This thesis is a part of a project run by The Department of Geography, Faculty of Science in Charles University in Prague. This project deals with processes in floodplains of the Lužnice, the Stropnice and the Blanice rivers. The research in the floodplain of the Lužnice started in the year 2008 and is focused on the interaction between groundwater and surface water. The monitored territory it is situated to the south of a locality called Halámky and its area is 0,6 km2. In this thesis mainly the outputs of the research were elaborated. The highlighted points were the interpretation of the groundwater level behaviour, the groundwater streaming orientation in the area and interaction between groundwater and surface water. The outputs of this thesis can be used in the next stages of the project.

A series of five east-west and two north-south hydrostratigraphic cross sections were drawn from drillers' logs of water wells within the southern half of Cache Valley, Utah. These cross-sections demonstrate that ground water flow to streams is restricted by a continuous low- II permeability layer, nearly 100-feet thick. This layer was correlated to the lake-bottom deposits of the Bonneville (30,000 -13,000 years ago) and Little Valley (140,000 - 90,000 years ago) cycles of the ancient Lake Bonneville. The most productive aquifers in the valley, collectively termed the principal aquifer , are in the southeast corner , approximately between Smithfield and Hyrum, and between the eastern valley margin and the valley center. Sands and gravels of the principal aquifer were deposited as alluvial fans and deltas by streams draining the Bear River Range. Ground water chemistry in the principal aquifer system is of the calcium-magnesium bicarbonate type with total dissolved solids (TDS) averaging about 300 ± 100 mg/L. TDS and the relative proportions of sodium, potassium, and chloride increase down flowpath, from recharge areas in the east to discharge areas in the west. Oxygen-18 (18O) and deuterium (D) analyses were performed on precipitation samples at three locations on the east valley benches, four surface water samples from streams entering the valley, and fourteen ground water samples from either wells or springs. Precipitation and surface water values generally plotted along the Global Meteoric Water Line (GMWL), although the precipitation values plotted significantly lower on the GMWL than the surface water values. Of the ground water samples, twelve from the principal aquifer generally clustered near the surface water data points, suggesting that water from streams, rather than infiltrating precipitation, recharges the principal aquifer. Twelve ground water samples were analyzed for tritium. The tritium values of eight samples from wells or springs in the principal aquifer suggest recharge after 1952. Two samples with tritium values dating prior to 1952 are from wells in the principal aquifer, and two are from wells west of the principal aquifer. Four samples were analyzed for 14C. Two of these wells were completed in the principal aquifer and two west of it. Correcting for partial carbon dilution, the age difference between the different areas is on the order of tens of thousands of years.

This research had two main objectives: quantify surface-water and groundwater interactions along a stream reach, and determine the hydraulic conductivity at the site where two reservoirs are proposed. The objectives of this research aim to help maintain stream ecology and increase surface water storage for recreational and industrial purposes. The stream reach, located in the Pascagoula River Basin of southeast Mississippi, begins at Lake Okatibbee and terminates at Pascagoula into the Gulf of Mexico. Four USGS continuous gauging stations provided more than forty years of stream discharge data for a hydrograph baselow-recession analysis, which determined the baseflow component within the stream. The analysis showed that baseflow decreases along the stream reach and increases again before reaching the Gulf of Mexico. Thirteen borehole samples were collected at the sites of the proposed reservoirs in George County, Mississippi to determine the hydraulic conductivity of the sediments, which showed high a hydraulic conductivity.

