Diffuse transfers of pesticides from agricultural land to ground and surface waters can lead to significant drinking water quality issues. This thesis describes the development and application of a parameter-efficient, numerical model to predict pesticide concentrations in raw water sources within an integrated hydrological framework. As such, it fills an unoccupied niche that exists in pesticide fate modelling for a computationally undemanding model that contains enough process complexity to be applicable in a wide range of catchments and hydrogeological settings in the UK and beyond. The model represents the key processes involved in pesticide fate (linear sorption and first-order degradation) and transport (surface runoff, lateral throughflow, drain flow, percolation to the unsaturated zone, calculated using a soil water balance) in the soil at a daily time step. Soil properties are derived from the national soil database for England and Wales and are used to define the boundary conditions at the interface between the subsoil and the unsaturated zone. This is the basis of the integrated hydrological framework which enables the application of the model to both surface water catchments and groundwater resources. The unsaturated zone model accounts for solute transport through two flow domains (accounting for fracture flow and intergranular matrix flow) in three hydrogeological settings (considering the presence and permeability of superficial deposits). The model was first applied to a small headwater sub-catchment in the upper Cherwell. Performance was good for drainflow predictions (Nash Sutcliffe Efficiency > 0.61) and performed better than the MACRO model and as well as the modified MACRO model. Surface water model performance was evaluated for eight pesticides in five different catchments. Performance was generally good for flow prediction (Nash Sutcliffe Efficiency > 0.59 and percentage bias below 10 %, in the validation period for all but two catchments). The 90th percentile measured concentration was captured by the model in 62 % of catchment-pesticide combinations. In theremaining cases predictions were within, at most, a factor of four of measured 90th percentile concentrations. The rank order of the frequency of pesticides detected over 0.1 μg L-1 was also predicted reasonably well (Spearman’s rank coefficient > 0.75; p < 0.05 in three catchments). Pesticide transport in the unsaturated zone model was explored at the point scale in three aquifers (chalk, limestone and sandstone). The results demonstrate that representing the unsaturated zone processes can have a major effect on the timing and magnitude of pesticide transfers to the water table. In comparison with the other catchment scale pesticide fate models that predict pesticide exposure at a daily time-step, the model developed stands out requiring only a small number of parameters for calibration and quick simulation times. The benefit of this is that the model can be used to predict pesticide exposure in multiple surface and groundwater resources relatively quickly which makes it a useful tool for water company risk assessment. The broad-scale approach to pesticide fate and transport modelling presented here can help to identify and prioritise pesticide monitoring strategies, to compare catchments in order to target catchment management and to highlight potential problems that could arise under different future scenarios.

This critical overview document (COD) presents, discusses and brings together the selected portfolio of publications that the author believes make a significant contribution to the field of wastewater treatment, focusing on the removal of endocrine disrupting chemicals (EDCs) in wastewater treatment applications. The aim of the research within this COD was to investigate the fate, mechanisms and optimisation of EDCs removal in wastewater treatment applications. The key objectives were to: 1. Investigate and understand the mechanisms of removal of EDCs in wastewater and sludge treatment processes. 2. Evaluate novel methods for the removal of EDCs in water and wastewater treatment applications. 3. Establish the kinetic and thermodynamic properties of the removal processes to inform process modelling of full scale design of treatment processes.

Hydraulic losses in sewer pipes are caused by wall roughness, blockages and in-pipe sedimentation. Hydraulic resistance is a key parameter that is used to account for the hydraulic energy losses and predict the sewer system propensity to flood. Unfortunately, there are no objective methods to measure the hydraulic resistance in live sewers. A common method to estimate the hydraulic resistance of a sewer is to analyse collected CCTV images and then to compare them against a number of suggested hydraulic roughness values published in the Sewer Rehabilitation Manual. This thesis reports on the development of a novel, non-invasive acoustic method and instrumentation to measure the hydraulic roughness in partially filled pipes under various structural and operational conditions objectively. This research presents systematic laboratory and field studies of the hydraulic and surface water wave characteristics, of shallow water flows in a sewer pipes with the presence of local and distributed roughness, in order to relate them to some fundamental properties of the acoustic field measured in the vicinity of the flow surface. The results of this thesis indicate that for the local roughness the energy content of the reflected acoustic signal is an indicator of the pipe head loss and hydraulic roughness. In the case of the distributed roughness, the variation in the temporal and frequency characteristics of the propagated sound wave can be related empirically to the mean flow depth, mean velocity, wave standard deviation and hydraulic roughness.

