Water requirement was defined by Briggs and Shantz in 1911 as the ratio of the weight of water absorbed by a plant during its growth to the weight of dry matter produced. Ballard (1933) and Williams (1935) defined water requirement as the ratio of the amount of water transpired to the amount of dry matter produced. Ballard (1933) and Williams (1935) defined water requirement as the ratio of the amount of water transpired to the amount of dry matter formed during the whole or any part of the life cycle of the plant. Miller (1938) and Kramer (1959) postulated that the water requirement is the ratio of water used to the dry matter produced, and therefore could more accurately be termed transpiration ratio because it is largely controlled by transpiration. Regardless of specific definition, the dry matter considered in such ratios is generally the amount harvested, including the entire plant except the roots. The amount of water measured is the amount lost during growth since the amount of water retained within the plant is insignificant when compared with either total water intake or the amount transpired. The water requirement thus constitutes a useful way to characterize the plant and soil-water conditions and plant growth. The availability of soil water to a plant is one of the factors that vitally affects its water requirements. In turn, the availability of soil water is affected by soil moisture tension and the salt content of the soil. Thus it seems likely that a significant relationship may exist between a plant's water requirement and its degree of salt tolerance. The relation between water requirement and salt tolerance could not be established based on the information found in the literature at this time. the study reported here was undertaken in an attempt to determine the effect of salt on the water requirement of plant species known to have different degrees of salt tolerance.

The salt attack of Fired Clay Bricks (FCBs) causes surface damage that is aesthetically displeasing and eventually leads to structural damage. Methods for determining the resistances of FCBs to salt weathering have mainly tried to simulate the process by using accelerating aging tests. Most research in this area has concentrated on the types of salt that can cause damage and the damage that occurs during accelerated aging tests. This approach has lead to the use of accelerated aging tests as standard methods for determining resistance. Recently, it has been acknowledged that are not the most reliable way to determine salt attack resistance for all FCBs in all environments. Few researchers have examined FCBs with the aim of determining which material and mechanical properties make a FCB resistant to salt attack. The aim of this study was to identify the properties that were significant to the resistance of FCBs to salt attack. In doing so, this study aids in the development of a better test method to assess the resistance of FCBs to salt attack. The current Australian Standard accelerated aging test was used to measure the resistance of eight FCBs to salt attack using sodium sulfate and sodium chloride. The results of these tests were compared to the water absorption properties and the total porosity of FCBs. An empirical relationship was developed between the twenty-four-hour water absorption value and the number of cycles to failure from sodium sulfate tests. The volume of sodium chloride solution was found to be proportional to the total porosity of FCBs in this study. A phenomenological discussion of results led to a new mechanism being presented to explain the derivation of stress during salt crystallisation of anhydrous and hydratable salts. The mechanical properties of FCBs were measured using compression tests. FCBs were analysed as cellular materials to find that the elastic modules of FCBs was equivalent for extruded FCBs that had been fired a similar temperatures and time. Two samples were found to have significantly different elastic moduli of the solid microstructure. One of these samples was a pressed brick that was stiffer due to the extra bond that is obtained during sintering a closely packed structure. The other sample was an extruded brick that had more firing temperature and time compared with the other samples in this study. A non-destructive method was used to measure the indentation hardness and indentation stress-strain properties of FCBs. The indentation hardness of FCBs was found to be proportional to the uniaxial compression strength. In addition, the indentation hardness had a better linear correlation to the total porosity of FCBs except for those samples that had different elastic moduli of the solid microstructure. Fractography of exfoliated particles during salt cycle tests and compression tests showed there was a similar pattern of fracture during each failure. The results indicate there were inherent properties of a FCB that determines the size and shape of fractured particles during salt attack. The microstructural variables that determined the fracture properties of FCBs were shown to be important variables to include in future models that attempt to estimate the resistance of FCBs to salt attack.

