Absorption heat pump water heaters offer improved performance compared to conventional direct-fired water heaters, with the potential for coefficients of performance well in excess of 1. A primary energy usage comparison with electric heat pumps shows that absorption systems can be competitive with current technology. However, the implementation of these systems in the residential and light commercial market has not been practical for several reasons, including a limited knowledgebase on absorption systems for this application and the lack of compact and economically viable heat and mass exchangers. An improved understanding of the coupled heat and mass transfer processes in thermally driven absorption systems to be used as heat pump water heaters was obtained over the course of this study. In addition, microchannel heat and mass exchangers that enable such compact gas-fired heat pump water heaters were developed and tested. Performance at design and off-design conditions over a range of water and ambient temperatures was simulated in detail with a system-level model developed for this purpose. The system-level model was coupled with a water-tank model to investigate several water heating scenarios including a cold start, response to a medium sized draw and response to stand-by losses. Heat and mass exchangers were designed using component-level heat and mass transfer models. The heat and mass exchangers were first installed and evaluated on a breadboard test facility. Insights from these experiments were then used to design and fabricate a monolithic unit integrating several of the microchannel heat and mass exchangers, coupled with a gas-fired desorber heat exchanger to yield a stand-alone water heater prototype. The performance of the prototype was investigated over a range of water and ambient temperatures. A comparison of results was performed to investigate the deviation between model predictions and experimental values. A refined model was developed that more accurately predicted experimental results. Energy-use and cost analyses were performed and showed the potentially significant energy savings of thermally driven heat pump water heaters.

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