The general characteristics of gold deposits are reviewed, and a classification of gold deposits based on mineability is proposed. Evaluation, mlnlng and beneficiation methods are briefly discussed. It is concluded that the most viable targets for small-scale companies comprise deposits that require the least pre-production time and expense. Great potential exists for the small-scale reclamation of gold from tailings dumps and abandoned mines in Southern Africa. There is also potential for developing new smallscale gold mines in the Archaean greenstone terranes of the Zimbabwean and Kaapvaal cratons.

Department of Mining and Environmental Geology / MESC

MENVSC / Department of Ecology and Resource Management / Mining has historically been the mainstay of the South African economy and has both shaped its social and environmental fabric. However, it has left the country with a negative legacy of abandoned mines that present environmental problems, and public health and safety concerns. The common physical and environmental problems of most of these abandoned mines are associated with open shafts, unstable slopes of waste dumps and pits, and dilapidated mine infrastructure. Even though the problems of these abandoned mines are known, little has been done to rehabilitate these mines. Some attempts have been made to rehabilitate mine openings but efforts to rehabilitate features such as mine waste dumps and dilapidated infrastructure has been woefully inadequate. The reasons for ineffective rehabilitation measures may include inappropriate measures that are used in rehabilitation of the abandoned mines, lack of financial resources to carry out the rehabilitation and the need to prioritize abandoned mine features and mine sites for rehabilitation in view of the fact that there are many of these abandoned mines that require urgent attention and resources to rehabilitate them are limited. It is therefore important that practicable rehabilitation strategies are developed and used to rehabilitate mine features and sites to provide long-lasting solutions to the physical, environmental, and social problems. This study focused on the evaluation of strategies for rehabilitation of selected abandoned mine sites in the Giyani Greenstone Belt. The approach used in this study involved conducting a detailed field inventory and characterization to establish the nature and seriousness of the physical and environmental conditions of the selected abandoned/historic mining sites in Giyani Greenstone Belt. Field inventory and characterization involved traversing around the mine-site to locate and describe abandoned mine features. The Global Positioning System (GPS) was used in capturing the absolute location of the identified major abandoned mine features such as open mine shafts, tailings dump, and dilapidated infrastructure. Each of the identified mine features was critically analyzed by scoring and ranking the associated hazards. The scoring focused on the source of the hazard, exposure pathways, and possible damage that might be caused by the hazard. Analytical Hierarchy Process (AHP) and Pugh Matrix were used to devise a multi-criteria framework for evaluating mine site rehabilitation strategies. AHP method was utilized to evaluate the significance of the deciding factors and the Pugh Matrix to relatively compare the strategies for the selection of the appropriate rehabilitation options. The results of the study showed that the best approach to effectively address the physical and environmental hazards at Louis Moore and Klein Letaba abandoned mines of the Giyani Greenstone Belt was to give priority to extremely hazardous open mine shafts and tailings dumps. Mine shafts present a high risk of falling and drowning in water in the mine workings. Such risks are likely to lead to death with no hope of recovery of the body. The next mine features to be rehabilitated are the tailings dumps since they have relatively less physical hazards but extremely high environmental hazards. Abandoned mine infrastructure was found to be less hazardous and should, therefore, receive the least attention. The preferred rehabilitation strategies for abandoned mines features were evaluated after a comprehensive characterization of the site, this was done to ensure that the selected strategy addresses both physical and environmental problems identified on the site. Based on the results of evaluation, backfilling was selected to be the most suitable rehabilitation strategy for mine shafts as it has a very high potential to eliminate the risks of people falling into the mine shaft and the chances of water contamination by abandoned mine shafts. The most ideal rehabilitation option for tailings dumps was revegetation, since it ensures the safety of the site after implementation and minimizes the future environmental impacts such as the discharge of contaminants to the nearby environment. The most preferred rehabilitation strategy for dilapidated abandoned infrastructure in the study area was the demolition of the infrastructure, this strategy will improve the safety status of the mine sites and make the land they occupy available for other traditional post-mining land uses. It was concluded that the approach of prioritizing the extremely and moderately hazardous abandoned mine features is appropriate for use in developing countries where there are numerous abandoned mines and limited resources to rehabilitate them. This will go a long way in ensuring that characterization and rehabilitation of the abandoned mine features are effectively carried out within the constraints of resources. / NRF

