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<p>The current work focuses on the synthesis and characterization of nano-devices with potential application in alkaline electrolysis and secondary polymer lithium ion batteries.</p>

In this thesis, photo luminescent diodes with the device structure of ITO/PEI/(CdTe/PDDA)*n/Al were fabricated using the method of layer-by-layer self assembly. The film thicknesses were varied from 150 nm to 380 nm. The films were characterized through X-ray diffraction (XRD), optical absorption and photoluminescence (PL) measurements. The XRD results on the film indicated a cubic crystalline structure (111) for the nano-CdTe particles. The band gap of the nano-particles were evaluated to be 2.1 eV in solution and 2 eV in films, which was further confirmed by the PL measurements as the solution exhibited a yellow luminescence while the film exhibited orange luminescence. The J vs. V curves revealed that the diodes exhibited rectifying behavior in both the forward and reverse biasing. Two models of current transport, one based on a Schottky mechanism and the other based on a tunneling mechanism were developed and were compared with the experimental values. The tunneling model developed could simulate the experimental currents up to four orders of magnitude. The tunneling mechanism of charge transport was further proved by the capacitance vs. voltage curves, which were identical to that of ITO/MEH-PPV/Al devices, where tunneling mechanism was the dominant method of charge transport.

Recent advances in nano technology have opened doors to several next generation devices and sensors. Characterizing nano particles and structures in a simple and effective way is imperative for monitoring and detecting processes at nano scale in a variety of environments. In recent years, the problem of studying nano particle interactions with surface plasmons or evanescent waves has gained significant interest. Here, a numerical model is presented to characterize nano-size particles and agglomerates near a metal or a dielectric interface. The methodology is based on a hybrid method, where the T-matrix approach is coupled with the image theory. The far field scattering patterns of single particles and agglomerates subjected to surface plasmons/evanescent waves are obtained. The approach utilizes the vector spherical harmonics for the incident and scattered fields relating them through a T-matrix. Effects of size, shape and orientation of the cluster on their scattering patterns are studied. An effort is made to distinguish particle characteristics from the scattering information obtained at certain observation angles. Understanding these scattering patterns is critical for the design of sensors using the surface plasmon scattering technique to monitor nano self assembly processes

Indium tin oxide (ITO) and molybdenum are substrates of choice in the manufacture of the CdS-CIS photovoltaic cell, which is the base for the leading thin-film solar cell technology. Substantial advancement in this technology is expected if these devices can be made in nanoporous alumina (AAO) templates. The first step to this endeavor is to learn to form AAO templates on molybdenum and ITO substrates. This was accomplished, and the results are reported in this thesis. Starting substrates were glass, coated with either a thin molybdenum layer or a thin ITO layer. Aluminum was deposited on top of this conducting substrate. Oxalic acid was used as the electrolyte for anodization. In the case of molybdenum substrates, average pore diameter was 45 nm when an anodization voltage of 40 volts was used for approximately 46 minutes; current density was approximately 23 amps/sq. m. In the case of ITO substrates, pores of 45 nm diameter were obtained for approximately 20 minute anodization at 40 V; current density was 40 amps/sq. m; annealing of aluminum layer prior to anodization, at 550 oC (degrees Centigrade) for 90 minutes was needed to obtain good pores. A one micrometer thick CdS layer was electrodeposited inside the AAO pores on top of the ITO substrate. In preliminary experiments, CdS/Cu2S photovoltaic heterojunctions with an open circuit voltage of 242 mV were formed inside the nanopores.

