Presently in ground vehicle industries, conducting durability tests with a high acceleration factor have become increasingly demanding for the less time and cost involvement. In the previous work, to accelerate the field test, the standard ‘test tailoring’ approach has been modified due to the requirement of high acceleration factors and the limitations of testing implementation. In this study, a computer-aided testing method is developed for the validation of this modified approach. Hence, a new test-piece has been designed by a conjugative approach involving the finite element technique and fatigue analysis. Afterwards, the accelerated durability loading profiles synthesized via the modified approach have been applied on the designed test-piece and the fatigue life has been simulated to verify the effectiveness of those loading profiles. Simulation results show that loading profiles with an acceleration factor up to 330 can be successfully generated with an accuracy of 95% by this modified approach.

Presently in ground vehicle industries, conducting durability tests with a high acceleration factor have become increasingly demanding for the less time and cost involvement. In the previous work, to accelerate the field test, the standard ‘test tailoring’ approach has been modified due to the requirement of high acceleration factors and the limitations of testing implementation. In this study, a computer-aided testing method is developed for the validation of this modified approach. Hence, a new test-piece has been designed by a conjugative approach involving the finite element technique and fatigue analysis. Afterwards, the accelerated durability loading profiles synthesized via the modified approach have been applied on the designed test-piece and the fatigue life has been simulated to verify the effectiveness of those loading profiles. Simulation results show that loading profiles with an acceleration factor up to 330 can be successfully generated with an accuracy of 95% by this modified approach.

Accelerated durability testing of automotive components has become a major interest as it may predict the life characteristics of the vehicle by testing fatigue failure at higher stress level within a shorter period of time. In this work, a specially designed sub-scaled experimental testing bed with the rigid and elastic supports of a simply supported beam was designed and built to compare the effects of the elastic foundation on the change of modal parameters of the tested structure which was later used to tune the FE model. Afterwards, the accelerated loading profiles of both sine sweep and random vibration were applied on the FE model to compare the deviation of the cumulative fatigue damage between the elastic and rigid supports. This work reveals a significant amount of inaccuracy in the current laboratory testing system where the dynamic properties of the tested structure are not maintained close to the real situation. / October 2016

Indiana University-Purdue University Indianapolis (IUPUI) / The innovation and investigation of catalysts in proton exchange membrane fuel cells are included in this thesis. In the first part of this work, stability of the catalyst support of PEMFC catalyst is investigated. Nanoscale platinum particles were loaded on two different kinds of carbon supports, nano graphene sheets and functionalized carbon black/graphene hybrid were developed by the liquid phase reaction. The crystal structure of two kinds of catalysts was characterized by X-ray diffractometer (XRD). The morphology and particle size were characterized by scanning electron microscope (SEM) and transmission electron microscope (TEM). Pt loading was measured by thermal gravimetric analysis (TGA). The Brunauer, Emmett and Teller (BET) method was applied to test the surface area of the catalysts. The electrochemical surface area (ECSA) and mass activity during oxygen reduction reaction (ORR) process for two kinds of catalyst were tested by cyclic voltammetry method under different conditions. The stability of the catalysts were tested by accelerated durability test (ADT). The results show that although the mass activity of Pt/graphene is much lower, the stability of it is much better than that of the commercial catalyst. After adding functionalized carbon black (FCB) as spacer, the stability of the catalyst is preserved and at the meantime, the mass activity becomes higher than 20% Pt/XC72 catalyst. The lower mass activity of both catalysts are due to the limitation of the electrolyte diffusion into the carbon support because of the aggregation nature of graphene nano-sheets. After introducing functional carbon black as spacer, the mass activity and ECSA increased dramatically which proved that FCB can be applied to prevent the restacking of graphene and hence solved the diffusion problem. In the meantime, the durability was still keeping the same as Pt/graphene catalyst. In the second part of the work, the restacking problem was solved by introducing FCB as spacers between functionalized graphene nanosheets. The same measurement was applied to test the electrochemical performance of Pt/FCB/FG catalyst. The new catalyst showed a higher mass activity compared to Pt/graphene catalyst which meant the restacking problem was partially solved. The durability of the Pt/FCB/FG catalyst was still excellent.