Water conservation practices are being widely implemented to alleviate sediment and nutrient losses from agricultural land and unsustainable groundwater use for irrigation. Tailwater recovery (TWR) systems are conservation practices being implemented to collect and store runoff to reduce nutrient losses and provide a source of irrigation water. This collection of research is focused on evaluating TWR systems through the following actions: 1) investigate ability to reduce solids and nutrients delivery to downstream systems, 2) compare differences in solid and nutrient concentrations in surface water samples from TWR systems to irrigation water from a TWR systems; 3) determine the potential to irrigate water containing solids and nutrients; 4) quantify a water budget for TWR systems; 5) conduct cost and benefit analyses of TWR systems; and 6) analyze economic cost to reduce solids and nutrients and to retain water. Tailwater recovery systems did not significantly reduce concentrations of solids and nutrients; however, loads of solids, P, and N were significantly reduced by 43%, 32% and 44%, respectively. Mean nutrient loads per hectare available to be recycled onto the landscape were 0.20 kg ha-1 P and 0.86 kg ha-1 N. Water budget analyses show these systems save water for irrigation but were inefficient. Net present value (NPV) and benefit cost ratios were positive and >1 for producers who owned the land, but remained <1 if land was rented. However, beyond improvements to irrigation infrastructure, farms with a TWR system installed lost NPV of $51 to $328 per ha. Mean total cost to reduce solids using TWR systems ranged from $0 to $0.77 per kg, P was $0.61 to $3,315.72 per kg, and N was $0.13 to $396.44 per kg. The mean total cost to save water using TWR systems ranged from $189.73 to $628.23 per ML, compared to a mean cost of groundwater of $13.99 to $36.17 per ML. Mechanistically, TWR systems retain runoff on the agricultural landscape, thereby reducing the amount of sediment and nutrients entering downstream waterbodies and provide an additional source of water for irrigation; however, more cost-effective practices exist for nutrient reduction and providing water for irrigation.

Many types of contaminants of emerging concern (CECs), including per- and poly-fluoroalkyl substances (PFAS), have been found in leachate of operating municipal landfills. However, information on CECs in leachate of historic landfills (≥3 decades since closure, often lacking engineered liners or leachate collection systems) and the related risk posed from groundwater plumes discharging to nearby aquatic ecosystems is limited. In this study, 48 samples of leachate-impacted groundwater were collected from 20 historic landfills in Ontario, Canada. The CECs measured included artificial sweeteners (ASs), PFAS, organophosphate esters (OPE), pharmaceuticals, bisphenols, sulfamic acid, perchlorate, and substituted phenols. Several landfills, including ones closed in the 1960s, had total PFAS concentrations similar to those previously measured at modern landfills, with a maximum observed here of 12.7 μg/L. Notably elevated concentrations of several OPE, cotinine, and bisphenols A and S were found at many 30-60 year-old landfills. There was little indication of declining concentrations with landfill age, suggesting historic landfills can be long-term sources of CECs to groundwater. A full-year field study was performed on a 0.5-km reach of an urban stream receiving contaminated groundwater from nearby historic landfills. Elevated concentrations of ammonium, the AS saccharin, an indicator of old landfill leachate, and CECs (e.g., maximum total PFAS of 31 μg/L) in the shallow discharging groundwater were relatively stable across the seasons but were spatially restricted by hyporheic exchange and discharge of other groundwater. This indicates a patchy but long-term exposure for endobenthic organisms, which are rarely monitored. Stream water concentrations were more dilute, but increased markedly across the landfill stretch, and showed signs of increases in winter and after rain/snowmelt events. These findings provide guidance on which CECs may require monitoring at historic landfill sites and suggest how landfill monitoring programs could be improved to fully capture the risk to receiving water bodies. / Thesis / Master of Science (MSc) / Historic landfills are a known source of groundwater contamination. This study investigated whether these landfills contain new groups of chemicals, called contaminants of emerging concern (CECs), which are suspected to pose serious environmental and human health risks. This study found many CECs at high concentrations in most of the 20 historic landfill sites investigated, even those closed up to 60 years. A full-year investigation at one historic landfill site showed that organisms living in the sediments of a nearby stream are exposed to high concentrations all year long. Concentrations in the stream increased as it flowed past the landfill, and may be higher in winter and after rains, times monitoring is rarely done. The elevated concentrations of harmful contaminants in this water are potentially threatening the stream ecosystem. Operators of historic sites should consider testing for CECs and ensure that monitoring strategies accurately evaluate the risk posed to the environment.

