study a model for the matter-radiation interaction, best known as Raman coupled model, which consists of an atom with three levels in the ? (lambda) conguration, coupled to two modes of the quantized field in a high atom-field detuning regime. At the beginning, we present a review of the subjects that form the background for understanding the work. After that, we deduce the Effective Hamiltonian of the model through the method of unitary transformation, keeping the terms of second order in the coupling constants and eliminating the intermediate level. In the sequence, we compare the atomic dynamics under two distinct preparations: in the first we consider the two modes as pure states (coherent states), while in the second we change the preparation in the mode 2, switching the coherent state to a state of maximum entropy (thermal state). We finish this dissertation presenting a study of the entanglement in the partition atommode 1 under the influence of the mode 2, considered as an external subsystem. Adopting the Negativity as the main measure of the atom-field entanglement, we verify in wich circumstances of the model (time, initial preparations) we achieve the maximum entanglement / Mestrado / Física Atômica e Molecular / Mestre em Física

Diverse hypotheses are behind the strength degradation in metals due to hydrogen diffusion, leading to a severe, sudden failure. These diverse hypotheses of hydrogen embrittlement include various mechanisms that are responsible for the embrittlement of metals due to hydrogen exposure in their microstructures. This research study focuses on one hydrogen embrittlement mechanism: Hydrogen-Enhanced-Localized-Plasticity (HELP). The HELP is the only single mechanism characterized by promoting localization of plastic flow ahead of the crack by increasing dislocation motion in that region. The current state of the art is a development of a numerical model representing a fully diffusion-mechanical coupled model. This fully coupled model attempts to gain valuable insights into hydrogen's influence on the mechanical properties and the fatigue life of metals, in general. First, detailed development of a numerical approach is illustrated describing how to fully couple the hydrogen diffusion and stresses using a finite element method. The formulation is based on a coupled temperature-displacement procedure using Abaqus. This coupled computational model, described in this first part, is novel because the mechanical part is based on an isotropic-kinematic hardening law. Furthermore, this fully coupled numerical model can capture both a hardening and softening effect of the stress-strain curve when the solution of the plastic properties is dependent on hydrogen. This can also contribute in a complementary way to the results previously shown by other researchers. Though these previous studies used the same hydrogen diffusion model, their mechanical part was based on a power law. Second, this research attempts to delve into the hydrogen effect on the constitutive response of metals undergoing a cyclic load. Hence, based on the HELP theory, this constitutive coupled model can capture different cyclic hardening behaviors. This study can largely contribute to understanding the degradation of the mechanical properties of materials before crack propagation, which has been heavily covered in the literature.

Este trabalho apresenta uma investigação da interação entre o gelo marinho Antártico e o setor austral e sudoeste do Atlântico Sul. Para realizar este estudo foram utilizados dados de satélite da concentração do gelo marinho e o modelo numérico acoplado do NCAR (Nacional Center for Atmospheric Research) o CCSM3 (Community Climate System Model) versão 3. O CCSM3 foi integrado por 150 anos em 3 diferentes simulações. Estas foram forçadas com as climatologias prescritas da concentração de gelo máximo (MAX), mínimo (MIN) e médio (controle) com o objetivo de avaliar o impacto das mudanças do gelo marinho Antártico no Mar de Weddell e na região da Confluência Brasil-Malvinas (CBM). Este estudo enfatiza a interação das escalas de tempo anual, interanual a decadal. A metodologia empregada nesta pesquisa inclue as análises de correlação e espectral, bem como as técnicas estatísticas de funções ortogonais empíricas (EOF) e decomposição de valores singulares (SVD). O comportamento climático das variáveis oceânicas apresentou sensibilidade às diferentes concentrações de gelo marinho Antártico. A variabilidade das anomalias de TSM e SSM mostraram para o experimento MIN padrões espaciais que caracterizam um regime frio do Giro de Weddell, associado a menor intrusão da CDW. A resposta da variabilidade da temperatura, entre os cenários de gelo MAX e MIN, para a região da CBM sugere que menores concentrações de gelo marinho Antártico intensificam as anomalias de TSM desta região, com periodicidade interanual de 2-3 anos e decadal de 25 anos. A circulação