Geochemistry plays a vital role in our understanding mechanisms behind major geological systems such as the Earth's crust and its oceans (Albarède, F. 2003). More recently, geo-chemistry has played a vital role in the field of forensic investigation and in period dating. Forensic soil samples have been traditionally analysed via examinations of colour, texture and mineral content by physical or chemical methods. However, these methods leave any organic or water-soluble fractions unexamined. Tephrochronology (the dating of sedimentary sequences using volcanic ash layers) is an important tool for the dating and correlation of sedimentary sequences containing archives and proxies of past environmental change. Its importance in this area has increased since the increased free carbon in out atmosphere has made radio-carbon dating unreliable. Tephrochronology requires successful geo-chemical identification of the tephras, a method reliant on electron probe micro-analysis (EPMA) to analyse major element composition. However, it is often impossible to differentiate key tephra layers using EPMA alone. Raman spectroscopy is commonly used in chemistry, since vibrational information is specific to the chemical bonds and symmetry of molecules, and can provide a fingerprint by which these can be identified. Here, we demonstrate how Raman spectroscopy can be used for the successful discrimination of mineral species in tephra through the analysis of individual glass shards. We further demonstrate how, with the use of oxidative preparation methods, Raman spectroscopy can be used to successfully discriminate between soil types using mineralogy as well as the organic and water-soluble fractions of soils.

Developing high quality software is the goal of every software development organization. Software quality models are commonly used to assess and improve the software quality. These models, based on the past releases of the system, can be used to identify the fault-prone modules for the next release. This information is useful to the open-source software community, including both developers and users. Developers can use this information to clean or rebuild the faulty modules thus enhancing the system. The users of the software system can make informed decisions about the quality of the product. This thesis builds quality models using logistic regression, neural networks, decision trees, and genetic algorithms and compares their performance. Our results show that an overall accuracy of 65 ? 85% is achieved with a type II misclassification rate of approximately 20 ? 35%. Performance of each of the methods is comparable to the others with minor variations.

No description available.

No description available.

No description available.

No description available.

The standard methodology when building statistical models has been to use one of several algorithms to systematically search the model space for a good model. If the number of variables is small then all possible models or best subset procedures may be used, but for data sets with a large number of variables, a stepwise procedure is usually implemented. The stepwise procedure of model selection was designed for its computational efficiency and is not guaranteed to find the best model with respect to any optimality criteria. While the model selected may not be the best possible of those in the model space, commonly it is almost as good as the best model. Many times there will be several models that exist that may be competitors of the best model in terms of the selection criterion, but classical model building dictates that a single model be chosen to the exclusion of all others. An alternative to this is Bayesian model averaging (BMA), which uses the information from all models based on how well each is supported by the data. Using BMA allows a variance component due to the uncertainty of the model selection process to be estimated. The variance of any statistic of interest is conditional on the model selected so if there is model uncertainty then variance estimates should reflect this. BMA methodology can also be used for variable assessment since the probability that a given variable is active is readily obtained from the individual model posterior probabilities. The multivariate methods considered in this research are principal components analysis (PCA), canonical variate analysis (CVA), and canonical correlation analysis (CCA). Each method is viewed as a particular multivariate extension of univariate multiple regression. The marginal likelihood of a univariate multiple regression model has been approximated using the Bayes information criteria (BIC), hence the marginal likelihood for these multivariate extensions also makes use of this approximation. One of the main criticisms of multivariate techniques in general is that they are difficult to interpret. To aid interpretation, BMA methodology is used to assess the contribution of each variable to the methods investigated. A second issue that is addressed is displaying of results of an analysis graphically. The goal here is to effectively convey the germane elements of an analysis when BMA is used in order to obtain a clearer picture of what conclusions should be drawn. Finally, the model uncertainty variance component can be estimated using BMA. The variance due to model uncertainty is ignored when the standard model building tenets are used giving overly optimistic variance estimates. Even though the model attained via standard techniques may be adequate, in general, it would be difficult to argue that the chosen model is in fact the correct model. It seems more appropriate to incorporate the information from all plausible models that are well supported by the data to make decisions and to use variance estimates that account for the uncertainty in the model estimation as well as model selection. / Ph. D.

