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This doctoral dissertation deals with the study of the effect of additives on the properties of the negative electrode of a lead-acid battery. The work focuses on the investigation of the additive/base material interface for the negative electrode (so-called active mass) using atomic force microscopy (AFM). A lead sheet was used as the base material, on which the given additive was applied. The effects of carbon, TiO2, glass fibers and Indulin AT were specifically investigated. The negative electrode was cycled by a potentiostat in a defined manner and the morphology of the electrode surface was continuously scanned by AFM. This created a time sequence of images on which events on the surface of the electrode during its charging/discharging were captured. These records serve to better understand the effect of additives on the resulting properties of constructed lead-acid cells, specifically on the ability to form or dissolve PbSO4 crystals, which are formed during cell discharge and are responsible for the decrease in total capacity - gradual surface sulfation.

The lead-acid batteries used in hybrid electronic vehicles HEV operate in high-rate mode in a state of partial charge PSoC. It occurs when the degradation mechanisms related to irreversible sulphation and negative electrodes are a limiting factor in the life of lead-acid batteries. The electrode system was applied to experimental pressure cells of different sizes. Exp. cells were subjected to measurement and evaluation of potential negative electrode, a negative active mass resistance, contact resistance of transition collector - the active mass with the evaluation and measurement of pressure fluctuations within four PSoC runs.

<p>Nowadays, office buildings often have large temperature variations during the day and building envelope acts as an energy storing mass and damp these effects and so Offices need more cooling because of internal heat sources. But we know that cooling is more expensive than heating and it uses the very good quality of energy sources (exergy). Controlled Active Mass (CAM) is new approach to absorb radiant heating and acts as a passive cooling device. It has direct cooling effect and reduces the peak load. CAM is a new cooling system design with applying the low energy sources and operates at water temperature close to room temperature and increase the efficiency of heat pumps and other systems.</p><p>In this project, we calculated the transient heat transfer analysis for CAM in a very well insulated test room with façade wall, Internal heat generators (such as Manikin, Computer simulator & lighting) and ventilation.</p><p>Then Polished (shiny) CAM constructed from Aluminum sheets with 0.003 m thickness. It is cube shape with 0.6 m length. This size of CAM is according to 2.5 times larger than human body volume and initial water temperature assumed near half of human body temperature. Then in order to more radiation damping (absorption) by CAM, it painted black (also based on color analysis in heat transfer calculation).</p><p>Some velocity and temperature measurement have been carried out on both polished CAM and black CAM, after visualization by smoke and Infrared Camera. And more cases tested to see the effect of façade wall, IHG’s and ventilation inlet temperature. Thermal comfort measurement also have been done for finding PMV, PPD and temperature equivalent for a seated person which is doing an office job with normal closing.</p><p>At the end results discussed which includes the effect of CAM in room, differences between polished CAM and black CAM and effect of main heat sources on both CAM types (Polished / Black).</p>

Nowadays, office buildings often have large temperature variations during the day and building envelope acts as an energy storing mass and damp these effects and so Offices need more cooling because of internal heat sources. But we know that cooling is more expensive than heating and it uses the very good quality of energy sources (exergy). Controlled Active Mass (CAM) is new approach to absorb radiant heating and acts as a passive cooling device. It has direct cooling effect and reduces the peak load. CAM is a new cooling system design with applying the low energy sources and operates at water temperature close to room temperature and increase the efficiency of heat pumps and other systems. In this project, we calculated the transient heat transfer analysis for CAM in a very well insulated test room with façade wall, Internal heat generators (such as Manikin, Computer simulator &amp; lighting) and ventilation. Then Polished (shiny) CAM constructed from Aluminum sheets with 0.003 m thickness. It is cube shape with 0.6 m length. This size of CAM is according to 2.5 times larger than human body volume and initial water temperature assumed near half of human body temperature. Then in order to more radiation damping (absorption) by CAM, it painted black (also based on color analysis in heat transfer calculation). Some velocity and temperature measurement have been carried out on both polished CAM and black CAM, after visualization by smoke and Infrared Camera. And more cases tested to see the effect of façade wall, IHG’s and ventilation inlet temperature. Thermal comfort measurement also have been done for finding PMV, PPD and temperature equivalent for a seated person which is doing an office job with normal closing. At the end results discussed which includes the effect of CAM in room, differences between polished CAM and black CAM and effect of main heat sources on both CAM types (Polished / Black).