The utilization of membrane treatment for the production of potable water has become more prevalent in today's industry. As drinking water regulations become more stringent this trend is expected to continue. Widespread use is also a result of membrane treatment being the best available treatment in many cases. While membrane treatment is a proven technology that can produce a consistently superior product to conventional treatment methods, membrane fouling and concentrate disposal are issues that drive up the cost of membrane treatment and can effectively eliminate it from consideration as a treatment alternative. This research focused on membrane fouling. A series of filtration experiments were conducted on various membranes to investigate the physical and chemical factors that influence fouling. The effects of both organic and colloidal fouling were explored by conducting research on various commercial membranes and experimental membranes by Saehan Industries, Inc. (Saehan). Saehan's membranes were in various stages of development in their process of creating a more fouling resistant membrane (FRM). Various hydrodynamic and chemical conditions were used to characterize the evolution of the Saehan commercial products to the experimental FRMs. The developmental stage of the membrane tested included analysis of the various trade secret coating techniques termed single, double, and special. A proprietary post-treatment process was also utilized in combination with each of the coating techniques. The developmental membranes were also compared to commercially available FRMs. The existing FRMs showed better fouling resistance than Saehan's commercially available products in high organic surficial groundwater testing. Synthetic colloidal water testing demonstrated the superior performance of the FRMs, but was not acute enough to differentiate the fouling performance within the group of FRMs or Saehan products. Average roughness decreased slightly as coating technique progressed from single to double to special. Post-treatment increased roughness in single coated membranes and reduced the roughness in double and special coated membranes. The relative charge differences in the developmental membranes were exhibited among non post-treated membranes. Post-treatment membranes did not demonstrate relative surface charge differences consistent with the manufacturer. Initial mass transfer coefficient, determined by clean water testing, increased as coating moved from single to double to special. Clean water testing showed increased initial mass transfer coefficient for membranes with post-treatment. Single coated membranes showed the best salt rejection capability among non post-treated membranes. Post-treatment increased selectivity for all membrane coating techniques. The coating effect on fouling potential had an inverse relationship between single coated versus double and special coated membranes. The post-treatment increased fouling resistance for the single coated membranes, but decreased fouling resistance of double and special coated membranes. The SN7 membranes showed the best performance of the developmental membranes.

No description available.

