The constants modernization in the fuels used request improvements in the combustioneffectiveness, as a consequence the material for components as the cylinder heads mustenhance their properties. Seven different compositions of compacted graphite iron (CGI)are analysed with the aim of characterized and select the most suitable material for thecylinder head service condition. The present master thesis report focuses on the impactof the matrix- either pearlitic or ferritic- and alloying elements such as molybdenum andnickel in the fatigue crack propagation ratedadNand fracture toughness (kIc).Tests to determined the fatigue crack growth rate, according to the ASTM standardE647 and fracture toughness (ASTM E399) were conducted. The equipment utilized was aservo hydraulic machine, for the fatigue crack propagation rate test and a electromechanicalmachine for the fracture toughness. Moreover, for measure the crack length a portablemicroscope camera and a camera connected to a DIC(digital image correlation) softwarewas used. The interpretation of the data obtained from the tests were done by TEMA- aDIC software- and MATLAB.The test results are analysed describing the influence of the composition and the microstructurehave over the mechanical properties achieved. Furthermore, an analyse forrelating the graphite average length and the hardness with the fatigue crack growth rateand the fracture toughness of the materials is performed.

Buildings construction and realization of public infrastructures have always been a primary need in the human society, developing low cost and user-friendly materials which also encounter safety and durability requirements. Portland cement is the most used material in construction industry from the industrial revolution up to date, but the raising concerns related to the climate change are pushing the governments worldwide to replace it with more eco-friendly and greener materials. Geopolymers are considered to be best alternatives to Portland cement in construction industry, but issues related to cost and mechanical properties are still hindering the commercialization of this material. Geopolymer incorporating wastes is one of the solutions. Fly ash, a thermal power plant by-product, and borosilicate glass, a recycled glass from pharmaceutical vials, are suitable candidates in geopolymers activation. NMR and FTIR spectroscopies demonstrated that borates from borosilicate glass are active compounds in geopolymerization, substituting the alumina is its role, composing a B-Al-Si network never observed before. Various fly ash and borosilicate glass weight contents were studied in terms of mechanical properties (compression test, 3-point bending test). It was found that fly ash 55 wt.% and borosilicate 45 wt.% composition activated in 13 M NaOH solution holds the best compressive and flexural strength (45 and 4 MPa respectively), 25% stronger than similar counterparts found in literature. Cellulose fibres in different weight contents were dispersed into the geopolymeric paste to produce geopolymer composites, with the aim to render the material more suitable for structural applications. 3-point bending test showed an improvement of the flexural strength of about 165% (12 MPa), while the chevron notch method displayed a fracture toughness of 0.7 MPam1/2, in line with the results of geopolymer composites found in literature. In this thesis work, fly ash was also successfully densified in 3 M NaOH solution and distilled water through a new method based on hydraulic pressure, called hydro-pressure sintering. This innovative technology involves a drastic reduction of NaOH utilization in geopolymerization, rendering the material more eco-friendly. XRD spectroscopy conducted on produced samples revealed a higher formation of crystals, most likely induced by the application of hydraulic pressure (450 MPa).

This dissertation consists of two projects. Project 1 is comprised of two systematic review studies in which self-report measures of adult characterological resilience were identified and summarized. In Study 1, 51 personality-based instruments across five personality-based resilience constructs (ego-strength, grit, hardiness, mental toughness, and resilience) were identified. Information for each measure inclusive of measure title, construct, item count, factors, response scale and items, scoring method, and score range was summarized. In Study 2, 1,322 articles were identified that described 1,193 studies and 1,351 participant samples who completed between one and four of these resilience measures. Measure use frequency and contextual use information related to study and sample attributes are summarized. Project 2 is a series of meta-analyses that were conducted to investigate the psychometric properties of scores on the Brief Resilience Scale (BRS) reported in 149 studies of adult participants. Reliability generalization methods are used to summarize 86 observations of internal consistency (mean Cronbach’s α = .86) and validity generalization methods are used to summarize eight observations of convergent validity (Mr = .61). Concurrent validity is also investigated via validity generalization methods for the most frequently observed mental health correlates of BRS scores. For each set of mental health measures, an estimated summary effect was calculated (anxiety, Mr = -.47; depression, Mr = -.49; optimism, Mr = .44; social support, Mr = .24; and stress, Mr = -.53). Of the significant moderators conducted for concurrent validity estimates, the largest was sample category (accounting for 100% of the variance in the observed correlations between the BRS and measures of social support). Geographic location and participant age, accounted for 55%, and 24%, of the variation in the observed correlations between the BRS and significantly moderated the relation between the BRS and perceived stress. Discussion for both projects include how the obtained relate to resilience theory, and the potential broader implications of these findings. Also based upon these reviews and meta-analyses, the challenges of resilience measure use are discussed and observations/recommendations are provided.