oceânica, em ambas as regiões analisadas, associada a fase positiva da SAM se intensifica devido a influência das menores concentrações de gelo marinho. / In this work the interaction between Antarctic sea-ice and the South Atlantic ocean (austral and southwestern sectors) is investigated. To accomplish this satellite-observed sea-ice concentration (SIC) and a coupled model from NCAR-CCSM3 (National Center for Atmospheric Research - Community Climate System Model version 3) were employed. Three 150-year simulations, one each with the maximum (MAX), minimum (MIN) and average (control) SIC prescribed climatologies, were used to drive the CCSM3 run. The goal of the research is to evaluate the Weddell Sea and Brazil-Malvinas confluence (BMC) response to observed extremes in Antarctic sea-ice. This study focuses on annual, interannual and decadal timescales. The applied methodology uses correlation and spectrum analyses, as well as Empirical Orthogonal Functions (EOF) and Singular Value Decomposition (SVD). The annual mean behavior of oceanic variables showed sensibility to Antarctic sea-ice changes. The variability of SST and SSS anomalies showed for the sea-ice MIN experiment a spatial pattern that characterizes the cold regime of the Weddell Gyre, associate with low CDW intrusion. The response of the temperature variability, between sea-ice MAX and MIN scenarios, for the BMC region suggests that less Antarctic sea-ice produces a SST anomaly intensification in this region with a interannual cycle of the 2-3year and decadal cycle of the 25-year. The oceanic circulation in both study regions, related to positive SAM events, showed a intensification to less SIC influence.

Este trabalho apresenta uma investigação da interação entre o gelo marinho Antártico e o setor austral e sudoeste do Atlântico Sul. Para realizar este estudo foram utilizados dados de satélite da concentração do gelo marinho e o modelo numérico acoplado do NCAR (Nacional Center for Atmospheric Research) o CCSM3 (Community Climate System Model) versão 3. O CCSM3 foi integrado por 150 anos em 3 diferentes simulações. Estas foram forçadas com as climatologias prescritas da concentração de gelo máximo (MAX), mínimo (MIN) e médio (controle) com o objetivo de avaliar o impacto das mudanças do gelo marinho Antártico no Mar de Weddell e na região da Confluência Brasil-Malvinas (CBM). Este estudo enfatiza a interação das escalas de tempo anual, interanual a decadal. A metodologia empregada nesta pesquisa inclue as análises de correlação e espectral, bem como as técnicas estatísticas de funções ortogonais empíricas (EOF) e decomposição de valores singulares (SVD). O comportamento climático das variáveis oceânicas apresentou sensibilidade às diferentes concentrações de gelo marinho Antártico. A variabilidade das anomalias de TSM e SSM mostraram para o experimento MIN padrões espaciais que caracterizam um regime frio do Giro de Weddell, associado a menor intrusão da CDW. A resposta da variabilidade da temperatura, entre os cenários de gelo MAX e MIN, para a região da CBM sugere que menores concentrações de gelo marinho Antártico intensificam as anomalias de TSM desta região, com periodicidade interanual de 2-3 anos e decadal de 25 anos. A circulação oceânica, em ambas as regiões analisadas, associada a fase positiva da SAM se intensifica devido a influência das menores concentrações de gelo marinho. / In this work the interaction between Antarctic sea-ice and the South Atlantic ocean (austral and southwestern sectors) is investigated. To accomplish this satellite-observed sea-ice concentration (SIC) and a coupled model from NCAR-CCSM3 (National Center for Atmospheric Research - Community Climate System Model version 3) were employed. Three 150-year simulations, one each with the maximum (MAX), minimum (MIN) and average (control) SIC prescribed climatologies, were used to drive the CCSM3 run. The goal of the research is to evaluate the Weddell Sea and Brazil-Malvinas confluence (BMC) response to observed extremes in Antarctic sea-ice. This study focuses on annual, interannual and decadal timescales. The applied methodology uses correlation and spectrum analyses, as well as Empirical Orthogonal Functions (EOF) and Singular Value Decomposition (SVD). The annual mean behavior of oceanic variables showed sensibility to Antarctic sea-ice changes. The variability of SST and SSS anomalies showed for the sea-ice MIN experiment a spatial pattern that characterizes the cold regime of the Weddell Gyre, associate with low CDW intrusion. The response of the temperature variability, between sea-ice MAX and MIN scenarios, for the BMC region suggests that less Antarctic sea-ice produces a SST anomaly intensification in this region with a interannual cycle of the 2-3year and decadal cycle of the 25-year. The oceanic circulation in both study regions, related to positive SAM events, showed a intensification to less SIC influence.