When designing urban water systems (i.e. water distribution and sewer systems) it is imperative that uncertainty is taken into consideration. However, this is a challenging problem due to the inherent uncertainty associated with both system loading requirements and the potential for physical components failure. It is therefore desirable to improve the reliability of each system in order to account for these uncertainties. Although it is possible to directly evaluate the reliability of a water distribution systems (WDS) (using reliability measures), the calculation processes involved are computationally intensive and therefore unsuitable for some state-of-the-art, iterative design approaches (such as optimisation). Consequently, interest has recently grown in the use of reliability indicators, which are simpler and faster to evaluate than conventional direct reliability methods. In this thesis, a novel measure (the RUF) is developed to quantify reliability in urban water systems with a view to enhance their robustness under a range of future scenarios (Policy Reform, Market Forces, Fortress World and New-Sustainability Paradigm). The considered four future scenarios were synthesized in the EPSRC supported multidisciplinary 4 year project: Urban Futures. Each investigated urban future scenario is characterised by a distinct household water demand and local demand distribution (emerging due to different urban forms evolving in future scenarios). In order to assess the impact of urban futures, RUF has been incorporated into Urban Water System (UWS) dynamic simulations for both WDSs and Foul Sewer Systems (FSSs) using open source codes of EPANET and SWMM. Additionally, in order to overcome extensive computational effort, resulting from the use of traditional reliability measures, a new holistic reliability indicator, the hydraulic power entropy (IHPE) has been developed and compared to existing reliability indicators. Additionally, the relationship between the new reliability indicator and the above mentioned RUF reliability measure is investigated. Results suggest that the magnitude of the IHPE in network solutions provides a holistic indication of the hydraulic performance and reliability for a WDS. However, the performance of optimal solutions under some Urban Futures indicates that additional design interventions are required in order to achieve desired future operation. This thesis also proposes a new holistic foul sewer system (FSS) reliability indicator (the IFSR). The IFSR represents sewer performance as a function of excess pipe capacity (in terms of available increase and also decrease in inflow). The indicator has been tested for two case studies (i.e. different sewer network layouts). Results suggest that the magnitude of IFSR has positive correlations with a number of identified key performance indicators (i.e. relating to capacity, velocity, blockages). Finally, an Integrated Design Approach (IDA) has been developed in order to assess the implications of applying design interventions on both a WDS and downstream FSS. The approach holistically considers present and future operation of each interconnected system. The approach was subsequently demonstrated using two proposed design interventions. Results suggest that, for the considered design interventions, there is trade-off between the simultaneous improvement of both WDS and FSS operation and reliability.

Desalination is a technique of producing fresh water from the saline water. Industrial desalination of sea water is becoming an essential part in providing sustainable source of fresh water for a large number of countries around the world. Thermal process being the oldest and most dominating for large scale production of freshwater in today's world. Multi-Stage Flash (MSF) distillation process has been used for many years and is now the largest sector in the desalination industry. In this work, a steady state mathematical model of Multistage Flash (MSF) desalination process is developed and validated against the results reported in the literature using gPROMS software. The model is then used for further investigation. First, a steady state calcium carbonate fouling resistance model has been developed and implemented in the full MSF mathematical model developed above using gPROMS modeling tool. This model takes into consideration the effect of stage temperature on the calcium carbonate fouling resistance in the flashing chambers in the heat recovery section, heat rejection section, and brine heaters of MSF desalination plants. The effect of seasonal variation of seawater temperature and top brine temperature on the calcium carbonate fouling resistance has been studied throughout the flashing stage. In addition, the total annual operating cost of the MSF process is selected to minimise, while optimising the operating parameters such as seawater rejected flow rate, brine recycle flow rate and steam temperature at different seawater temperature and fouling resistance. Secondly, an intermediate storage between the plant and the client is considered to provide additional flexibility in design and operation of the MSF process throughout the day. A simple polynomial based dynamic seawater temperature and different freshwater demand correlations are developed based on actual data. For different number of flash stages, operating parameters such as seawater rejected flow rate and brine recycle flow rate are optimised, while the total annual operating cost of the MSF process is selected to minimise.The results clearly show that the advantage of using the intermediate storage tank adds flexible scheduling in the MSF plant design and operation parameters to meet the variation in freshwater demand with varying seawater temperatures without interrupting or fully shutting down the plant at any time during the day by adjusting the number of stages. Furthermore, the effect of non-condensable gases (NCG) on the steady state mathematical model of MSF process is developed and implemented in the MSF model developed earlier. Then the model is used to study effect of NCG on the overall heat transfer coefficient. The simulation results showed a decrease in the overall heat transfer coefficient values as NCG concentrations increased. The model is then used to study the effect of NCG on the design and operation parameters of MSF process for fixed water demand. For a given plant configuration (fixed design) and at different seawater and steam temperatures, a 0.015 wt. % of NCG results in significantly different plant operations when compared with those obtained without the presence of NCG. Finally, for fixed water demand and in the presence of 0.015 wt. % NCGs, the performance is evaluated for different plant configurations and seawater temperature and compared with those obtained without the presence of NCG.

