Different aspects of natural organic matter composition and cycling have been studied using solid-state 13C and 31P Nuclear Magnetic Resonance (NMR) spectroscopy. Depending on the specific study, complementary analytical techniques such as elemental, isotopic and molecular analyses have also been applied. Samples from a variety of environments were examined including ocean waters, marine sediments and atmospheric aerosols. Studies from all these environments illustrate differences in natural organic matter composition resulting from various factors such as sources, cycling mechanisms and redox conditions. In the marine water column, organic matter of two different size fractions (dissolved and particulate) is found to have distinctly different bulk chemical and isotopic compositions. Overall, this indicates that particulate organic matter does not form from the simple physical aggregation of dissolved organic matter, and dissolved organic matter is not the primary source for particulate organic matter. Comparison of carbon and phosphorus compositional changes with depth in the ocean within the dissolved and particulate fractions reveals differences in cycling mechanisms. In the marine water column, selective mineralization of specific carbon compounds such as carbohydrates and amino acids occurs relative other species such as lipids. Whereas for phosphorus, the relative proportion of the different functional groups are unvarying with depth. In marine sediments, NMR spectroscopy reveals P cycling for specific phases such as polyphosphates is a function of sediment redox conditions. In atmospheric aerosols 13C NMR spectroscopy shows differences in water-soluble organic carbon composition from urban versus biomass burning sources. Urban aerosols have higher aliphatic and lower aromatic compound contents relative to samples derived from biomass burning. The results of these studies provide new insights into carbon and phosphorus cycling in the environment and demonstrate the capabilities of solid-state NMR as a tool for investigating natural organic matter composition.

Caisson or pier foundations are encountered as part of the foundation system of tall structures such as bridges, transmission towers, heliostats, etc, and correspond to rigid blocks of length-to-diameter (D/B) ratio on the order of D/B = 2-6. As a result of their geometry and stiffness characteristics, the mechanisms of load transfer from the superstructure to the surrounding soil and their kinematic response to seismic wave propagation are governed by a complex stress distribution at the pier-soil interface, which cannot be adequately represented by means of simplified Winkler models for shallow foundations or flexible piles. Continuum model solutions, such as 3D finite elements (FE) cannot be employed frequently in practice for the design of non-critical facilities due to the cost and effort associated with these analyses. The objective of this work is to develop a Winkler-type model for the analysis of transversely-loaded caissons, which approximately accounts for all the main soil resistance mechanisms mobilized, while retaining the advantages of simplified methodologies for design at intermediate levels of target accuracy. Investigation of the governing load-transfer mechanisms and development of complex spring functions is formulated on the basis of 3D FE simulations. Initially, the soil-structure stiffness matrix is computed by subjecting the pier to transverse static and dynamic loading at the top, and numerically estimating the response. Complex frequency-dependent functions are next developed for the spring constants by equating the stiffness matrix terms to the analytical expressions developed for the four-spring model. Sensitivity analyses are conducted for optimization of the truncated numerical domain size, finite element size and far-field dynamic boundary conditions to avoid spurious wave reflections. Simulations are next conducted to evaluate the transient response of the foundation subjected to vertically propagating shear waves, and results are compared to the response predicted by means of the 4-spring model. Finally, the applicability of the method is assessed for soil profiles with depth-varying properties. While the methodology developed is applicable for linear elastic media with no material damping, the expressions of complex spring functions may be extended to include hysteretic damping, nonlinear soil behavior and soil-foundation interface separation, as shown in the conclusions.

In reality, dynamic response of a structure supported on a compliant soil may vary significantly from the response of same structure when supported on a rigid base. A parametric study is conducted for the analysis of the variation in the global and the local deformation demands caused by the inertial soil-structure interaction effects. For the purposes of the study, nonlinear dynamic analyses are performed on 7 steel moment-resisting frame models, which are prepared by the virtue of fixed-base and flexible-base (interacting) conditions. Foundation is modeled with the Truncated Cone Model (Wolf, 1994) with the frequency independent coefficients. Free-field earthquake acceleration records are selected to conform to NEHRP equivalent Site Classes C and D. The study is limited to the structures founded on surface rigid mat foundations subjected to vertically propagating horizontally polarized coherent shear waves. Statistical analysis based on multiple linear regression procedure is performed to represent the variation in the response. Within the scope of the study, the wave parameter and the aspect ratio are observed to be directly proportional to the variation in the response, as a general trend. Maximum beneficial contribution of the SSI is found to be 6% in both global and local deformation demands. In addition, the contribution of inertial interaction effects is found to be in a decreasing trend for the increasing levels of ductility demands. Finally, upper limits of wave parameter for H/R=0.5, 1, 2 and 3 are calculated where the variation in the demands are capped at 1.0.

