Thesis (M.S.)--University of Florida, 2003. / Title from title page of source document. Includes vita. Includes bibliographical references.

This thesis focuses on the radiation mechanisms of non-thermal X-rays and soft gamma-rays of two types of thousands year old spin-down powered pulsars. The thousands year old pulsars have distinct radiation behaviors from the middle-aged gamma-ray pulsars. In the magnetosphere of the pulsar, the particles are accelerated by the electric field resulting from the rotation of the neutron star. These accelerated particles move along the magnetic field lines and emit GeV gamma-ray curvature photons. For the middle-aged pulsars, most of the curvature photons, whose observed spectra are described well by power law with exponential cut-off, can escape out of the light cylinder. In X-ray band, the middle-aged pulsars usually have black body radiation with a weak non-thermal component described by power law. On the other hand, for the thousands-year-old pulsars, the curvature spectra in GeV band, which obey power law with exponential cut-off, are smeared out by the pair creation or missed by the line of sight. The secondary pairs generated by pair creation processes spiral around the magnetic field lines and emit synchrotron photons, and the young pulsars have stronger non-thermal X-ray and soft gamma-ray radiation than the middle-aged ones. Seven young pulsars have been studied here, they are the Crab pulsar, PSRs B0540-69, B1509-58, J1846-0258, J1811-1925, J1617-5055 and J1930+1852. These seven fall into two categories: the Crab-like pulsars and soft gamma-ray pulsars. The Crab-like pulsars include the Crab pulsar and the Giant Crab PSR B0540-69, and the soft gamma-ray pulsars include the other five. The main difference between the two types of young pulsars is that the Crab-like pulsars’ spectra peak at E ≤ 1MeV while the soft gamma-ray pulsars’ spectra (in units of MeV/cm2/s) peak at E ∼ 10MeV. Their spectra also have different photon indices in X-ray band. The physics behind is two different pair creations, the photon-photon pair creation and the magnetic pair creation. The former happens when a high energy photon collides with a soft photon, and the latter happens when a high energy photon penetrates through strong perpendicular magnetic field. In the outer gap of the pulsar, a large mount of pairs are generated around the null charge surface via photon-photon pair creation, and the electric field separates the two charges to move in opposite directions. Therefore, there are outflow and inflow of particles in the magnetosphere, whose curvature photons are converted to pairs by photon-photon pair creation and magnetic pair creation respectively. For the Crab-like pulsar, the non-thermal X-rays and soft gamma-rays are emitted by the outgoing secondary pairs generated by photon-photon pair creation in the outer magnetosphere; for the soft gamma-ray pulsar, the radiating secondary pairs are generated below the null charge surface by the magnetic pair creation. / published_or_final_version / Physics / Doctoral / Doctor of Philosophy

No description available.

Polythiophenes have shown potential as inexpensive organic semiconductors because of their charge mobility properties. Small changes in structures can change the electronic and optical properties. Because oligothiophenes demonstrate the same electronic properties, have better solubility, and are easier to purify without defects, oligothiophenes are used as models for the polythiophenes. X-ray diffraction is an accepted method for studying the structure and arrangement of atoms in oligothiophenes; however, XRD requires crystalline solids for analysis. Obtaining suitable crystals can be difficult. In this paper, two crystallization techniques, vapor diffusion and zone sublimation, and the results are discussed. Raman spectroscopy, a type of vibrational spectroscopy, will give information about the structure of a molecule and can act as the molecular fingerprint of the molecule. Raman spectroscopy does not require crystalline solids and provides a relatively fast analysis. If the Willets lab can characterize the oligothiophenes by Raman spectroscopy, demonstrate distinguishable spectra for the different morphologies, and correlate this to the X-ray diffraction data, Raman spectroscopy will be an easier and faster means for analyzing the oligothiophenes. / text

published_or_final_version / Chemistry / Master / Master of Philosophy

published_or_final_version / Physics / Master / Master of Philosophy

No description available.

Quantitative multielemental analysis using Particle Induced X-ray Emission (PIXE) using 1 and 2 MeV proton bombardment on thin targets has been achieved. The method is based on the calculation of atomic ratios from experimentally determined relative x-ray efficiency curves. Sample preparation techniques involving digestion and homogenous deposition of samples and standards with a minimum of contamination have been investigated. The accuracy of the method has been evaluated using five standard reference materials obtained from the National Bureau of Standards. The elimination of bremsstrahlung associated with the charging effect of non-conducting samples in PIXE analysis has been accomplished using thin carbon foils in the beam path. Applications of the PIXE technique to studies on deep-sea ferromanganese nodules were performed. The utility of PIXE in the analysis of noduoles and in the following of the distribution of a large number of elements through the various stages of a processing scheme were demonstrated.

No description available.

The application and use of non-destructive portable x-ray fluorescence (XRF) analysis is a critical tool in the preservation and interpretation of cultural material. Portable XRF instrumentation produce elemental compositional data that is used to reconstruct current artifact composition, which can be related to materials and methods of manufacture, technological practice, as well as object condition and presence of corrosion surfaces. Portable XRF analysis is used to assess a variety of material classes utilized in artifact manufacture. The dissertation research is based on a series of three case studies that represent typical groups of material culture commonly encountered in conservation and conservation science research.Conservators and conservation scientists frequently undertake analysis and interpretation of disparate groups of materials. Often, these objects are tied together by research questions or themes directed by outside influences including preservation issues requiring action; curatorial research interests; museum exhibition programs; as well as many other cultural heritage stakeholders. To this end, both non-destructive and destructive tools that provide measurements of interest play critical roles in analysis. The case studies have been designed to answer common compositional questions relating to (a) bulk analysis of Chinese coins, (b) characterization of Southwestern ceramic colorants, and, (c) chemical examination of post-depositional manganese dioxide accretions occurring on archaeological ceramic materials. They evaluate the value of data produced using effectiveness of non-destructive portable XRF analysis for the interpretation of archaeological materials. The case studies provide a template for the development of conservation science research, predicated on object preservation, which produce meaningful data for the interpretation and conservation of the analyzed archaeological artifacts. Portable XRF provides useful data that is used to successfully interpret archaeological materials through (a) classification of metal alloys that can be related to published coin data, (b) identification of ceramic colorants and production technologies, and, (c) characterization of post-depositional product composition when used with established visual typologies.