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This study reports a novel and simple technique for successfully coating multi-walled carbon nanotubes (MWCNTs) on to the surface of carbon fibre (CF) fabric for the production of multi-scale CF-epoxy composites. Initially, epoxy composites with multi-scale reinforcement were produced by resin infusion (RI) using woven CF fabric coated with a dispersion of 1 wt. % MWCNTs in an epoxy binder of low molar mass. The effects of this reinforcement on the CF-epoxy interface with MWCNTs was studied in mode I and mode II interlaminar fracture toughness (ILFT) using double-cantilever beam (DCB) and 4 point end-notch flexure (4ENF) tests, respectively. Relative to an equivalent composite reinforced with non-coated CF reinforcement, the binder/MWCNTs coating increased significantly the ILFT of the CF-epoxy composite; in mode I by 105% and in mode II by 50%. This increase in ILFT was attributed to two main effects: Firstly, the binder alone (without MWCNTs), which has a much lower glass transition temperature (Tg) than that the matrix (45 vs. 140 °C), hindered crack propagation and increased the ILFT of the epoxy matrix by 25% for mode I and 15% for mode II; Secondly, the energy absorbing mechanisms of MWCNTs during fracture particularly pull-out and crack bridging. However the Tg of the matrix epoxy of the multi-scale composites was reduced to 118 °C compared to 140 °C, for the unmodified composite, due to phase mixing with the low Tg binder. For RI processing, the CF volume fraction of the composites prepared using coated CF was ≈50% compare to at ≈55% for the composite with non-coated CF. Curing agents were added to the binder, which not only increased the Tg from ≈50 °C to ≈100 °C, but also increased the Tg of the matrix epoxy of the multi-scale composites to 154 °C. Relative to an equivalent composite reinforced with non-coated CF reinforcement, the curable-binder/MWCNTs coating increased the ILFT of the CF-epoxy composite; in mode I by 120% and in mode II by 90%. A hybrid RI-hot press (HP) process was used to prepare CF-epoxy composites from coated fabrics with CF volume fractions of ≈55%. The damping curves for the HP-composites consisted of a β-peak, due to the formation of a third mixed phase, in addition to a γ-peak (assigned to the Tg of the binder) and an α-peak (assigned to the Tg of matrix epoxy). The β-peak, and the uniformly distributed nodular particles observed on the fracture surface of the matrix, by SEM, for HP-composites, are indicative of the formation of mixed-phase particles due to reaction induced phase separation (RIPS). Relative to an equivalent RI-composite, the curable-binder/MWCNTs treatment increased the ILFT of the CF-epoxy multi-scale composite; in mode I by 134% and in mode II by 15% for HP-composites. Impact test results showed that HP-composites absorbed more energy, due to CF fracture, compared to equivalent RI composites, which showed larger delamination areas after 5 J and 10 J impact. The out-of-plane electrical conductivity and thermal conductivity of the HP-composite with CF coated with curable-binder/MWCNTs was increased by ≈38% and ≈50%, respectively, compared to the composite with non-coated CF, indicating formation of MWCNTs networks in the matrix rich areas of the multi-scale composite.

The main aim of this work is to examine fracture toughness improvement mechanisms of a composite material containing tough interlayers modified with large thermoplastic particles. ¶ Various vinyl-ester (VE)/ poly(acrylonitrile-butadiene-styrene) (ABS) blends were used for the interlayer-toughening of a VE/glass fibre composite to increase delamination resistance of the material under mode I and mode II loading. Dry ABS powder was mixed with the liquid resin in four different weight ratios: 3.5, 7, 11 and 15 phr (parts per hundred parts of resin) while the layer thickness was varied from 150 to 500um. Firstly, the tensile and mode I fracture toughness properties of the VE/ABS blends were assessed, and, by using the Raman Spectroscopy technique, a chemical reaction was discovered which occurred during ABS/VE mixing. This reaction consisted of butadiene dissolution from the ABS particles into the VE. Also, butadiene saturation within the VE was achieved at a composition of around 7% ABS particle content. Both mode I and mode II fracture toughness of the composite were significantly improved with the application of interlayers. Mode I fracture toughness GIc was found to be a function of interlayer thickness and ABS particle content variations, with the latter dominating GIc after the saturation point. Mode II fracture toughness was found to be independent of interlayer thickness and only moderately influenced by particle content. The toughening mechanisms that were the most influential within this interlayered material were plastic deformation and micro-cracking of the layer materials. Evidence of both mechanisms was found using optical and scanning electron microscopy (SEM). ¶ A numerical analysis was conducted, using the experimental results from this study, to further explain the basic toughening mechanisms and fracture behaviour in the materials. The aim of the analysis was to examine the influence of the particles on the plastic zone size that develops in front of the crack tip, and the interaction between the particles and the crack tip. For this purpose FEA elastic-plastic crack propagation models were employed. Good agreement with the experimental data was found.