Irrigation water of poor quality can have deleterious effects on soils. However, the effect of drip irrigation on seasonal and long term (e.g. over 50 years) changes in soil chemical properties is poorly understood, complicated by the two-dimensional water flow patterns beneath drippers. Field and laboratory experiments were conducted, along with computer modelling, to evaluate morphological and physio-chemical changes in a typical Barossa Valley Red Brown Earth (Palexeralf, Chromosol or Lixisol) when drip irrigated under various changing management practices. This work focused on the following two management changes : (i) switching from long-term irrigation with a saline source to less saline water and (ii) gypsum (CaSO₄) application. A literature review (Chapter 1) focuses on the distribution, features, properties and management of Red Brown Earths in the premium viticultural regions of the Barossa Valley and McLaren Vale, South Australia. The effects of irrigation method and water quality on the rate and extent of soil deterioration are emphasised. The review also discusses the irrigation of grapes (Vitis vinifera) and summarises previous research into the effect of sodicity and salinity on grape and wine characteristics. This chapter shows the importance of Red Brown Earths to Australian viticulture, but highlights their susceptibility to chemical and physical degradation. Degradation may be prevented or remediated by increasing organic matter levels, applying gypsum, modifying cropping and through tillage practices such as deep ripping. Chapter 2 provides general information on the two study sites investigated, one in the Barossa Valley and the other at McLaren Vale. Local climate, geology, geomorphology and soils are described. Chapter 3 details laboratory, field and sampling methods used to elucidate changes in soil chemical and physical properties following irrigation. The genesis of the non-irrigated Red Brown Earth in the Barossa Valley is described in Chapter 4, and is inferred from geochemical, soil chemical, layer silicate and carbonate mineralogical data. Elemental gain and loss calculations showed 42% of original parent material mass was lost during the formation of A and A2 horizons, while the Bt1 and Bt2 horizons gained 50% of original parent material mass. This is consistent with substrate weathering and illuviation of clay from surface to lower horizons. The depth distributions of all major elements were similar ; the A horizon contained lower amounts of major elements than the remainder of the profile, indicating this region was intensely weathered. This chapter also compares the non-irrigated site to the adjacent irrigated site (separated by 10 m) to determine if the sites are pedogenically identical and geochemical changes from irrigation. Many of the differences between the non-irrigated and irrigated sites appear to be correlated with variations in quartz, clay, Fe oxide and carbonate contents, with little geological variation between the sample sites. In Chapter 5 morphological, chemical and physical properties of a non-irrigated and irrigated Red Brown Earth in the Barossa Valley are compared. Alternating applications of saline irrigation water (in summer) and non-saline rain water (in winter) have caused an increase in electrical conductivity (EC [subscript se]), sodium adsorption ratio (SAR), bulk density (ρ b) and pH. This has resulted in enhanced clay dispersion and migration. Impacts on SAR and ρ b are more pronounced at points away from the dripper due to the presence of an argillic horizon, which has greatly influenced the variations in these soil properties with depth and distance from the dripper. Dispersion and migration of clay were promoted by alternating levels of EC, while SAR remained relatively constant, resulting in the formation of a less permeable layer in the Bt1 horizon. Clay dispersion (breakdown of micro-aggregate structure) was inferred from reduced numbers of pores and voids, alterations in colouring (an indication that iron has changed oxidation state) and increased bulk density (up to 30 %). Eleven years of irrigation changed the soil from a Calcic Palexeralf (non-irrigated) to an Aquic Natrixeralf (irrigated) (Soil Survey Staff, 1999). These results, combined with data from Chapter 4, were used to develop a mechanistic model of soil changes with irrigation. Chapters 6, 7 and 8 describe field experiments conducted in the Barossa Valley and McLaren Vale regions. This data shows seasonal and spatial variations in soil saturation extract properties ( EC [subscript se], SAR [subscript se], Na [subscipt se] and Ca [subscript se] ). At the Barossa Valley site (Chapter 6) non-irrigated soils had low EC [subscript se], SAR [subscript se], Na [subscript se] and Ca [subscript se] values throughout the sampling period. The irrigated treatments included eleven years of drip irrigation with saline water (2.5 dS / m) and also gypsum application at 0, 4 or 8 tonnes/hectare in 2001 and 2002. Salts in the profile increased with gypsum application rate, with high levels occurring midwinter 2002 prior to rainfall leaching salts. SAR has declined with gypsum application, particularly in the A horizon and at 100 cm from the dripper in the Bt1 horizon ; this has the potential to reflocculate clay particles and improve soil hydraulic conductivity. Chapter 7 presents further results from the Barossa Valley site, this treatment had been irrigated for 9 years with saline water (2.5 dS / m) prior