In this study, weight optimization of two dimensional steel frames is carried out in which the flexibility of beam-to-column connections and the soil-structure interaction are considered. In the analysis and design of steel frames, beam-tocolumn connections are assumed to be either fully rigid or perfectly pinned. However, the real behavior of beam-to-column connections is actually between these extremes. Namely, even the simple connections used in practice possess some stiffness falling between these two cases mentioned above. Moreover, it is found that there exists a nonlinear relationship between the moment and beam-to-column rotation when a moment is applied to a flexible connection. These partially restrained connections influence the drift (P- effect) of whole structure as well as the moment distribution in beams and columns. Use of a direct nonlinear inelastic analysis is one way to account for all these effects in frame design. To be able to implement such analysis, beam-to-column connections should be assumed and modeled as semi-rigid connections. In the present study, beam-to-column connections are modeled as &ldquo / end plate without column stiffeners&rdquo / and &ldquo / top and seat angle with web angles&rdquo / . Soil-structure interaction is also included in the analysis. Frames are assumed to be resting on nonlinear soil, which is represented by a set of axial elements. Particle swarm optimization method is used to develop the optimum design algorithm. The Particle Swarm method is a numerical optimization technique that simulates the social behavior of birds, fishes and bugs. In nature fish school, birds flock and bugs swarm not only for reproduction but for other reasons such as finding food and escaping predators. Similar to birds seek to find food, the optimum design process seeks to find the optimum solution. In the particle swarm optimization each particle in the swarm represents a candidate solution of the optimum design problem. The design algorithm presented selects sections for the members of steel frame from the complete list of sections given in LRFD- AISC (Load and Resistance Factor Design, American Institute of Steel Construction). Besides, the design constraints are implemented from the specifications of the same code which covers serviceability and strength limitations. The optimum design algorithm developed is used to design number of rigid and semi-rigid steel frames.

Numerical assessment of soil structure interaction problems require heavy computational efforts because of the dynamic and iterative (nonlinear) nature of the problems. Furthermore, modeling soil-structure interaction may require

Seismic safety of underground structures (culvert, subway, natural gas and water sewage systems) plays a major role in sustainable public safety and urban development. Very few experimental data are currently available and there is not generally accepted procedure to estimate the dynamic pressures acting on underground structures. This study aims to enhance the state of prevalent information necessary in understanding the dynamic behavior of box culverts and the stresses acting under dynamic excitations through experimental analyses. For this purpose, a series of shaking table tests were conducted on box-type culverts buried in dry sand. To simulate the free-field boundary conditions, a laminar box was designed and manufactured for use in a 1-g shake table. Four culvert models having different rigidities were tested under various harmonic motions in order to examine the effect of flexibility ratio on dynamic lateral soil pressures. Based on the tests results, a simplified dynamic pressure distribution acting on sidewalls of the culvert model was suggested. Then, a dynamic lateral coefficient was defined for the proposed peak pressure value in the distribution. The values of this coefficient were obtained as a function of shear strain and relative stiffness between the soil and underground structure. Finally, a simplified frame analysis approach was suggested for the assessment of the forces on the structure, to help to carry out a preliminary design of box-type culverts. In this approach, it was assumed that the culvert was fixed at bottom and subjected to lateral stresses on sidewalls and shear stresses on the upper face. For the confirmation of the method, centrifuge tests were conducted on a box-type culvert model under the Seventh Framework Programme of European Union with Grant Agreement No.227887. Results show that the proposed simplified procedure can be used in reasonable accuracy as a practical approach for the preliminary assessment of box-type culverts buried in dry sand under seismic action.

The coupled and uncoupled consolidation theories for saturated-unsaturated soils have been discussed. A new method for constructing the constitutive surfaces for saturated-unsaturated soils has been proposed. The consolidation processes for saturated-unsaturated soils have been explained by thermodynamic analogue. One dimensional consolidation theory for saturated-unsaturated soils is presented and a new method is proposed to calculate the immediate settlement, total settlement and the time history of the consolidation settlement manually in the same way as what we have done for saturated soils with a higher accuracy. It makes the consolidation theory of unsaturated soils as applicable as that of saturated soils. This method can also be used to perform uncoupled two or three dimensional consolidation calculation for both expansive soils and collapsible soils. From the analysis, the equivalent effective stress and excessive pore water pressure can be easily calculated. At the same time, the physical meanings for the parameters in the constitutive laws for saturated-unsaturated are illustrated. A new set of the differential equations for the coupled two or three dimensional consolidation of saturated-unsaturated soils are proposed, together with the corresponding method to solve the differential equations. It is also proved numerically and analytically that during the consolidation process the Mandel-Cryer effect exists for unsaturated expansive soils and there is a ??reverse?? Mandel-Cryer effect for unsaturated collapsible soils. A new method is proposed to estimate the volume change of expansive soils. A complete system is proposed for the numerical simulation of residential buildings on expansive soils. The strength of this method lies in its use of simple and readily available historic weather data such as daily temperature, solar radiation, relative humidity, wind speed and rainfall as input. Accurate three dimensional predictions are obtained by integrating a number of different analytical and numerical techniques: different simulation methods for different boundary conditions such as tree, grass, and bare soils, coupled hydro-mechanical stress analysis to describe deformation of saturated-unsaturated soils, jointed elements simulation of soil-structure interaction, analysis of structure stress moment by general shell elements, and to assess structural damage by the smeared cracking model. The real-time and dynamic simulation results are consistent with filed measurements.