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Bioactive glasses are a type of ceramic material designed to be used as bioresorbable therapeutic bone implants. Thermal treatment of bioactive glass ceramics dictates many important features such as microstructure, degree of crystallinity, mechanical properties, and mineralization. This study investigates the effects of temperature, time, and heating rates on the crystallization kinetics of melt cast bioactive glass 45S5. Bulk crystallization (three dimensional crystallite formation) was found to always occur in bulk bioactive glass 45S5 irrespective of the processing conditions. A comparative study of crack paths in amorphous and crystalline phases of bioactive glass 45S5 revealed crack deflections and higher fracture resistance in partially crystallized bioactive glass. Such toughening is likely attributed to different crystallographic orientations of crystals or residual thermal mismatch strains. Furthermore, in vitro immersion testing of partially crystalline glass ceramic revealed higher adhesion capabilities of the mineralized layer formed on amorphous regions as compared to its crystalline counterpart. / Materials Engineering

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abstract: Laboratory assessment of crack resistance and propagation in asphalt concrete is a difficult task that challenges researchers and engineers. Several fracture mechanics based laboratory tests currently exist; however, these tests and subsequent analysis methods rely on elastic behavior assumptions and do not consider the time-dependent nature of asphalt concrete. The C* Line Integral test has shown promise to capture crack resistance and propagation within asphalt concrete. In addition, the fracture mechanics based C* parameter considers the time-dependent creep behavior of the materials. However, previous research was limited and lacked standardized test procedure and detailed data analysis methods were not fully presented. This dissertation describes the development and refinement of the C* Fracture Test (CFT) based on concepts of the C* line integral test. The CFT is a promising test to assess crack propagation and fracture resistance especially in modified mixtures. A detailed CFT test protocol was developed based on a laboratory study of different specimen sizes and test conditions. CFT numerical simulations agreed with laboratory results and indicated that the maximum horizontal tensile stress (Mode I) occurs at the crack tip but diminishes at longer crack lengths when shear stress (Mode II) becomes present. Using CFT test results and the principles of time-temperature superposition, a crack growth rate master curve was successfully developed to describe crack growth over a range of test temperatures. This master curve can be applied to pavement design and analysis to describe crack propagation as a function of traffic conditions and pavement temperatures. Several plant mixtures were subjected to the CFT and results showed differences in resistance to crack propagation, especially when comparing an asphalt rubber mixture to a conventional one. Results indicated that crack propagation is ideally captured within a given range of dynamic modulus values. Crack growth rates and C* prediction models were successfully developed for all unmodified mixtures in the CFT database. These models can be used to predict creep crack propagation and the C* parameter when laboratory testing is not feasible. Finally, a conceptual approach to incorporate crack growth rate and the C* parameter into pavement design and analysis was presented. / Dissertation/Thesis / Ph.D. Civil and Environmental Engineering 2013

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Crack propagation in structures when subjected to fatigue loading, follows three different phases namely - short crack growth, stable crack growth and unstable crack growth. Accurate fatigue life prediction demands the consideration of every crack propagation phase rather than only the stable crack growth stage. Further, the use of existing crack growth laws in structures with small cracks under-predicts the growth rate compared to experimentally observed ones, thereby leading to an unsafe design and keeping the structure in a potentially dangerous state. In the present work, an attempt is made to establish fatigue crack propagation laws for plain concrete, reinforced concrete and concrete-concrete jointed interfaces from first principles using the concepts of dimensional analysis and self-similarity. Different crack growth laws are proposed to understand the behavior in each of the three regimes of the fatigue crack growth curve. Important crack growth characterizing material and geometrical parameters for each zone are included in the proposed analytical models. In real life applications to structures, the amplitude of cyclic loading rarely remains constant and is subjected to a wide spectrum of load amplitudes. Furthermore, the crack growth behavior changes in the presence of high amplitude load spikes within a constant amplitude history and this is incorporated in the model formulation. Using scaling laws, an improved understanding of the scaling behavior on different parameters is achieved. The models describing different regimes of crack propagation are finally unified to obtain the entire crack growth curve and compute the total fatigue life. In addition, crack growth analysis is performed for a reinforced concrete member by modifying the model derived for plain concrete in the Paris regime. Energy dissipation occurring due to shake-down phenomenon in steel reinforcement is addressed. The bond-slip mechanism which is of serious concern in reinforced concrete members is included in the study and a method is proposed for the prediction of residual moment carrying capacity as a function of relative crack depth. The application of the proposed analytical model in the computation of fatigue crack growth is demonstrated on three practical problems – beam in flexure, concrete arch bridge and a patch repaired beam. Through a sensitivity study, the influence of different parameters on the crack growth behavior is highlighted.