The San Joaquin Valley is part of the Great Central Valley of California, a major agricultural centre and food supplier for the United States. This area has significant water management concerns given the very high water demand for an increasing state population and for intense irrigation in a hot, temperate to semi-arid climate where the overall rate of evapotranspiration (ET) is high, and the overall rate of precipitation is low. Irrigation heavily relies upon groundwater and surface water extractions. Through the historical and current concerns of regional water resources reliability, land surface subsidence, water quality issues, and the health of ecosystems, a need for regional-scale water resource management and planning has developed. The physically-based surface-subsurface HydroGeoSphere (HGS) model is used to examine the regional-scale hydrologic budget of a large portion of the San Joaquin Valley. The objective of this investigation is to develop a steady-state groundwater-surface water model of the San Joaquin Valley representative of predevelopment hydrologic conditions. The groundwater-surface water system has undergone drastic changes since the employment of groundwater and surface water extractions for irrigation and mining, and is still responding to past and present stresses. The only certain stable initial condition must therefore be that of the natural system. The model input parameters were constrained by all relevant available hydrologic data. The model was not calibrated to subsurface hydraulic heads or river flows. However, the model does provide a fair match between simulated and actual estimated water table elevations. Historic river flow estimates were not used to calibrate the model, because data consistent with that collected by Hall (1886) and representative of the natural system were not available. For this investigation, water enters through precipitation and the inflow of major rivers only. The subsurface domain is bounded by no-flow boundaries, and groundwater is therefore only able to exit the subsurface through discharge to surface water features or through ET. Surface water is only able to exit the model through discharge via the San Joaquin River and through ET. Average river inflows circa 1878 to 1884 documented by Hall (1886) were applied where the rivers enter into the valley. The spatially variable average rate of precipitation (years 1971 to 2000) from a PRISM dataset was applied to the top of the model. The spatially variable long term average potential ET rates from the California Department of Water Resources (DWR) et al. (1999) were applied to the top of the model. Averaged overland flow parameters and vegetation factors needed to calculate actual ET were specified at the top of the model based on literature values and the 1874 spatial distribution of natural vegetation provided by California State University at Chico et al. (2003). Hydrogeological data including hydraulic conductivities, porosities, specific storage, and unsaturated zone properties are based on literature values from other relevant studies. The resulting steady state model is therefore characterized by historical long term average data assumed to be representative (as close as possible) of the flow system circa 1848. Results indicate that the natural hydrologic setting of the San Joaquin Valley is a complex one. Complex hydrologic processes, including significant groundwater-surface water interaction along the major rivers and within wetland areas formed by flooded surface water, as well as ET and impacted root zone processes were identified in the model domain. Identification and simulation of the complex recharge and discharge relationships in the model domain sheds insight into the hydrologic nature of some historic natural wetlands. Evapotranspiration is a very significant sink of both surface water and groundwater (44.8 % of the water balance input), and has a major impact on hydrologic processes in the root zone. The presence and path of the major rivers in the domain are well defined in the model output and agree well with their actual locations. The model simulates gaining and losing reaches of the major rivers, replicating the historic recharge-discharge relationship documented by others. The general location, formation, and hydrologic processes of some significant wetlands simulated by the model have a fair agreement with historical records. As mentioned above, there is also a fair match between simulated and actual estimated water table elevations. Successful simulation of the complex hydrologic processes and features that characterize the predevelopment hydrologic conditions of the San Joaquin Valley and that resolve the water balance of the natural system underscores the importance and necessity of using an integrated model. This steady state model should serve as a reasonable initial condition for future transient runs that bring the model up to current hydrologic conditions capable of estimating present and future water budgets.