to switching to a less saline water source (0.5 dS / m). The soil also received gypsum at 0, 4 or 8 tonnes / hectare in 2001 and 2002. It was found that the first few years are critical when switching to a less saline water source. EC declines rapidly, but SAR requires a number of years, depending on conditions, to decline, resulting in a period during which the Bt1 horizon may become dispersed. Gypsum application increased the EC [subscipt se] but not to the EC [subscript se] levels of soil irrigated with saline water. Chapter 8 examines soil chemical properties of a McLaren Vale vineyard, irrigated with moderately saline water (1.2 dS / m) since 1987 and treated with gypsum every second year since establishment. This practice prevented the SAR (< 8) rising and a large zone of the soil profile (20 to 100 cm from dripper) has a high calcium level (> 5 mmol / L). However, irrigation caused the leaching of calcium beneath the dripper in both the A and B horizons (0 to 20 cm from dripper) (< 4 mmol / L). Chapters 9 and 10 interpret and discuss results from continuous monitoring of redox potential (Eh) and soil solution composition in the Barossa Valley vineyard, irrigated with saline or non-saline water, and gypsum-treated at 0 and 4 tonnes / hectare. Soil pore water solution (Chapter 9) collected by suction cups is compared to results obtained in chapters 6 and 7. The soil has extended zones and times of high SAR and low EC. This was particularly evident in the upper B horizon, where the SAR of the soil remained stable throughout the year while the EC was more seasonally variable with EC declining during the winter months. The A horizon does not appear to be as susceptible to clay dispersion (compared to the B horizon) because during periods of low EC the SAR also declines, which may be due to the low CEC (low clay and organic matter content) of this horizon. Chapter 10 presents redox potentials (Eh) measured using platinum redox electrodes installed in the A, A2 and Bt1 horizons to examine whether Eh of the profile varies with irrigation water quality and gypsum application. Saline irrigation water caused the B horizon to become waterlogged in winter months, while less saline irrigation water caused a perched watertable to develop, due to a dispersed Bt1 horizon. Application of gypsum reduced the soil Eh particularly in the A2 horizon (+ 500 to + 50 mV) during winter. Thus redox potential can be influenced by irrigation water quality and gypsum applications. Chapter 11 incorporated site data from the Barossa Valley non-irrigated site into a predictive mathematical model, TRANSMIT, a 2D version of LEACHM. This model was used to predict zones of gypsum accumulation during long-term irrigation (67 years). When applied over the entire soil surface, gypsum accumulated at 60 to 90 cm from the dripper in the B horizon; higher application rates caused increased accumulation. When applied immediately beneath the irrigation dripper, gypsum accumulated in a 'column' under the dripper (at 0 to 35 cm radius from the dripper), with very little movement away from the dripper. Also, the zone of accumulation of salts from high and low salinity irrigation water was investigated. These regions were found to be similar, although concentrations were significantly lower with low salinity water. In low rainfall years salts accumulated throughout the B horizon (35 - 150 cm), while in periods of high rainfall (and leaching) the A, A2 and Bt1 horizons (0 - 60 cm) were leached, although at greater depths (80 - 150 cm) salt concentrations remained high. Chapter 12 summarises results and provides an understanding of soil processes in drip irrigated soils to underpin improved management options for viticulture. This study combines results from redox and soil solution monitoring, mineralogy, elemental gains and losses, and seasonal soil sampling to develop a mechanistic model of soil processes, which was combined with computer modelling to predict future properties of the soil. Major conclusions and recommendations of this study include : - Application of saline irrigation water to soil then ameliorated with gypsum - The first application of gypsum was leached by the subsequent irrigation from extended regions of the soil. As Na continues to enter the system via irrigation water, gypsum needs to be regularly applied. Otherwise calcium will be leached through the soil and SAR increases. - Application of non-saline irrigation water to soil then ameliorated with gypsum - The soil was found to only require one application at 8 tons / ha as this reduced SAR sufficiently. As less salt is entering the soil, subsequent gypsum applications can be at a lower rate or less frequently than required for saline irrigation water. - Gypsum applied directly beneath the dripper systems distributes calcium to a narrow region of the soil, while large regions of the soil require amelioration (high SAR) and are not receiving calcium. Therefore, gypsum application through the drip system or only beneath the dripper should be combined with broad acre application. - A range of methods to sample vineyards is recommended for duplex soils, including the use of saturation extracts, sampling time, sampling location (distance from dripper) and depth of sampling. This work is critical for vineyard management and may be applicable to other Australian viticulture regions with Red Brown Earths. / Thesis (Ph.D.) -- University of Adelaide, School of Earth and Environmental Sciences, 2004.