Das Ziel dieser Arbeit ist die Untersuchung der Wasserhaushaltsprozesse und Stofftransportvorgänge innerhalb der grundwassergeprägten Talauenlandschaften von Tieflandeinzugsgebieten am Beispiel der im Nordostdeutschen Tiefland gelegenen Havel. Die Arbeiten in verschieden skaligen Teileinzugsgebieten der Havel beschäftigen sich dabei zum einen mit der experimentellen Untersuchung und vorrangig qualitativen Beschreibung der Wasserhaushaltsdynamik, zum anderen mit der Entwicklung eines zur quantitativen Analyse von Wasserhaushalts- und Stofftransportprozessen geeigneten Modells und der anschließenden Modellsimulation von Wasserhaushalt und Stickstoffmetabolik im Grundwasser sowie der Simulation von Landnutzungs- und Gewässerstrukturszenarien.<br><br> Für die experimentelle Untersuchung der Abflussbildung und der Wasserhaushaltsprozesse in den Talauenlandschaften des Haveleinzugsgebiets wurde Einzugsgebiet der &#8221;Unteren Havel Niederung&#8220; ein umfangreiches Messnetz installiert. Dabei wurden an mehreren Messstationen und Pegeln meteorologische Parameter, Bodenfeuchte sowie Grundwasserstände und Abflüsse beobachtet. Die Analyse der Messergebnisse führte zu einem verbesserten Verständnis von Wasserhaushaltsprozessen in der durch das oberflächennahe Grundwasser und die Oberflächengewässerdynamik beeinflussten Talauenzone. Darüber hinaus konnten durch die Implementierung der Messergebnisse konsistente Anfangs- und Randbedingungen für die Wasserhaushalts- und Grundwassermodellierung im Modellkonzept IWAN realisiert werden. Mit dem Modell IWAN (Integrated Modelling of Water Balance and Nutrient Dynamics) wurde ein Werkzeug geschaffen, welches die Berücksichtigung spezifischer hydrologischer Eigenschaften von Tieflandauen, wie z. B. den Einfluss des oberflächennahen Grundwassers bzw. der Dynamik von Oberflächenwasserständen auf den Wasserhaushalt, ermöglicht. Es basiert auf der Kopplung des deterministischen distribuierten hydrologischen Modells WASIM-ETH mit dem dreidimensionalen Finite-Differenzen-basierten Grundwassermodel MODFLOW. Die Modellierung der Stickstoffmetabolik im Grundwasser erfolgt durch das mit Grundwassermodell gekoppelte Stofftransportmodel MT3D. Zur modellbasierten Simulation des Wasserhaushalts der Tieflandauenlandschaften wurde das Modellkonzept IWAN für verschieden skalige Teileinzugsgebiete an der Havel für Simulationszeiträume von 2 Wochen bis zu 13 Jahren angewandt. Dabei wurden die Teilmodelle für Wasserhaushalts- und Grundwassermodellierung in zwei unterschiedlichen Teileinzugsgebieten der &#8221;Unteren Havel Niederung&#8220; kalibriert. Die anschließende Validierung erfolgte für das gesamte Einzugsgebiet der &#8221;Unteren Havel&#8220;. Die Unsicherheiten des Modellansatzes sowie die Anwendbarkeit des Modells im Untersuchungsraum wurden geprüft und die Limitierung der Übertragbarkeit auf andere grundwasserbeeinflusste Tieflandeinzugsgebiete analysiert. Die Ergebnisse der Wasserhaushaltssimulationen führen einerseits zum erweiterten Prozessverständnis des Wasserhaushalts in Flachlandeinzugsgebieten, andererseits ermöglichten sie durch die Quantifizierung einzelner Prozessgrößen die Beurteilung der Steuerungsfunktion einzelner Wasserhaushaltsprozesse. Auf der Basis lokaler Simulationsergebnisse sowie geomorphologischer und gewässermorphologischer Analysen wurde ein Algorithmus entwickelt, welcher die Abgrenzung des direkten Eigeneinzugsgebiets der Havel als Raum der direkten Interaktion zwischen Oberflächengewässer und umgebendem Einzugsgebiet beschreibt. Durch Simulation des Wasserhaushalts im Eigeneinzugsgebiet mit dem Modell IWAN konnten die Interaktionsprozesse zwischen Fluss und Talauenlandschaft quantitativ beschrieben werden. Dies ermöglichte eine Bewertung der Abflussanteile aus dem Eigeneinzugsgebiet sowie eine Quantifizierung der zeitlich variablen Retentionskapazität der Auenlandschaft während Hochwasserereignissen. Zur Abschätzung des Einflusses veränderter Landnutzung und angepassten Managements auf den Wasserhaushalt der Talaue wurden Szenarien entwickelt, welche Änderungen der Landnutzung sowie der Gewässergeometrie implizieren. Die Simulation des Wasserhaushalts unter jeweiligen Szenariobedingungen ermöglichte die detaillierte Analyse sich ändernder Randbedingungen auf den Gebietswasserhaushalt und auf die Austauschprozesse zwischen Grundwasser und Oberflächengewässer. Zur Untersuchung der