MENVSC / Department of Ecology and Resource Management / Historically, mining activities have generated vast quantities of abandoned tailings dumps in several regions of South Africa and throughout the world. The management and disposal of huge volumes of tailings dumps has constituted a major challenge to the environment. The current study aims to establish the physicochemical properties and mineralogical characterization of the old copper tailings dump in Musina, to reveal the mobility patterns and attenuation dynamics of potentially toxic or heavy metal species as a function of depth, with a view of assessing their potential environmental impact with respect to surface and ground water systems. This information is crucial in the beneficial utilization of copper tailings in the development of sustainable construction materials as part of reuse approach management system. About twelve tailings samples were collected into polyethylene plastic bags from three established tailings profiles drilled by a hand auger. The collected tailings samples were characterized using standard analytical procedures i.e., X-ray fluorescence (XRF), X-ray diffraction (XRD) and scanning electron microscopy/energy dispersive spectroscopy (SEM-EDS). The transfer of potentially toxic or heavy metal species from tailings to water was evaluated using the standardized batch leaching test (EN 12457) and speciation-equilibrium calculations on the aqueous extracts performed by MINTEQA2. The leachate concentration of cations in the collected tailings samples was determined by inductively coupled mass spectrometry (ICP-MS) and the leachate concentration of anions was determined by ion chromatography (IC). A modified sequential extraction scheme was applied on the selected tailings samples of the drilled tailings profiles to further understand the mode of occurrence, the geochemical partitioning and distribution, real mobility, and environmental bioavailability of potentially toxic or heavy metal species in the tailings and tailings-soil interface. The extracted fractions or phases from sequential scheme were as follows: (F1) water-soluble fraction, (F2) exchangeable fraction, (F3) carbonate fraction, (F4) iron and manganese hydroxide associated fraction, (F5) organic matter and secondary sulphide associated fraction, (F6) primary sulphide bound fraction, and (F7) residual or silicate fraction. The results obtained from the seven steps sequential extraction scheme were validated by the determination vi of percentage recoveries from pseudo-total digestion or total metal content of the original sample. The distribution of major elements and potentially toxic or heavy metal species in different leachate fractions obtained after each step of sequential extraction of the selected tailings samples was determined by inductively coupled plasma mass spectrometry (ICP-MS). The appraised data was used to reveal the impact of atmospheric oxygen and infiltrating rain-water on the chemistry of copper tailings dump by depth profiles. Macroscopic properties revealed that the abandoned Musina copper tailings are fine to medium coarse grained, and range in color from light/dark gray at the upper or shallow depth of the tailings, to dark reddish-brown at the deeper zone where the tailings are mixed with the underlying soil or soil-interface. The drilled respective tailings profiles were uniform and slightly varied in both mineralogical and bulk chemical compositions with tailings depth. Mineralogical analysis showed the following order of mineralogical composition within the respective tailings profiles: quartz> epidote> chlorite> muscovite> calcite> hematite. Chalcopyrite was the only sulphide mineral observed by optical microscopy, although not identified or quantified by XRD and SEM-EDS analysis. The observed discrete chalcopyrite grains were attributed to the primary mined ore (i.e., chalcopyrite, chalcocite and bornite) during past copper mining activities in Musina. The tailings profiles were characterized by a medium alkaline pH (7.97-8.37) that corresponds very well with the tailings leachates or pore-water pH (8.36-8.46). This pH was constant and slightly varied with tailings depth in the respective tailings profiles. The high abundance of alumino-silicate minerals and traces of carbonates as calcite coupled with low sulphide mineral content, suggested a high neutralization capacity of the tailings which was in common agreement with an alkaline