Thesis (Ph. D.)--University of Rhode Island, 2006. / Typescript. Includes bibliographical references (leaves 178-197).

Increasing salinity has been a growing concern for users of waters from the Pecos River and the reservoirs it feeds in the Texas portion of the River's watershed. Irrigation water diverted from the river in the northern reach of this watershed is often only suitable for a limited number of crops, reducing harvesting options for local farmers. In the south, the Pecos feeds into the International Amistad Reservoir along the border with Mexico. During the 1990s, total dissolved solids concentrations in the reservoir rose as much as 10 mg/L per year and often approached the drinking water standard for potable water (1000 mg/L). Since this time, control efforts have focused on reducing the river's salinity, requiring the identification of salt sources. Hydrologic trend analysis and geochemical identification methods were used to determine these sources for the reach of the river between Red Bluff Reservoir and Brotherton Ranch. Between Red Bluff Reservoir and Coyanosa, flow diversions remove much of the flow that carries the salts, resulting in decreased salt loads, but also making the river more sensitive to evapotranspirative concentration. This sensitivity is evident in the river between Coyanosa and Girvin, where salinity begins to increase to the highest levels within the study area. However, salt loads increase here as well, indicating external salt sources as a contributor. The most substantial increase in bromide ions and the Br-/Cl- ratio appears between Grandfalls and Imperial, although no conclusion could be drawn regarding the identity of the source. The ratio continues to increase up to Girvin, where it appears that evapotranspirative concentration again has a significant effect. Here, several points drifted to the right of the groundwater mixing zones, plotting at values that were uncharacteristic of these sources.

The MixAlco process uses an anaerobic, mixed-culture fermentation to convert lignocellulosic biomass to carboxylate salts. The fermentation broth must be clarified so that only carboxylate salts, water, and minimal impurities remain. Carboxylate salts are concentrated by evaporation and thermally decomposed into ketones. The ketones can then be chemically converted to a wide variety of chemicals and fuels. The presence of excess lime in the thermal decomposition step reduced product yield. Mixtures of calcium carboxylate salts were thermally decomposed at 450 degrees C. Low lime-to-salt ratios (g Ca(OH)2/g salt) of 0.00134 and less had a negligible effect on ketone yield. In contrast, salts with higher lime-to-salt ratios of 0.00461, 0.0190, and 0.272 showed 3.5, 4.6, and 9.4% loss in ketone yield, respectively. These losses were caused primarily by increases in tars and heavy oils; however, a three-fold increase in hydrocarbon production occurred as well. To predict ketone product distribution, a random-pairing and a Gibbs free energy minimization model were applied to thermal decompositions of mixed calcium and sodium carboxylate salts. Random pairing appears to better predict ketone product composition. For sodium and calcium acetate, two types of mixed sodium carboxylate salts, and two types of mixed calcium carboxylate salts, activation energy (EA) was determined using three isoconversional methods. For each salt type, EA varied significantly with conversion. The average EA for sodium and calcium acetate was 226.65 and 556.75 kJ/mol, respectively. The average EA for the two mixed sodium carboxylate salts were 195.61, and 218.18 kJ/mol. The average EA for the two mixed calcium carboxylate salts were 232.78, and 176.55 kJ/mol. In addition, three functions of conversion were employed to see which one best modeled the experimental data. The Sestak-Berggren model was the best overall. Possible reactor designs and configurations that address the challenges associated with the continuous thermal decomposition of carboxylate salts are also presented and discussed. Methods of fermentation broth clarification were tested. Flocculation showed little improvement in broth purity. Coagulation yielded broth of 93.23% purity. Filtration using pore sizes from 1 micrometer to 240 Daltons increased broth purity (90.79 to 98.33%) with decreasing pore size.

To predict the effectiveness of land reclamation, it is important to understand how water and solutes are transported within reconstructed landscapes. The objective of this study was to examine the influence of preferential flow on salt leaching in reclamation soil covers. The study site was a reconstructed landscape where saline-sodic minespoil from oil sands mining was capped with layers of glacial and peat mix soil. Preferential flow was investigated using laboratory column experiments and in situ adsorptive dye and conservative tracer experiments.<p> Results from column experiments and dye tracer experiments indicate that preferential flow is an important and prevalent mechanism of solute transport. Column experiments, which used time-domain reflectometry to monitor the transport of a chloride tracer through an undisturbed core of peat mix soil, determined immobile water fractions (èim/è) ranging from 80-99% and diffusive mass transfer rates (á) between 0.15 - 2.0 h-1. Breakthrough curves showed the early arrival of chloride and extended tailing. Dye tracer experiments, in which Brilliant Blue dye was applied in solution to the soil surface, were carried out at 6 hillslopes plots. Approximately 24 hours after dye application, a vertical soil face was excavated to reveal stained flow patterns. Preferential flow as macropore flow, fingering, and / or funneling was observed at each plot.<p> Results from the conservative tracer field study indicated soil solutes were flushed by a combination of vertical and lateral flow processes. A large pulse of bromide and chloride was applied across the lower slope of the 0.35-m cover. Soil sampling at approximately 1 and 2 years later determined vertical leaching, lateral translocation downslope, and upwards movement of soil solutes. Matrix flow during the spring melt, combined with matrix flow and / or preferential flow during summer and fall periods, was responsible for the vertical leaching of solutes. Subsurface flow generated in response to the spring melt or due to differences in soil hydraulic conductivity was responsible for the lateral transport of solutes. As a result of advective or diffusive processes, solutes were transported upwards into the overlying soil. These results suggested that despite the existence of preferential flow, there were other mechanisms of solute transport which served to leach and flush salts from the soil.