An experiment was carried out in order to locate and quantify osteon types within a sample of cortical bone taken from a human tibia. This was done using a microscope-camera assembly and the BioQuant computer software. The results of this were correlated with a previous experiment’s results on fracture toughness so that an analysis could be run on the data in order to determine the factors that most affect the value of fracture toughness of this cortical bone. Results were examined closely and the analysis repeated until the author was satisfied that the best possible model for fracture toughness had been achieved. A combination of usable parameters included: region, porosity, volume fraction of lightfield osteons, volume fraction of hooped osteons, volume fraction of dark osteons, volume fraction of alternating osteons, volume fraction total, density, average diameter total, average diameter of hooped osteons, average diameter of lightfield osteons, average diameter of darkfield osteons and average diameter of alternating osteons. This model explains the parameters that most affect fracture toughness by using a regression analysis, which also provides a regression equation to show exactly how much each specific parameter affects the fracture toughness value

This diploma thesis examines the effect of short fiber reinforcement in particle composite with a polymer matrix and the effect of its structure on the mechanical properties. It studies the refraction toughness depending on the addition of short polyvinylalcohol fibers (PVAL), nanosilica and pulverized polymethylacrylate (PMMA) to a dimethylacrylate matrix. Matrix strengthening was characterised with the help of differential compensation photocalorimetry. The inner structure of the composite and the morphology of fracture were studied using a scanning electron microscope. For the tested samples, the modules of elasticity and toughness were measured, the critical values of stress intensity factor and the energy release rate were determined. The findings suggest that the limit value of short fibers content is 4 vol. %. This content of fibers significantly increases the tenacity of the material but at the same time the uniform distribution of fibers and the ease of preparation of the material decrease. Within the possible applications, the manipulation of this material worsens as well. The fibers content of 2 ± 0.5 vol. % is an acceptable compromise between good treatability, uniform distribution of fibers and the required mechanical properties. During the study of the fracture surfaces of the material, different types of fibers disruption were witnessed (extraction from the matrix, plastic deformation, fibrillation on the surface of the fibers, fracture) depending on the type of used matrix and filling.

Diploma paper deals with fracture toughtness of pipe type HDPE. The influence of material structure on its fracture toughness at temperature 0°C and 23°C measured by PSI test was determined. Experimental results were compared with gained results of S4 test and the conclusions about usage of PSI test in screening of impact properties of polymeric materials were formulated.

This paper describes the analytical work done by modelling and evaluating a thermal shock in a WWER-440 reactor pressure vessel due to an emergency case. An axial oriented semielliptical underclad/surface crack is assumed to be located in the core weld line. Threedimensional finite element models are used to compute the global transient temperature and stress-strain fields. By using a three-dimensional submodel, which includes the crack, the local crack stress-strain field is obtained. With a subsequent postprocessing using the j-integral technique the stress intensity factors KI along the crack front are obtained. The results for the underclad and surface crack are provided and compared, together with a critical discussion of the VERLIFE code.