Increasing freshwater scarcity is making reclamation of wastewater effluent more economically attractive as a means of preserving freshwater resources. The use of an integrated membrane system (IMS), the combination of micro/ultra-filtration (MF/UF) followed by reverse osmosis (RO) membranes, represents a key process for municipal wastewater reuse. A major drawback of such systems is the fouling of both the MF/UF and RO membranes. The water to be treated by the IMS system varies from one wastewater treatment plant (WWTP) to another, and its fouling propensity changes correspondingly. It is thus preferable to conduct pilot trials before implementing a full-scale plant. This thesis aims to look at the sustainability of IMS technology dedicated to indirect potable reuse (IPR) in terms of fouling minimisation and cost via a 600 m3 .d- 1 pilot plant. Wastewater reuse plants, using IMS, as well as statistical methods for membrane optimisation were reviewed. Box-Behnken design was used to define optimum operating envelopes of the pilot plant for both the microfiltration and the reverse osmosis in terms of fouling minimisation. Same statistical method was used to enhance the efficiency of the MF cleaning-in place through bench-scale test. Data from the pilot plant MF process allow to determine relationship between reversible and irreversible fouling, and operating parameters and feed water quality. Life cycle cost analysis (LCCA) of the both trains (MF/RO/AOP and MF/AOP) of the pilot plant was performed and compared with the LCCA of two full-scale plant.

Coagulation is a ubiquitous process in the treatment of raw surface water for eventual potable use. Despite its capabilities, the sheer scale of its use is manifested in the volumes of chemicals it demands and waste sludge it produces. Recovering and reusing the chemical activity of the coagulant sludge in water treatment is a logical solution but this practice has been restricted by the presence of contaminants within the sludge. This thesis has investigated methods that can separate the coagulant metals from these primarily natural organic contaminants, with an aim of producing a sufficiently pure coagulant for effective treatment performance when reused. A process of ultrafiltration of the impure regenerated coagulant followed by a powdered activated carbon polishing stage compared favourably to a number of other separation processes and was found to remove the most dissolved organic compounds. When the purified coagulant was used to treat raw water, it provided better turbidity removal than commercial coagulant and matched its removal of trihalomethane precursors, making the process suitable for consideration at full-scale. Analysis of the whole life cost suggested that such performance could be reproduced at full-scale within a 25 year payback period. The reuse of even purified recovered coagulants in drinking water treatment still carries risks which may deter its implementation. Therefore the efficacy of recovered coagulants in the role of phosphorus removal from wastewater was also investigated. This showed that both acidified and unacidified waterworks sludges, with sufficient contact time, could remove similar levels of phosphorus as fresh coagulants, at approximately half the whole life cost.