Orientador: Vicente Lopes Júnior / Banca: Nobuo Oki / Banca: José Manoel Balthazar / Resumo: Este trabalho tem como propósito projetar controladores para aplicação em tempo real em uma estrutura flexível, objetivando a redução de vibração estrutural. Os controladores são projetados segundo o enfoque de otimização convexa, com formulações envolvendo desigualdades matriciais lineares (LMIs). Duas diferentes sínteses de realimentação são consideradas. A primeira é o projeto de controladores por realimentação de estados, estimados por um observador. A segunda metodologia é baseada no controle H∞ via realimentação do sinal de saída. O modelo matemático da estrutura, usado no projeto dos controladores, foi obtido utilizando o método de Lagrange. A estrutura considerada representa um modelo de um edifício flexível controlado por uma massa móvel (Active Mass Damper -AMD) localizada no topo. A estrutura é submetida a dois tipos de excitações, sísmica e senoidal. Uma mesa de vibração (Shake Table) foi usada para aplicar as excitações. Para rodar o experimento de controle foi usado uma placa de aquisição (MultiQ - PCI) e o software de controle Wincon. Os controladores foram desenvolvidos usando o Simulink e executado em tempo real usando o Wincon. Testes experimentais foram realizados para comprovação e avaliação das metodologias propostas. / Abstract: The proposal of this work is to design real time controllers for application in flexible structure, aiming the structural vibration reduction. The controllers are designed by convex optimization involving linear matrix inequalities (LMIs) approaches. Two different methodologies to feedback the system are explained. The first one is the design controller by state feedback based on observer. The second one is based on H∞ output feedback control. The mathematical model of the structure, used in the controller design, was obtained by Lagrange's method. The structure can represent a flexible building, and it is controlled by a driving mass located at the top. The structure is submitted to seismic and sinusoidal excitations. A vibration table (Shake Table) was used to apply the excitations. The experimental tests were realized using an acquisition board (MultiQ - PCI) and the Wincon control software. The controllers were developed using Simulink, and it run in real time using the Wincon software. Experimental tests were accomplished to validate and evaluate the proposal methodologies. / Mestre

The lead-acid bateries for hybrid-electric vehicle (HEV) working under high-rate partial-state-of-charge (HRPSoC) conditions. The negative plates of lead-acid batteries have low charge acceptance. The cycle life of the batteries is dependent on the rate accumulation of PbSO4 on the negative plates. Addition of some carbon or graphite forms to the negative paste mix improves the charge efficieny and slows down sulfation of the negative plates. The master’s thesis wants to explain the contribution of electrochemically active carbon (EAC) additives to the mechanis of the electrochemical reaction of charge of the negative plates.