Pipe jacking, has seen a rise in popularity, particularly in urban areas where infrastructure does not permit cut-and-cover methods. As pipe jacking has becomes more commonplace, engineers are pushing the limits of the technology more and more by designing longer drives in more difficult ground conditions. Lubrication is essential to reduce the frictional resistance generated at the pipe-soil interface. Even though lubrication is widely utilized, there is not a clear understanding of the conditions required to obtain the full benefit of lubrication. This dissertation focuses on bentonite slurry characteristics and interface behavior under different lubricating conditions with the goal to further the understanding of the mechanisms responsible for the large friction reductions observed in the field. An interface shear device capable of measuring interface behavior on pipe surfaces was used to perform tests under two lubricating conditions. Pipes were sheared against a mixture of sand and slurry and the effect of the slurry was quantified. In another series of tests, slurry was injected at the pipe-soil interface. An axisymmetric interface shear device was developed to further investigate the lubrication mechanism associated with injection of slurry into sand. The device was designed to inject slurry through injection ports built into a shaft displaced within a sealed sand-filled chamber. A series of tests were performed on dry sand as well as sand where water or slurry was injected during shearing. The effect of sand type and viscosity are also investigated. Findings from the experimental studies are related back to full-scale behavior with the objective of assessing the lubrication methods and their effectiveness. A rational procedure for predicting non-lubricated and lubricated jacking forces is proposed to optimize design and serve as a framework for evaluating jacking forces in the field.

Serving as critical gateways for international trade, seaports are pivotal elements in transportation networks. Any disruption in the activities of port infrastructures may lead to significant losses from secondary economic effects, and can hamper the response and recovery efforts following a natural disaster. Particularly poignant examples which revealed the significance of port operations were the 1995 Kobe earthquake and 2010 Haiti earthquake in which liquefaction and lateral spreading of embankments imposed severe damage to both structural and non-structural components of ports. Since container wharf structures are responsible for loading and unloading of cargo, it is essential to understand the performance of these structures during earthquakes. Although previous studies have provided insight into some aspects of the seismic response of wharves, limitations in the modeling of wharf structures and the surrounding soil media have constrained the understanding of various features of the wharf response. This research provides new insights into the seismic behavior of wharves by using new and advanced structure and soil modeling procedures to carry out two and three-dimensional seismic analyses of a pile-supported marginal wharf structure in liquefiable soils. Furthermore, this research investigates the interaction between cranes and wharves and closely assesses the role of wharf-crane interaction on the response of each of these systems. For this purpose, the specific effect of wharf-crane interaction is studied by incorporating advanced models of the crane with sliding/uplift base conditions. To reduce the computational time required for three-dimensional nonlinear dynamic analysis of the wharf in order to be applicable for probabilistic seismic demand analysis, a simplified wharf model and an analysis technique are introduced and verified. In the next step probabilistic seismic demand models (PSDMs) are generated by imposing the wharf models to a suit of ground deformations of the soil embankment and pore water pressure generated for this study through free-field analysis. Convolving PSDMs and the limit states, a set of fragility curves are developed for critical wharf components whose damage induces a disruption in the normal operation of ports. The developed fragility curves provide decision makers with essential tools for maximizing investment in wharf retrofit and fill a major gap in seismic risk assessment of seaports which can be used to assess the regional impact of the damage to wharves during a natural hazard event.

The consequences of land use choices on soil water and gas transport properties are significant for gas and water flux in agricultural environments. Spatial and temporal patterns and associations of soil water and soil gas characteristics and processes in different land uses are not well understood. The objectives of this study were to 1) characterize soil structure under crop and grass systems, 2) quantify spatial patterns and associations of soil physical characteristics in crop and grass systems, and 3) quantify spatial and temporal patterns and associations of CO2 and N2O fluxes. The research was conducted in a 60 by 80 m field divided into grass and crop systems. Sixty sampling points were distributed in four transects with 5- and 1-m spatial intervals between measurement points. Gas fluxes were measured, at two-week time intervals, 22 times during a year. Pore size distribution was more homogeneous and more continuous pores were found in the grass than in the crop system. The spatial variability of most selected soil physical characteristics was more structured in the crop than in the grass system, which reflected the impact of land use and soil structure on their spatial patterns. CO2 flux was dependent for a longer distance in the grass than in the crop system, however, the two land-use systems exhibited similar spatial ranges of N2O flux. Gas fluxes were temporally dependent for a longer period in the grass than in the crop system. The spatial associations between CO2 and N2O fluxes and selected biochemical and physical factors depended on the flux sampling season and land use. Soil temperature was the dominant controlling factor on the temporal variability of CO2 and N2O fluxes but not on the spatial behavior. Considering the spatial and temporal ranges and dependency strength of soil variables helps identify efficient sampling designs that can result in better time and resource management. Spatial and temporal relationships between the selected soil variables also improve understanding soil management and sampling soil variables. This study provides the baseline and recommendations for future investigations specifically for sampling designs, soil management, and predictions of different soil processes related to gas fluxes.