Recently, the use of thermite-based pressure waves for applications in cellular transfection and drug delivery have shown significant improvements over previous technologies. In the present study, a new technique for producing thermite-generated pressure pulses using fully-dense nano-scale thermite mixtures was evaluated. This was accomplished by evaluation of a stoichiometric mixture of aluminium (Al) and copper(II)-oxide (CuO) prepared by mechanical alloying. Flame propagation speeds, constant-volume pressure characteristics and underwater pressure characteristics of both a micron-scale and mechanically alloyed mixture were measured experimentally and compared with conventional nano-scale thermites. It was determined that mechanically alloyed mixtures are capable of attaining flame propagation speeds on the same order as nano-scale mixtures, with flame speeds reaching as high as approximately 100 m/s. Constant-volume pressure experiments indicated that mechanically alloyed mixtures result in lower pressurization rates compared with conventional nano-scale mixtures, however, an improvement by as much as an order of magnitude was achieved compared with micron-scale mixtures. Thermochemical equilibrium predictions for pressures observed in constant-volume reactions were found to capture relatively well the equilibrium pressure for both low and high values of relative density. Generally, the predictions over-estimated the measured pressures by approximately 60%. Results from underwater experiments indicated that the mechanically alloyed samples produced peak shock pressures and waveforms similar to those for a nano-scale Al-Bi2O3 mixture reported by Apperson et al. (2008). In an effort to model the pressure signal obtained from the underwater reaction, calculations were performed based on the rate of expansion of the high pressure gas sphere. Predicted pressures were found to agree fairly well in terms of both the peak pressure and pressurization rate. The present study has thus identified the ability for mechanically alloyed thermite mixtures to produce underwater pressure profiles that may be conducive for applications in cellular transfection and drug delivery. Récemment, l'utilisation d'ondes de pression produite par des mélanges de thermite pour des applications dans la transfection cellulaire et l'administration de médicaments ont démontré des améliorations importantes par rapport aux technologies précédentes. Dans l'étude ci jointe, une nouvelle technique pour produire des impulsions de pression générée par un mélange thermite, soumit a de l'alliage mécanique, a été évaluée. Ceci a été accompli par l'évaluation d'un mélange stoechiométrique d' aluminium (Al) et de l'oxyde de cuivre(II) (CuO), préparé par mécanosynthèse. Les vitesses de propagation de la flamme, les caractéristiques de pression pour la combustion à volume constant et les caractéristiques de pression pour la combustion sous l'eau ont été mesurées expérimentalement et comparés avec les thermites conventionnel à l'échelle nano. Nous avons déterminé que les mélanges alliés mécaniquement sont capables d'atteindre des vitesses de propagation de flamme du même ordre que les mélanges à l'échelle nanométrique, atteignant jusqu'à environ 100 m/s. Les expériences de combusition à volume constant, indique que les mélanges alliés mécaniquement induit des taux de pressurisation inférieures à celles des mélanges de nano-échelle conventionnel, cependant, une amélioration de près d'un ordre de grandeur a été atteint par rapport aux mélanges d'échelle micronique. Prédictions thermochimiques des pression de compbustion se sont révélés capable de relativement bien saisir les valeurs observées dans les expériences à volume constant. En règle générale, les prévisions sur-estimé les pressions mesurées par environ 60%. Les résultats des expériences sous-marines ont indiqué que les échantillons alliés mécaniquement ont produit des pressions et des profils d'onde similaires à celles produit par un mélange de Al-Bi2O3 de nano-échelle, comme indiqué par Apperson et al. (2008). Pour modéliser les pressions obtenues dans les expériences sous-marines, des calculs basés sur le taux d'expansion de la bulle de gaz à haute pression ont été obtenus. Les pressions prédites ont été trouvés d'être relativement en accord avec la pression maximale et le taux de pressurisation observé. Cette étude a ainsi identifié la possibilité pour l'utilisation des mélanges de thermites alliés mécaniquement pour produire des profils de pression sous l'eau propices pour des applications de transfection cellulaire et l'administration de médicaments.

Apertureless near-field scanning infrared microscopy is a technique in which an impinging infrared beam is scattered by a sharp atomic force microscopy (AFM) tip oscillating at the resonant frequency of the cantilever in close proximity to a sample. Several advantages offered by near-field imaging include nanoscale imaging with high spatial resolution (near-field imaging is not restricted by the diffraction limit of light) and the ability to differentiate between chemical properties of distinct compounds present in the sample under study due to differences in the scattered field. An overview of the assembly, tuning, and implementation of the near-field instrumentation is provided, as well as detailed descriptions about the samples probed and other instrumentation used. A description of the near-field phenomena, a comparison between aperture and apertureless-type near-field microscopy, and the coupled dipoles model explaining the origin of the chemical contrast present in near-field infrared imaging was discussed. Simultaneous topographic and chemical contrast images were collected at different wavelengths for the block copolymer thin film, polystyrene-b-poly(methyl ethacrylate) (PS-b-PMMA) and for amyloid fibrils synthesized from the #21-31 peptide of β2-microglobulin. In both cases it was observed that the experimental scattered field spectrum correlates strongly with that calculated using the far-field absorption spectrum, and using near-field microscopy, nanoscale structural and/or compositional variations were observed, which would not have been possible using ensemble FTIR measurements. Lastly, tip-enhanced Raman spectra of the #21-31 and #16-22 peptide fragments from the β2-microglobulin and Aβ(1-40) peptide were collected, examined, and an outline of the optimization conditions described.