In recent years, as the availability of remote sensing imagery of varying resolution has increased, merging images of differing spatial resolution has become a significant operation in the field of digital remote sensing. This practice, known as data fusion, is designed to enhance the spatial resolution of multispectral images by merging a relatively coarse-resolution image with a higher resolution panchromatic image of the same geographic area. This study examines properties of fused images and their ability to preserve the spectral integrity of the original image. It analyzes five current data fusion techniques for three complex scenes to assess their performance. The five data fusion models used include one spatial domain model (High-Pass Filter), two algebraic models (Multiplicative and Brovey Transform), and two spectral domain models (Principal Components Transform and Intensity-Hue-Saturation). SPOT data were chosen for both the panchromatic and multispectral data sets. These data sets were chosen for the high spatial resolution of the panchromatic (10 meters) data, the relatively high spectral resolution of the multispectral data, and the low spatial resolution ratio of two to one (2:1). After the application of the data fusion techniques, each merged image was analyzed statistically, graphically, and for increased photointerpretive potential as compared with the original multispectral images. While all of the data fusion models distorted the original multispectral imagery to an extent, both the Intensity-Hue-Saturation Model and the High-Pass Filter model maintained the original qualities of the multispectral imagery to an acceptable level. The High-Pass Filter model, designed to highlight the high frequency spatial information, provided the most noticeable increase in spatial resolution. / Master of Science

Return on Capital Employed (ROCE) is a popular financial instrument and communication tool for the appraisal of companies. Often, companies management and other practitioners use untested rules and behavioural approach when investigating the key determinants of ROCE, instead of the scientific statistical paradigm. The aim of this dissertation was to identify and quantify key determinants of ROCE of individual companies listed on the Johannesburg Stock Exchange (JSE), by comparing classical multiple linear regression, principal components regression, generalized least squares regression, and robust maximum likelihood regression approaches in order to improve companies decision making. Performance indicators used to arrive at the best approach were coefficient of determination ( ), adjusted ( , and Mean Square Residual (MSE). Since the ROCE variable had positive and negative values two separate analyses were done. The classical multiple linear regression models were constructed using stepwise directed search for dependent variable log ROCE for the two data sets. Assumptions were satisfied and problem of multicollinearity was addressed. For the positive ROCE data set, the classical multiple linear regression model had a of 0.928, an of 0.927, a MSE of 0.013, and the lead key determinant was Return on Equity (ROE),with positive elasticity, followed by Debt to Equity (D/E) and Capital Employed (CE), both with negative elasticities. The model showed good validation performance. For the negative ROCE data set, the classical multiple linear regression model had a of 0.666, an of 0.652, a MSE of 0.149, and the lead key determinant was Assets per Capital Employed (APCE) with positive effect, followed by Return on Assets (ROA) and Market Capitalization (MC), both with negative effects. The model showed poor validation performance. The results indicated more and less precision than those found by previous studies. This suggested that the key determinants are also important sources of variability in ROCE of individual companies that management need to work with. To handle the problem of multicollinearity in the data, principal components were selected using Kaiser-Guttman criterion. The principal components regression model was constructed using dependent variable log ROCE for the two data sets. Assumptions were satisfied. For the positive ROCE data set, the principal components regression model had a of 0.929, an of 0.929, a MSE of 0.069, and the lead key determinant was PC4 (log ROA, log ROE, log Operating Profit Margin (OPM)) and followed by PC2 (log Earnings Yield (EY), log Price to Earnings (P/E)), both with positive effects. The model resulted in a satisfactory validation performance. For the negative ROCE data set, the principal components regression model had a of 0.544, an of 0.532, a MSE of 0.167, and the lead key determinant was PC3 (ROA, EY, APCE) and followed by PC1 (MC, CE), both with negative effects. The model indicated an accurate validation performance. The results showed that the use of principal components as independent variables did not improve classical multiple linear regression model prediction in our data. This implied that the key determinants are less important sources of variability in ROCE of individual companies that management need to work with. Generalized least square regression was used to assess heteroscedasticity and dependences in the data. It was constructed using stepwise directed search for dependent variable ROCE for the two data sets. For the positive ROCE data set, the weighted generalized least squares regression model had a of 0.920, an of 0.919, a MSE of 0.044, and the lead key determinant was ROE with positive effect, followed by D/E with negative effect, Dividend Yield (DY) with positive effect and lastly CE with negative effect. The model indicated an accurate validation performance. For the negative ROCE data set, the weighted generalized least squares regression model had a of 0.559, an of 0.548, a MSE of 57.125, and the lead key determinant was APCE and followed by ROA, both with positive effects.The model showed a weak validation performance. The results suggested that the key determinants are less important sources of variability in ROCE of individual companies that management need to work with. Robust maximum likelihood regression was employed to handle the problem of contamination in the data. It was constructed using stepwise directed search for dependent variable ROCE for the two data sets. For the positive ROCE data set, the robust maximum likelihood regression model had a of 0.998, an of 0.997, a MSE of 6.739, and the lead key determinant was ROE with positive effect, followed by DY and lastly D/E, both with negative effects. The model showed a strong validation performance. For the negative ROCE data set, the robust maximum likelihood regression model had a of 0.990, an of 0.984, a MSE of 98.883, and the lead key determinant was APCE with positive effect and followed by ROA with negative effect. The model also showed a strong validation performance. The results reflected that the key determinants are major sources of variability in ROCE of individual companies that management need to work with. Overall, the findings showed that the use of robust maximum likelihood regression provided more precise results compared to those obtained using the three competing approaches, because it is more consistent, sufficient and efficient; has a higher breakdown point and no conditions. Companies management can establish and control proper marketing strategies using the key determinants, and results of these strategies can see an improvement in ROCE. / Mathematical Sciences / M. Sc. (Statistics)