The problems with the crack length determination by the unloading compliance method are well known for Charpy size specimens. The final crack lengths calculated for bent specimens do not fulfil ASTM 1820 accuracy requirements. Therefore some investigations have been performed to resolve this problem. In those studies it was considered that measured compliance should be corrected for various factors, but satisfying results were not attained. In the presented work the problem was attacked from the other side, the measured specimen compliance was taken as a correct value and what had to be adjusted was the calculation procedure. On the basis of experimentally obtained compliances of bent specimens and optically measured crack lengths the investigation was carried out. Finally, a calculation procedure enabling accurate crack length calculation up to 5mm of plastic deflection was developed. Applying the new procedure, out of investigated 238 measured crack lengths, more than 80% of the values fulfilled the ASTM 1820 accuracy requirements, while presently used procedure provided only about 30% of valid results. The newly proposed procedure can be also prospectively used in modified form for the specimens of different than Charpy size.

The investigation of reactor pressure vessel (RPV) material from the decommissioned Greifswald nuclear power plant representing the first generation of Russian-type WWER-440/V-230 reactors offers the opportunity to evaluate the real toughness response. The Greifswald RPVs of 4 units represent different material conditions as follows: • Irradiated (Unit 4), • irradiated and recovery annealed (Units 2 and 3), and • irradiated, recovery annealed and re-irradiated (Unit1). The recovery annealing of the RPV was performed at a temperature of 475° for about 152 hours and included a region covering ±0.70 m above and below the core beltline welding seam. Material samples of a diameter of 119 mm called trepans were extracted from the RPV walls. The research program is focused on the characterisation of the RPV steels (base and weld metal) across the thickness of the RPV wall. This report presents test results measured on the trepans from the beltline welding seam No. SN0.1.4. and forged base metal ring No. 0.3.1. of the Units 1 2 and 4 RPVs. The key part of the testing is focussed on the determination of the reference temperature T0 of the Master Curve (MC) approach following the ASTM standard E1921 to determine the facture toughness, and how it degrades under neutron irradiation and is recovered by thermal annealing. Other than that the mentioned test results include Charpy-V and tensile test results. Following results have been determined: • The mitigation of the neutron embrittlement of the weld and base metal by recovery annealing could be confirmed. • KJc values of the weld metals generally followed the course of the MC though with a large scatter. • There was a large variation in the T0 values evaluated across the thickness of the multilayered welding seams. • The T0 measured on T-S oriented SE(B) specimens from different thickness locations of the welding seams strongly depended on the intrinsic structure along the crack front. • The reference temperature RT0 determined according to the “Unified Procedure for Lifetime Assessment of Components and Piping in WWER NPPs - VERLIFE” and the fracture toughness lower bound curve based thereon are applicable on the investigated weld metals. • A strong scatter of the fracture toughness KJc values of the recovery annealed and re-irradiated and the irradiated base metal of Unit 1 and 4, respectively is observed with clearly more than 2% of the values below the MC for 2% fracture probability. The application of the multimodal MC-based approach was more suitable and described the temperature dependence of the KJc values in a satisfactory manner. • It was demonstrated that T0 evaluated according to the SINTAP MC extension represented the brittle fraction of the data sets and is therefore suitable for the nonhomogeneous base metal. • The efficiency of the large-scale thermal annealing of the Greifswald WWER 440/V230 Unit 1 and 2 RPVs could be confirmed.

The present study investigates the fracture toughness of FSW X-80 HSLA steel welds. Weld cooling rate and peak temperature were varied among welds; indirectly manipulated through FSW travel speed, rpm, and weld preheat. Fracture toughness was tested according to ASTM 1820 standard along the weld centerline using surface-notched SEB specimen cooled to -40 °C. This study resulted in a reliable, repeatable process for generating friction stir welds with CTOD’s consistently above that of the original base metal. CTOD and microstructure of friction stir welds can be selected by controlling weld cooling rate and peak temperature. Material properties and microstructure similar to the original base metal can be recreated throughout the weld stir zone. CTOD of FSW X80 has a strong inverse linear correlation with post-weld cooling rate.