The viscoelastic and creep properties of salt create challenges in the design of salt mines. Salt undergoes steady state creep for a long period of time, and the time of failure is not easily predicted. Developing functions for creep behavior is important in predicting the deformation of salt pillars. Through literature reviews, it was found that there are many relationships to determine the deformation rate of salt specimens through constitutive models. Mine panels have also been modeled to understand the stress and deformational behavior of the pillars. The purpose of this was project was to develop a relationship that determines the convergence rate from knowing the pillar width to pillar height ratio and thickness of the salt strata immediately above and below the mine. The third power law was adopted in the modeling of salt pillars, which is applicable to low stresses of less than 10 MPa that is typical of salt mine conditions. The finite difference software, FLAC3D was used for the simulations of salt pillar models. A square pillar was modeled using four pillar width to pillar height ratios from 1.5 to 4.6. In mining practices, the pillar width to pillar height ratios are designed to be 1.0 to 5.0. Three sets of pillar dimensions were used for each pillar width to pillar height ratio, this was done to determine whether different room and pillar dimensions for each pillar width to pillar height ratio resulted in different convergence rates. Eight salt thicknesses of 0 m to 26 m were modeled for each set of pillar dimensions, which was sufficient to determine the effect of salt thickness on convergence rate. From the modeled results, general trends among the various pillar width to pillar height ratios were observed. The convergence rate increased as the pillar width to pillar height ratio decreased. In addition, an exponential relationship was found between the convergence rate and the pillar width to pillar height ratio. There was a strong correlation between convergence values calculated from the developed function and the modeled values for the power law exponent of three. The developed expression can be used to estimate the convergence rate due to pillar compression and room convergence.

To predict the effectiveness of land reclamation, it is important to understand how water and solutes are transported within reconstructed landscapes. The objective of this study was to examine the influence of preferential flow on salt leaching in reclamation soil covers. The study site was a reconstructed landscape where saline-sodic minespoil from oil sands mining was capped with layers of glacial and peat mix soil. Preferential flow was investigated using laboratory column experiments and in situ adsorptive dye and conservative tracer experiments.<p> Results from column experiments and dye tracer experiments indicate that preferential flow is an important and prevalent mechanism of solute transport. Column experiments, which used time-domain reflectometry to monitor the transport of a chloride tracer through an undisturbed core of peat mix soil, determined immobile water fractions (èim/è) ranging from 80-99% and diffusive mass transfer rates (á) between 0.15 - 2.0 h-1. Breakthrough curves showed the early arrival of chloride and extended tailing. Dye tracer experiments, in which Brilliant Blue dye was applied in solution to the soil surface, were carried out at 6 hillslopes plots. Approximately 24 hours after dye application, a vertical soil face was excavated to reveal stained flow patterns. Preferential flow as macropore flow, fingering, and / or funneling was observed at each plot.<p> Results from the conservative tracer field study indicated soil solutes were flushed by a combination of vertical and lateral flow processes. A large pulse of bromide and chloride was applied across the lower slope of the 0.35-m cover. Soil sampling at approximately 1 and 2 years later determined vertical leaching, lateral translocation downslope, and upwards movement of soil solutes. Matrix flow during the spring melt, combined with matrix flow and / or preferential flow during summer and fall periods, was responsible for the vertical leaching of solutes. Subsurface flow generated in response to the spring melt or due to differences in soil hydraulic conductivity was responsible for the lateral transport of solutes. As a result of advective or diffusive processes, solutes were transported upwards into the overlying soil. These results suggested that despite the existence of preferential flow, there were other mechanisms of solute transport which served to leach and flush salts from the soil.

No description available.