The San Joaquin Valley is part of the Great Central Valley of California, a major agricultural centre and food supplier for the United States. This area has significant water management concerns given the very high water demand for an increasing state population and for intense irrigation in a hot, temperate to semi-arid climate where the overall rate of evapotranspiration (ET) is high, and the overall rate of precipitation is low. Irrigation heavily relies upon groundwater and surface water extractions. Through the historical and current concerns of regional water resources reliability, land surface subsidence, water quality issues, and the health of ecosystems, a need for regional-scale water resource management and planning has developed. The physically-based surface-subsurface HydroGeoSphere (HGS) model is used to examine the regional-scale hydrologic budget of a large portion of the San Joaquin Valley. The objective of this investigation is to develop a steady-state groundwater-surface water model of the San Joaquin Valley representative of predevelopment hydrologic conditions. The groundwater-surface water system has undergone drastic changes since the employment of groundwater and surface water extractions for irrigation and mining, and is still responding to past and present stresses. The only certain stable initial condition must therefore be that of the natural system. The model input parameters were constrained by all relevant available hydrologic data. The model was not calibrated to subsurface hydraulic heads or river flows. However, the model does provide a fair match between simulated and actual estimated water table elevations. Historic river flow estimates were not used to calibrate the model, because data consistent with that collected by Hall (1886) and representative of the natural system were not available. For this investigation, water enters through precipitation and the inflow of major rivers only. The subsurface domain is bounded by no-flow boundaries, and groundwater is therefore only able to exit the subsurface through discharge to surface water features or through ET. Surface water is only able to exit the model through discharge via the San Joaquin River and through ET. Average river inflows circa 1878 to 1884 documented by Hall (1886) were applied where the rivers enter into the valley. The spatially variable average rate of precipitation (years 1971 to 2000) from a PRISM dataset was applied to the top of the model. The spatially variable long term average potential ET rates from the California Department of Water Resources (DWR) et al. (1999) were applied to the top of the model. Averaged overland flow parameters and vegetation factors needed to calculate actual ET were specified at the top of the model based on literature values and the 1874 spatial distribution of natural vegetation provided by California State University at Chico et al. (2003). Hydrogeological data including hydraulic conductivities, porosities, specific storage, and unsaturated zone properties are based on literature values from other relevant studies. The resulting steady state model is therefore characterized by historical long term average data assumed to be representative (as close as possible) of the flow system circa 1848. Results indicate that the natural hydrologic setting of the San Joaquin Valley is a complex one. Complex hydrologic processes, including significant groundwater-surface water interaction along the major rivers and within wetland areas formed by flooded surface water, as well as ET and impacted root zone processes were identified in the model domain. Identification and simulation of the complex recharge and discharge relationships in the model domain sheds insight into the hydrologic nature of some historic natural wetlands. Evapotranspiration is a very significant sink of both surface water and groundwater (44.8 % of the water balance input), and has a major impact on hydrologic processes in the root zone. The presence and path of the major rivers in the domain are well defined in the model output and agree well with their actual locations. The model simulates gaining and losing reaches of the major rivers, replicating the historic recharge-discharge relationship documented by others. The general location, formation, and hydrologic processes of some significant wetlands simulated by the model have a fair agreement with historical records. As mentioned above, there is also a fair match between simulated and actual estimated water table elevations. Successful simulation of the complex hydrologic processes and features that characterize the predevelopment hydrologic conditions of the San Joaquin Valley and that resolve the water balance of the natural system underscores the importance and necessity of using an integrated model. This steady state model should serve as a reasonable initial condition for future transient runs that bring the model up to current hydrologic conditions capable of estimating present and future water budgets.

One of the most essential resources for life on our planet is water. A concern for water resource sustainability has shifted towards the sustainable development of clean water body resource (SWDF, 2009). Data for the Vaal River water chemistry is in abundance. However, research on the historic natural conditions influencing the inorganic water quality, is not as extensive. Inorganic data was obtained from the Department of Water Affairs, for the period 1972 to 2011, for identified monitoring stations along the Vaal River. Water quality was evaluated using various geochemical techniques to analyse the data. The results of the study indicate that the water chemistry of the Vaal River is controlled by: 1. Chemical weathering of siliceous sediment, intrusive igneous rocks and metamorphic rocks (Na+, K+, Mg2+, Ca2+ and (HCO3)-). 2. Anthropogenic influences increasing the sulphate (SO4) concentration There is no major increase in ion concentrations for the stations. However the concentrations of bicarbonate (HCO3)- and SO4 change as it progresses downstream from the first upstream station to the last downstream station. Based on the chemical characterisation, three groups have been identified. (1) Group 1 stations appear to suggest a higher influence in chemical weathering than the group 2 stations. (2) Group 2 stations appear to suggest a greater influence from SO4. (3) Group 3 stations appear to suggest an influence from both the bicarbonate and the SO4 influences. Geographically the chemical weathering is an indication of the three different groups with strong anthropogenic influences in the middle group. The water chemistry for the Vaal River is controlled by two processes, namely chemical weathering and anthropogenic influences. The prominent indication of the difference in these two influences can be seen between group 1 and group 2. A secondary conclusion indicates that a total dissolved solid (TDS) alone is not an accurate representation of anthropogenic influence (or poor water quality) on inorganic water quality of the Vaal River. The natural weathering or geological influences appears to play a more dominant role in certain sections or catchments with lower contributions from anthropogenic influences. / MSc (Environmental Sciences), North-West University, Potchefstroom Campus, 2015