Stickstoffmetabolik im Grundwasser der Talauenlandschaft wurde das im Modellkonzept IWAN integrierte Stofftransportmodell MT3D für das Eigeneinzugsgebiet der Havel angewandt. Dies ermöglichte eine Bilanzierung der aus dem Grundwasser des Eigeneinzugsgebiets stammenden Nitratfrachtanteile der Havel sowie von Nitratkonzentrationen im Grundwasser. Szenariensimulationen, welche verminderte Nitrateinträge aus der durchwurzelten Bodenzone annehmen, ermöglichten die Quantifizierung der Effizienz von Managementmaßnahmen und Landnutzungsänderungen in Hinblick auf die Minimierung von Einträgen in Grundwasser und Oberflächengewässer. / For a sustainable management of lowland river basins, a comprehensive knowledge about floodplain water balance and nutrient transport processes is required. This investigation aims to analyse water balance processes and nutrient dynamics and transport within the groundwater influenced floodplains of lowland areas. Thus, the investigation was focused on the Havel river catchment at the Northeast German Lowlands, which is a typical example of a lowland floodplain. Experimental investigations were performed at different spatial scales for qualitative analysis of water balance. The complex model IWAN was developed which enables the simulation and quantitative analysis of water balance and nutrient dynamics. Furthermore it allows the scenario based simulation and analysis of changing landuse management and boundary conditions.<br><br> For experimental investigation of runoff generation and water balance processes within the floodplains of the Havel river an extensive measurement campaign was installed at several testsites of the 198 km2 catchment of the &#8220;Lower Havel river basin&#8220;. These testsites include stations and gauges for the observation of meteorological parameters, soil moisture, groundwater depths and river runoff. Analysis of the observed data led to an improved understanding of water balance processes within the specific part of the floodplain which is influenced by the dynamics of the uppermost groundwater and by the surface water dynamics. Furthermore the implementation of the observed data within the model concept realised the consistent definition of time variable, spatial distributed initial and boundary conditions. The IWAN model was developed as a tool which implements the speci- fic hydrological characteristics of floodplains within the concept of modelling water balance and nutrient dynamics. It is based on the coupling of the distributed deterministic hydrological model WASIM-ETH with the three-dimensional finite difference based numerical groundwater model MODLFOW. Simulation of the metabolism of nitrogen within the groundwater passage was realised by the nutrient transport model MT3D which was coupled with the groundwater model. For model based simulation of the water balance within lowland river floodplains the IWAN model was applied for different scaled subcatchments of the Havel river with varying sizes from 2 to 1000 km2 and simulation periods from 2 weeks up to 13 years. Calibration of the model was performed for two different sized subcatchments of the &#8220;Lower Havel river basin&#8220;. The subsequent validation of the model focused on the entire &#8220;Lower Havel river basin&#8220;. Uncertainties of the model approach and the limited applicability and transferability for further groundwater influenced floodplain landscapes were analysed. The results of the water balance simulations led to an improved understanding of the processes and dynamics within floodplains. It furthermore enabled the quantification and impact analysis of certain processes and interactions. Based on local simulation results and on the analysis of surface and groundwater morphology an algorithm was developed which was used for delineation of the direct catchment of the Havel river. This direct catchment is specified as the part of the floodplain which is characterised by the direct interaction between river and adjacent catchment. Water balance simulations with the IWAN model in the direct catchment led to the quantification of interaction processes between river and floodplain. This enabled the assessment of the runoff fraction from the direct catchment during the ecologically sensitive low flow periods in summer and of the retention capacity of the floodplain during flood events. For the evaluation