Thesis (MCE)--University of Delaware, 2005. / Principal faculty adviser: Nii O. Attoh-Okine , Dept. of Civil & Environmental Engineering. Includes bibliographical references.

Thesis (MIng)--University of Stellenbosch, 2007. / Bibliography. Also available via the Internet.

No description available.

abstract: This research focused on the structure-property relationships of a rejuvenator to understand the comprehensive rejuvenation mechanism of aged asphalt binder. Aged asphalt such as recycled asphalt shingles (RAS) and reclaimed asphalt pavement (RAP) contain various amounts of asphalt binder. However, the asphalt binder in RAS and RAP is severely aged and inferior in properties compared to a virgin binder. To address this issue, liquid additives have been used under the general title of rejuvenators. That poses an additional challenge associated with the lack of clear metrics to differentiate between softeners and rejuvenators. Therefore, there is a need for a thorough study of rejuvenators. In this study, diverse-sourced rejuvenators have been used in RAS and RAP-modified binders as well as laboratory-prepared aged binders. The properties of the rejuvenated aged binder were characterized at a macro-level and molecular level. The study showed that the performance of the RAS-modified binder was significantly improved after bio-modification by a bio-rejuvenator. This study further evaluated laboratory-prepared aged asphalt rejuvenated with different rejuvenators. The results found that oxidized bitumen became soft after adding rejuvenators, regardless of their source. Molecular dynamics simulation showed that the effective rejuvenator restored the molecular conformation and reduced the size of asphaltene nanoaggregates. The study results showed that due to the specific chemical composition of certain rejuvenators, they may negatively impact the durability of the mixture, especially about its resistance to moisture damage and aging. Computational analysis showed that while the restoration capacity of rejuvenators is related to their penetration into and peptizing of asphaltene nanoaggregates, the durability of the restored aged asphalt is mainly related to the polarizability values of the rejuvenator. Rejuvenators with lower polarizability showed better resistance to aging and moisture damage. In summary, this study develops the rheology-based indicators which relate to the molecular level phenomenon in the rejuvenation mechanism. The rheology-based indicators, for instance, crossover modulus and crossover frequency differentiated the rejuvenators from recycling agents. Moreover, the study found that rejuvenation efficiency and durability are depended on the chemistry of rejuvenators. Finally, based on the learning of chemistry, a chemically balanced rejuvenator is synthesized with superior rejuvenation properties. / Dissertation/Thesis / Doctoral Dissertation Civil, Environmental and Sustainable Engineering 2020

Asphalt concrete pavement is subjected to several damaging actions from traffic loads, water (from precipitation and/or groundwater sources), and temperature. The durability of the asphalt-aggregate mixture, its ability to withstand these damaging actions for long periods, is a very important engineering property. While the durability of the asphalt-aggregates mixture depends on several factors such as the mixture's properties, construction methods, traffic loads and environmental conditions, they have to be evaluated to predict their field performance. Based on mixture evaluations, the mixtures that fail the test would have to be modified by additives or by changing the materials. The first objective of this thesis was to evaluate asphalt-aggregate mixtures for water damage using the Environmental Conditioning System (ECS), and rank the asphalt and aggregate types based on water sensitivity. The second objective was to relate the ECS ranking of the asphalt and aggregate types to Oregon State University (OSU) and University of Nottingham, UK (SWK/UN) wheel tracking test results, and to Net Adsorption Test (NAT) results. The third objective was to evaluate open-graded mixtures and rubber modified mixtures for water sensitivity using the ECS. The ECS test results indicate that performance ranking of mixtures by asphalt type or aggregate type alone cannot be made for the ECS test results due to the significant interaction between asphalt and aggregate. Water sensitivity in the ECS is significant for combinations of asphalt and aggregate. The ECS test results have shown that ECS performance ranking after one cycle is not statistically significant and does not correlate with ranking after three cycles. The results show that the ECS test program has similar aggregate rankings to those of the NAT and SWK/UN test program, while good agreement exists between SWK/UN wheel tracking results and the NAT test program results. However, poor agreement exists between the OSU wheel tracking results and those of the other two tests. Poor or very little agreement exists among the wheel tracking test results, ECS, and NAT test results in terms of asphalt type rankings. When considering the comparisons of materials ranking by different test procedures, one must keep in mind that the mechanisms leading to varying "performance" are not the same. The testing reported herein was aimed at measuring water sensitivity, but all the tests do not do so directly. The NAT procedure addresses only the potential for stripping (adhesion) and is not capable of evaluating cohesion loss. The other tests (ECS, OSU and SWK/UN wheel tracking) included all the mechanisms simultaneously, and these provided a gross effect without clearly separating the cause of failure in each case. Open-graded mixtures used by Oregon Department of Transportation (ODOT) performed well in the ECS in terms of water sensitivity. In the ECS evaluation, six mixtures passed the criteria of 75 % established for Indirect Retained Strength (IRS) test by ODOT, and one mixture was marginal. However, only one mixture passed the IRS evaluation, and another mixture was marginal. This confirms that the IRS test is a very severe test and is not suitable for water sensitivity evaluation of open-graded mixtures. Finally, the IRS test evaluation would suggest that these mixtures would fail prematurely after construction, but all of these mixtures have been used in projects which have been in service for more than three years with no visible signs of distress, or failures. / Graduation date: 1994

This thesis investigates and documents fundamental studies of highway materials (asphalt engineering properties) especially on different modified asphalt binders and mixtures in order to understand failure mechanisms at low temperature and superior performance of such asphalt binders with the aim of preventing premature cracking on Ontario highways. In addition, seven asphalt binders of different compositions were used as a template for study and this research work is tailored towards Superpave® performance-based specification testing with the aim of improving asphalt pavement performance under various conditions and consequently reducing premature cracking in order to achieve long lasting highways. Based on the actual applied pattern of Superpave® specification criteria, the mechanical responses of the binders are analyzed by extended bending beam rheometer (eBBR), tensile stress ductilometer (Petrotest DDA3®), compact tension test (Instron AsphaltPro®), double-edge-notched tension and single-edge-notched tension (MTS 810 universal testing machine) protocols. The objective of this study entails establishing and developing of a proper procedure for the testing of binders with the aim of ranking (grading) the performance after validation of laboratory and field experiments. Analysis of the results appears to show that the premature distress on the Highway 417 trial sections can be attributed to reversible aging tendency (wax crystallization) at low temperatures coupled with low fatigue resistance of the binders. The results suggest that different polymer modifications had significant influence on the performance of asphalt mix as demonstrated from the results obtained from essential and plastic work of fracture using double-edge-notch-tension test (DENT). Crack tip opening displacement (CTOD) parameter consistently show the performing grading of asphalt binder while compact tension test protocol provides plane strain fracture toughness (K1c) which could be used to rank binders with respect to fracture resistance at low temperature. Hence, CTOD is a promising parameter which can be used to establish performance ranking of the binders. / Thesis (Master, Chemistry) -- Queen's University, 2008-05-26 09:54:23.308

Thesis (M.S.)--Auburn University, 2007. / Abstract. Vita. Includes bibliographic references (ℓ. 114-117)

Thesis (M.S.)--University of Nevada, Reno, 2006. / "May, 2006." Includes bibliographical references (leaves 54-56). Online version available on the World Wide Web.

Thesis (M.S.)--University of Nevada, Reno, 2007. / "May, 2007." Includes bibliographical references (leaves 45-46). Online version available on the World Wide Web.

Thesis (M.S.)--University of Nevada, Reno, 2007. / "December, 2007." Includes bibliographical references (leaves 63-66). Online version available on the World Wide Web.