Return on Capital Employed (ROCE) is a popular financial instrument and communication tool for the appraisal of companies. Often, companies management and other practitioners use untested rules and behavioural approach when investigating the key determinants of ROCE, instead of the scientific statistical paradigm. The aim of this dissertation was to identify and quantify key determinants of ROCE of individual companies listed on the Johannesburg Stock Exchange (JSE), by comparing classical multiple linear regression, principal components regression, generalized least squares regression, and robust maximum likelihood regression approaches in order to improve companies decision making. Performance indicators used to arrive at the best approach were coefficient of determination ( ), adjusted ( , and Mean Square Residual (MSE). Since the ROCE variable had positive and negative values two separate analyses were done. The classical multiple linear regression models were constructed using stepwise directed search for dependent variable log ROCE for the two data sets. Assumptions were satisfied and problem of multicollinearity was addressed. For the positive ROCE data set, the classical multiple linear regression model had a of 0.928, an of 0.927, a MSE of 0.013, and the lead key determinant was Return on Equity (ROE),with positive elasticity, followed by Debt to Equity (D/E) and Capital Employed (CE), both with negative elasticities. The model showed good validation performance. For the negative ROCE data set, the classical multiple linear regression model had a of 0.666, an of 0.652, a MSE of 0.149, and the lead key determinant was Assets per Capital Employed (APCE) with positive effect, followed by Return on Assets (ROA) and Market Capitalization (MC), both with negative effects. The model showed poor validation performance. The results indicated more and less precision than those found by previous studies. This suggested that the key determinants are also important sources of variability in ROCE of individual companies that management need to work with. To handle the problem of multicollinearity in the data, principal components were selected using Kaiser-Guttman criterion. The principal components regression model was constructed using dependent variable log ROCE for the two data sets. Assumptions were satisfied. For the positive ROCE data set, the principal components regression model had a of 0.929, an of 0.929, a MSE of 0.069, and the lead key determinant was PC4 (log ROA, log ROE, log Operating Profit Margin (OPM)) and followed by PC2 (log Earnings Yield (EY), log Price to Earnings (P/E)), both with positive effects. The model resulted in a satisfactory validation performance. For the negative ROCE data set, the principal components regression model had a of 0.544, an of 0.532, a MSE of 0.167, and the lead key determinant was PC3 (ROA, EY, APCE) and followed by PC1 (MC, CE), both with negative effects. The model indicated an accurate validation performance. The results showed that the use of principal components as independent variables did not improve classical multiple linear regression model prediction in our data. This implied that the key determinants are less important sources of variability in ROCE of individual companies that management need to work with. Generalized least square regression was used to assess heteroscedasticity and dependences in the data. It was constructed using stepwise directed search for dependent variable ROCE for the two data sets. For the positive ROCE data set, the weighted generalized least squares regression model had a of 0.920, an of 0.919, a MSE of 0.044, and the lead key determinant was ROE with positive effect, followed by D/E with negative effect, Dividend Yield (DY) with positive effect and lastly CE with negative effect. The model indicated an accurate validation performance. For the negative ROCE data set, the weighted generalized least squares regression model had a of 0.559, an of 0.548, a MSE of 57.125, and the lead key determinant was APCE and followed by ROA, both with positive effects.The model showed a weak validation performance. The results suggested that the key determinants are less important sources of variability in ROCE of individual companies that management need to work with. Robust maximum likelihood regression was employed to handle the problem of contamination in the data. It was constructed using stepwise directed search for dependent variable ROCE for the two data sets. For the positive ROCE data set, the robust maximum likelihood regression model had a of 0.998, an of 0.997, a MSE of 6.739, and the lead key determinant was ROE with positive effect, followed by DY and lastly D/E, both with negative effects. The model showed a strong validation performance. For the negative ROCE data set, the robust maximum likelihood regression model had a of 0.990, an of 0.984, a MSE of 98.883, and the lead key determinant was APCE with positive effect and followed by ROA with negative effect. The model also showed a strong validation performance. The results reflected that the key determinants are major sources of variability in ROCE of individual companies that management need to work with. Overall, the findings showed that the use of robust maximum likelihood regression provided more precise results compared to those obtained using the three competing approaches, because it is more consistent, sufficient and efficient; has a higher breakdown point and no conditions. Companies management can establish and control proper marketing strategies using the key determinants, and results of these strategies can see an improvement in ROCE. / Mathematical Sciences / M. Sc. (Statistics)