of the influences of alternative landuse management on the water balance within floodplains, complex scenarios were developed which implemented alterations of landuse or changes of surface water geometries and drainage structures. Simulation of water balances for each scenario allowed the detailed analysis of changing boundary conditions on the floodplain water balance and on the interaction processes between groundwater and river. Modelling nitrogen metabolism within the groundwater: For investigation of the nitrogen metabolism within the groundwater of floodplains the nutrient transport and dynamics model MT3D, which considers also interactions between groundwater and surface waters, was integrated in the IWAN concept. The model was applied for the simulation of nitrate dynamics within the direct catchment of the Havel river.With this approach, the nitrate loads between groundwater and river could be quantified. In addition, nitrate concentrations within the groundwater were analised in dependence of surface water dynamics. Scenario simulations, assuming a decrease of incoming nitrate loads from the root zone, caused by landuse techniques, led to the quantification of the efficiency of landuse changes and advanced management strategies to inhibit pollution of groundwater and surface waters.

La mayoría de las estructuras de hormigón armado se someten a solicitaciones combinadas de esfuerzos axiles, flexión, cortante y torsión. La fisuración del hormigón, plastificación de las armaduras y otros efectos no-lineales hacen que las secciones transversales de estos elementos presenten un comportamiento anisótropo que deriva en el acoplamiento de los esfuerzos normales y tangenciales. Es decir, esfuerzos normales o momentos flectores pueden producir deformaciones de corte y vice versa. Aunque en algunas ocaciones, esta interacción es considerada de forma simplificada en el dimensionamiento de estructuras, hasta el momento no se ha realizado un análisis profundo de los efectos acoplados en secciones de forma arbitraria bajo cargas 3D generales utilizando modelos de fibras.El objetivo principal de esta tesis es generalizar el análisis de secciones de hormigón armado mediante fibras, de forma que se pueda reproducir la res-puesta no-lineal acoplada frente a esfuerzos normales y tangenciales bajo solicitaciones tridimensionales generales. De igual forma, se pretende obtener, para los esfuerzos cortantes y torsión, la misma capacidad de representación de geometrías y combinación de materiales que ofrecen los modelos de fibras para esfuerzos de flexo-compresión.La primera problemática estriba en representar adecuadamente la cinemática de la sección transversal. Con la excepción de las deformaciones normales contenidas en el plano de la sección, no existe una teoría cinemática que a priori pueda dar la distribución del resto de deformaciones o tensiones en la sección, sin dejar de satisfacer las condiciones de equilibrio interno o continuidad entre las fibras que componen la misma.Por otra parte, para materiales anisótropos, como el hormigón fisurado, en general todos los esfuerzos internos pueden estar acoplados. Además, es preciso considerar la distorsión de la sección transversal para satisfacer el equilibrio entre fibras.El problema se aborda de forma general, considerando una sección de forma y materiales cualesquiera. Se parte del problema diferencial de equilibrio de un sólido con el que se ha podido deducir un sistema de equilibrio entre fibras (equilibrio a nivel sección). Se puede demostrar que éste es complementario al problema estándar de vigas. El sistema complementario permite recuperar información tridimensional que normalmente se pierde al resolver un problema de vigas.Posteriormente, se propone una solución interna del problema complementario, en la que el alabeo y la distorsión de la sección quedan expresados como una función de las deformaciones generalizadas de una viga: deformaciones axil y cortantes, curvaturas de flexión y torsión. No son necesarios grados de libertad adicionales a nivel estructura ni hipótesis a-priori sobre la forma de los campos de deformación o tensión interna.A partir de la formulación teórica, se desarrolla un modelo de elementos finitos plano de la sección transversal. El modelo está preparado para servir como respuesta constitutiva de cualquier tipo de elemento viga en sus puntos de