nature of the copper tailings dump. The chemical composition of major elements within the respective tailings profiles followed the order: Si>Al>Fe>Ca>Mg>K>Na, and corresponds very well with the mineralogical composition of the tailings, whereby alumino-silicates were the most abundant minerals in the tailings samples. Nevertheless, the solid-phase concentration of metals decreases with increasing tailings depth as Cu>Sr>Zr>Ni>Zn and was incongruent with the mineralogical composition within the respective tailings profiles. The main secondary minerals were calcite and hematite, and their proportion increased with increasing tailings vii depth. In addition, hematite formed coatings on the rims and corners of chlorite as observed from optical microscopy, and retained relatively high amounts of potentially toxic or heavy metals (up to 862 ppm of Cu, up to 36 ppm of Ni, and up to 25 ppm of Zn) at the upper and shallow depth of the respective tailings profiles, where bulk density was high and low porosity. Based on batch leaching tests, the amounts of potentially toxic or heavy metal species released into solution were low (0.27-0.34 μg/L Pb, 0.54-0.72 μg/L Ni, 0.88-1.80 μg/L Zn, and 20.21-47.9 μg/L Cu) and decreases with increasing tailings depth, indicating that, presently, the tailings have a minor impact on heavy metals load transported to the receiving surface and groundwater systems. The low concentration of potentially toxic or heavy metal species in solution is primarily due to their retention by secondary Fe oxide phases (i.e., hematite) and the prevailing medium alkaline pH condition of the tailings leachate or pore-water. The observations are consistent with MINTEQA2 speciation calculations, which predicted the precipitation of secondary phase cuprite (Cu2O) as the main solubility-controlling mineral phase for Cu, Zn, and Ni. Primary factors influencing aqueous chemistry at the site are neutralization and dissolution reactions as a function of pH, precipitation, and sorption into hydrous oxides (hematite and cuprite). Based on sequential extraction results, the leachable concentration of potentially toxic or heavy metal species in the water-soluble, exchangeable and carbonate fractions of the respective tailings profiles was relatively low, except for Cu and Mn. For instance, the leachable concentration of Cu and Mn reached 10.84 mg/kg and 321.7 mg/kg at the tailings-soil interface (3 m) in tailings profile C, respectively. The low concentration of potentially toxic or heavy metal species (Cr, Co, Ni, Zn, Cd, and Pb) in these fractions could be due to the low solubility of minerals bearing these trace elements caused by variations in pore-water pH in the respective tailings profiles. The high concentration of Cu and Mn in these fractions suggests their high mobility and therefore most available for uptake in the environment. Except for Cu>Mn>Cr, the contents of potentially toxic or heavy metal species in the Fe and Mn oxides and organic matter or sulphides bound fractions was low, due to the low viii quantity of these fractions in the tailings, despite their high affinity and sorption capacity for potentially toxic or heavy metal species. Likewise, the residual fraction of the respective tailings profiles contained the highest proportion of potentially toxic or heavy metal species. Although the highest potentially toxic or heavy metal species content was in fractions with limited mobility, care must be taken since any geochemical change or shift in the tailings pH or acidic conditions may cause them to be displaced to more mobile fractions, thereby increasing their mobility and environmental bioavailability. Therefore, physicochemical properties of the tailings including pH and mineralogical composition of the tailings samples were the main substrate controlling the geochemical partitioning and distribution, potential mobility, and environmental bioavailability of potentially toxic or heavy metal species by tailings depth. The knowledge of mobility and eco-toxicological significance of tailings is needed when considering tailings dump disposal or reuse in the environment. The addition of copper tailings at 3 and 28 days successfully improved the compressive strength of cement mortar mixtures incorporating tailings at C5 (5%) and C10 (10%) respectively, although with small margin relative to the control mixture (C0). The maximum strength was 31.15 Mpa attained after 28 curing days, and slightly varied when compared with other compressive strength on copper blended cement mortars mixtures in other countries, used for the development of sustainable construction materials. The chemical composition, physical properties and improved compressive strength on cement mortars mixtures incorporating copper tailings, implies that copper tailings are suitable for the development of sustainable construction materials, thereby ensuring job creation, availability of land for development usage, and the reduction of environmental pollution induced by the abandoned copper tailings dumps.