Around 770 million people lack access to improved drinking water sources (WHO 2013), urgently necessitating implementation of contaminant removal by e.g. desalination systems on a large scale. To improve water quality and enable use of brackish water sources for human consumption in remote arid areas, a directly coupled wind – electrodialysis system (Wind-ED) was developed. Modularity, sustainability and above all suitability for the practical use in off-grid locations were the main motivations and design objectives. The direct coupling of wind energy with membranes reduces the system costs as well as technical drawbacks associated with using intermediate energy storage systems. During this research, systematic experiments were performed using the Wind-ED system in order to determine desalination performance and clean water production, specific energy consumption (SEC) and current efficiency (ηc) under relevant conditions, such as varying: i) wind speed, ii) wind turbulence intensity, iii) oscillation periods, iv) varying NaCl concentrations and v) flow rates. Moreover, the competitive removal of four commonly available inorganic contaminants in brackish groundwater sources, nitrate (NO3-), fluoride (F-), sulphate (SO42-) and chloride (Cl-), were investigated. Firstly, to establish a systematic understanding of how and to what extent energy fluctuations influence the transport of the salt (i.e. NaCl) ions across the membranes, experiments were conducted using pulsed electric field assisted electrodialysis (pulsed-ED) over a wide range of frequencies (0.001 – 10 Hz) and duty cycles (20 – 80). The results showed that pulsation applied in the sub-limiting regime resulted in reduced water production, explained by the delays caused by the off-periods during the pulsed desalination process. At higher current densities, pulsation led to considerable improvements in current (e.g. up to 95%, for a feed solution of 500 mg/L and a pulse regime of 1 Hz at 50 V peak voltage) and significant reduction in water dissociation, explained by a reduction of concentration polarisation. Importantly, the pulsation had no significant effect on energy consumption or current efficiency suggesting that ED could be suitable for direct coupling to fluctuating energy sources such as wind energy. ED was consequently coupled to a wind turbine system and a series of desalination tests were performed over a wide range of wind speeds (2-10 m/s), turbulence intensities (TI of 0-0.6) and oscillation periods (0-180 s). Results showed that water production and SEC increased with wind speed. However, both the water production and SEC stopped increasing as the power output from the turbine levelled off at wind speeds above the rated value (vrated: 7.9 – 8.4 m/s). The impact of wind speed fluctuations on the system performance were insignificant up to a TI of 0.4. The desalination performance declined under high turbulence intensity fluctuations (TIs ≥ 0.5) and long periods of oscillation (> 40 s), as the wind-ED system periodically cycled off in response to operation below the cut-in wind speed of the wind turbine (vcut-in: ~ 2 m/s). The off-cycling of the system caused significant delays in the desalination process, and thus resulted in reduced water production. Further reduction in the water production resulted as the wind-ED system operated under intermittent wind speed conditions with off-wind periods longer than 10 s. It was concluded that the main challenge in direct coupling of ED to a wind resource was not the magnitude of the fluctuations but the impact of the power cycling off during long periods of oscillation and lengthy periods of no wind. Interestingly, the SEC of the process remained relatively unaffected by the fluctuations and intermittencies in the wind resource. The effect of energy fluctuations on the competitive transport of F-, Cl-, NO3- and SO42- from artificial brackish water (TDS ~4350 mg/L) was investigated using different sets of real wind data. The ion removal, independent of the wind regime tested, followed the order: NO3- ≥ Cl- > F- > SO42-. The competitive removal of the ions was linked to differences in physicochemical properties (i.e. hydration energy, ionic mobility and valence). The specific selectivity (e.g. preferential transport of NO3- over SO42- ions) was found to increase with concentration polarisation being either minimised (by lowering the mean wind speed) or disrupted (by fluctuations in the wind resource). The results from flow rate and feed concentration experiments, showed that power production of the wind turbine depended on not only the available wind energy but also the resistance of the load (i.e. the ED stack). Thus, increasing the feed concentration and the flow rate resulted in reduced resistance in the ED stack (Rstack), which inversely influenced the current induction counter torque force applied on the shaft of the wind turbine and caused the rotor to spin at a lower angular velocity. This led to increased sensitivity of the wind-ED system to wind speed fluctuations (e.g. system cycled off due to extreme fluctuations and intermittencies with low TDS feed concentration of 2400 mg/L) and hence a reduction of desalination performance. Impact of flow rate on the SEC was found to be negligible; this was attributed to the automatic voltage to current adjustments done by the wind turbine, in order to minimise the impacts of Rstack on the power production by the turbine at a given wind speed. Increased flow rate and resulting shrinkage of the boundary layer’s thickness, caused the concentration profiles at the solution-membrane interface to become steeper. This favoured the transport of ions with the highest diffusion coefficients in the mixture (i.e. Cl- and NO3-). Decreased flow rate favoured the transport of ions with larger valence numbers and higher electric mobility inside the electrolyte (i.e. SO42-); as the former property governed the faster migration of SO42- ions through the thick boundary layer and the latter property assisted with the improved affinity of the ion-exchange membrane to SO42- ions compared to the monovalent anions in the mixture. Increasing the feed concentration of Cl- from 500 to 2,550 mg/L led to reduced transport numbers for the other anions in the mixture and significantly reducing their removal rate. The results obtained from both the pulsed-ED and wind-ED experiments showed that, despite direct coupling to the fluctuating energy source the SEC of the process remained relatively unaffected by the energy fluctuations. Although the desalination process might require more time to be completed when operating under extreme wind speed fluctuations and intermittencies, the quality of the drinking water produced was always within the WHO standards. In conclusion, the findings from this research prove the wind-ED system to be an energetically robust and a reliable off-grid desalination technique suitable for the treatment of brackish groundwater in water stressed remote regions.