integración. %Se evita así la necesidad de realizar un modelo de elementos sólidos de toda la barra para estudiar la respuesta frente a una combinación general de esfuerzos normales y tangenciales.Se implementan una serie de modelos constitutivos para distintos materiales. En particular, se implementa un modelo constitutivo triaxial para hormigón fisurado, considerando la anisotropía inducida por la fisuración e incluyendo la superficie de rotura según un criterio multiaxial.La formulación seccional es validada mediante varios casos de estudio teóricos y experimentales. La respuesta no-lineal acoplada bajo diversas combinaciones de esfuerzos normales y tangenciales es reproducida con precisión, lo cual queda patente tanto en las curvas esfuerzo-deformación obtenidas como en las matrices de rigidez seccionales.Finalmente, se recopilan las conclusiones derivadas de la presente investigación y seofren recomendaciones para futuros trabajos. / Most RC structures are subjected to combined normal and tangential forces, such as bending, axial load, shear and torsion. Concrete cracking, steel yielding and other material nonlinearities produce an anisotropic sectional response that results in a coupling between the effects of normal and shear forces, i.e. normal force or bending moments may produce shear strains and vice versa. Although this interaction is sometimes taken into account, in a simplified manner, in the design of RC structures, a deep analysis of the coupling effects of RC sections using fiber models has not yet been made for arbitrary shape sections under general 3D loading.The main objective of this thesis is to generalize the fiber-like sectional analysis of reinforced concrete elements, to make it capable of considering the coupled non-linear response under tangential and normal internal forces, from a general 3D loading.Similarly, it is desired to obtain, for torque and shear forces, the same capacity and versatility in reproducing complex geometry and materials combination that fiber-like sectional representations offers for bending and stretching.The first problematic lies in finding a proper representation of the section's kinematics under such general loading. Except for in-plane normal strains, there is no single kinematical theory capable of a-priori representing the correct distribution of the others strains or stresses satisfying, at the same time, inter-fiber equilibrium and continuity. On the other hand, for rather anisotropic materials, such as cracked concrete, all internal forces are, in general, coupled. It is also required that distortion is allowed for the section's kinematics in order to guarantee satisfaction of internal equilibrium.The problem is dealt in a general form considering arbitrary shaped sections and any material behaviour. Starting from the differential equilibrium of a solid, an inter-fiber equilibrium system (equilibrium at the sectional level) was deduced. This system, which is complementary to the standard equilibrium problem of a beam-column, allows to recuperate information of the three-dimensional problem that is generally lost when solving a beam problem.Further, a solution of the equilibrium at the sectional level is proposed in which the section's warping and distortion are posed as a function of the generalized beam-column strains (axial and shear strains, bending and torsion curvatures). No additional degrees of freedom are required at the structural level nor a-priori hypotheses on the distribution of the internal strains or stresses.After the theoretical formulation, a planar finite element model for cross-sectional analysis is developed. The model can be used as a constitutive law for general beam column elements at their integration points.A series of constitutive models have been implemented for several materials. In particular, a triaxial constitutive model for cracked concrete is implemented considering crackinduced anisotropy and a multiaxial failure criterion.The sectional formulation is validated by means of various theoretical and experimental case studies. Non-linear coupled response under normal and tangential internal forces is reproduced with accuracy, as can be seen both in the predicted internal force-strain curves and in the sectional stiffness matrixes.Finally, the conclusions drawn from the current research are summarized andrecomendations for future works are given.