Mounting recognition of the socio-political context of the management of water resources has rendered the application of technocratic approaches in isolation insufficient in addressing future management challenges with participatory approaches increasingly promoted in response. Against this background, new regulatory mechanisms in the water sector in England and Wales promise an increased role for the views of customers in water utility planning and decision- making. Yet, existing scholarship on the institutionalisation of participative approaches in water utility planning and decision-making in England and Wales is sparse. This thesis contributes to an improved understanding of factors that hold potential to impact institutionalisation of participative approaches in this context by focusing on three specific aspects of effectiveness; motivational clarity, the influence of participative mechanism design, and the use and influence of water utility customer contributions in water sector planning and decision-making. This has been achieved through the deployment of participatory research in collaboration with the sponsoring organisation (a water utility operating in England and Wales) utilising group discussion and semi-structured interviews with domestic water customers and water utility practitioner respectively. Findings demonstrate that preference elicitation vehicles embedded within participatory mechanisms hold the potential to influence participants expressed preferences thus representing a key design consideration where multi- mechanism approaches are deployed in planning and decision-making contexts. Furthermore, useful design considerations for multi-attribute presentation in participatory mechanisms are presented. Findings also identify a dominance of instrumental and legalistic practitioner motivations for the use of participative approaches in water utility decision-making. Foremost, it identified the significance of the regulator in driving water utility practices for the management and influence of customer contributions in planning and decision- making, and more fundamentally illustrates the significant barrier posed by a legacy of technocratic practices for the institutionalisation of participatory approaches in water utilities.

Developing countries pay a high price for water treatment due to importation of water treatment chemicals. Today, more than 663 million people lack access to a clean water supply which results in many deaths. Hibiscus plant seeds, namely Okra, Sabdariffa and Kenaf were investigated to identify their suitability as alternative water treatment materials to provide clean water supply to people in developing countries. Coagulation and disinfection ability of the extracts were assessed using a jar tester and Collilert-18 Quanti-Tray methods whereas dissolved organic carbon (DOC) test was performed using Shimadzu TOC analyser. The results of this work revealed that all the seed samples possess an anionic coagulant protein with a low molecular weight of 39 kDa. The potential of the seeds in crude form was clearly demonstrated, albeit with some issues regarding organic nutrient addition to the clarified water. However, this challenge was overcome by purifying the seed proteins in an ion exchange column where the impact of DOC addition was significantly reduced in the treated water, as demonstrated via fluorescence excitation-emission matrices. Additionally, the coagulant proteins identified in the region of tryptophan-like fluorescence were found to be stable after heat treatment. Furthermore, sludge production using seed extracts was found to be 5 times lower than that of aluminium sulphate (AS) and the pH of the treated water remained largely unaffected after treatment. Floc strength tests, undertaken using a laser diffraction instrument Mastersizer 2000, showed that the use of seeds as coagulant aids in combination with AS improved floc properties, leading to faster floc growth and shorter coagulation time.