Thesis (MScEng (Mechanical and Mechatronic Engineering))--University of Stellenbosch, 2010. / ENGLISH ABSTRACT: The thesis was initiated by a Consulting Engineering Company (KV3) as a research project to investigate various options in which the efficiency and energy utilisation of conventional air conditioning systems may be enhanced by using alternative and renewable energy. Initially, eight options had been identified and through a process of determining the degree of commercialisation the alternative options were reduced to three. These options, referred to as the sustainable cooling alternatives, are active mass cooling, night flushing and roof cooling system. The roof cooling system comprised a roof-pond, roof-spray, pump and storage tank. The roof cooling system was mathematically and experimentally modelled. The roof cooling experiment was performed under a variety of weather conditions with the roof-pond and storage tank temperatures continuously recorded. The experimentally recorded temperatures were compared to the temperatures generated by the theoretical simulation calculations for the same input and weather conditions. Good agreement was found between the mathematical and experimental model. The largest discrepancy found between the simulated temperature and the experimental temperature was in the order of 1 ºC. A one-room building has been assumed to serve as a basis to which the sustainable cooling alternatives could be applied to for theoretical simulation. The one-room building had four façade walls and a flat roof slab. Night flushing, active mass cooling and the roof cooling system were applied to the one-room building such that the room air temperature and space cooling load could theoretically be simulated. The theoretical simulations were also repeated for the case where the roof-pond and roof-spray were applied as standalone systems to the one-room building. The theoretical simulation calculations were performed for typical summer weather conditions of Stellenbosch, South Africa. Under base case conditions and for a room thermostat setting of 22 ºC the peak cooling load of the one-room building was 74.73 W/m². With the application of night flushing between the hours of 24:00 and 07:00, the room cooling load was reduced by 5.2% by providing 3.9 W/m² of cooling and reducing the peak room temperature by 1.4 ºC. The active mass cooling system was modelled by supplying water at a constant supply temperature of 15 ºC to a pipe network embedded in the roof slab of the one-room building. The sea may typically be considered as a cold water source for buildings situated at the coast. The active mass cooling system reduced the peak cooling load of the one-room building by 50% by providing 37.2 W/m² of cooling and reducing the peak room temperature by 6.7 ºC. When the roof-spray and roof-pond systems were applied as standalone systems to the oneroom building, the peak cooling load of the one-room building could be reduced by 30% and 51% respectively. This is equivalent to 22.3 W/m² of peak cooling by the roof-spray and 38 W/m² of peak cooling by the roof-pond. The roof-spray reduced the peak room temperature by 3.71 ºC while the roof-pond reduced the peak room temperature by 5.9 ºC. Applying the roof cooling system to the one-room building produced 46 W/m² of peak cooling which resulted in a 61.1% reduction in peak cooling load. The roof cooling system reduced the peak temperature by 8 ºC. By comparing the sustainable cooling alternatives, the roof cooling system showed to be the most effective in reducing the one-room building peak cooling load. Over a 24 hour period the roof cooling system reduced the net heat entry to the one-room building by 57.3%. In a further attempt to reduce the peak cooling load, the sustainable cooling alternatives were applied in combinations to the one-room building. The combination of night flushing and roof-spray reduced the peak cooling load by 36% while a combination of night flushing and active mass cooling reduced the peak cooling load by 55%. Combining night flushing with the roof-pond also yielded a 55% peak cooling load reduction. The combination of roofpond, active mass cooling and night flushing provided 51 W/m² of cooling which corresponded to a 68% reduction in peak cooling load. Utilising the sustainable cooling alternatives in a combination in the one-room building gave improved results when compared to the case where the sustainable cooling alternatives were employed as standalone systems. It is illustrated by means of a sensitivity analysis that the ability of the roof cooling system to produce cool water is largely influenced by ambient conditions, droplet diameter and roofspray rate. Under clear sky conditions, an ambient temperature of 15 ºC, relative humidity of 80%, a roof-spray rate of 0.02 kg/sm² and a roof-pond water level of 100mm, water could be cooled at a rate of 113 W/m². The roof-spray energy contributed to 28 W/m² whilst the night sky radiation was responsible for 85 W/m² of the water cooling. It must however be noted that the water of the roof cooling system can never be reduced to a temperature that is lower than the ambient dew point temperature. / AFRIKAANSE OPSOMMING: Die tesis is geïnisieer deur ‘n Raadgewende Ingenieurs Maatskappy (KV3) as a navorsingsprojek om verskeie opsies te ondersoek waarmee die effektiwiteit en energie verbruik van konvensionele lugversorgingstelsels verbeter kan word deur middel van alternatiewe en hernubare energie. Agt opsies is oorspronglik geïdentifiseer en deur middel van ‘n proses waarby die graad van kommersialisering van hierdie alternatiewe maniere bepaal is, kon die opsies verminder word tot drie. Hierdie opsies, ook verwys na as die volhoubare verkoelingsalternatiewe, sluit in aktiewe massa verkoeling, dakverkoeling en nagventilasie. Die dakverkoelingstelsel bestaan uit dakwater, ‘n dakspuit, ‘n pomp en ‘n stoortenk. Die dakverkoelingstelsel is wiskundig en eksperimenteel gemodelleer. Die dakverkoelingseksperiment is uitgevoer onder ‘n verskeidenheid van weersomstandighede. Die dakwater asook die stoortenk se water temperatuur is voortdurend aangeteken. Dieselfde weer- en insetkondisies is gebruik vir die simulasie berekening en die temperature van die stoortenk se water en die dakwater is vergelyk met die temperatuurlesings van die eksperimentele werk. Die temperature van die eksperimentele lesings het goed vergelyk met die temperatuur simulasie berekeninge. Die grootste verskil tussen die simulasie en eksperimentele temperatuur was in die orde grootte van 1 ºC. ‘n Een-kamer gebou is aangeneem om as basis te dien waarop die volhoubare verkoelingsalternatiewe aangewend kon word vir teoretiese simulasie. Die een-kamer gebou het uit vier buite mure en ‘n horisontale beton dak bestaan. Nag ventilasie, aktiewe massa verkoeling en die dakverkoelingstelsel is toegepas op die een-kamer gebou en die kamer se verkoelingslas asook die kamer se lugtempertuur is teoreties gesimuleer. Die teoretiese simulasies is ook herhaal vir die geval waar die dakwater and dakspuitstelsel apart aangewend is op die een-kamer gebou. Die teoretiese simulasie berekeninge is uitgevoer vir tipiese somer weersomstandighede vir Stellenbosch, Suid Afrika. Onder basisgeval omstandighede, waar die een-kamer gebou gesimuleer is, sonder enige volhoubare verkoelingsalternatiewe en ‘n termostaat verstelling van 22 ºC, is die piek verkoelingslas bereken as 74.73 W/m². Met die toepassing van nagventilasie tussen die ure 24:00 en 07:00 was die piekverkoelingslas van die kamer verminder met 5.2% deur 3.9 W/m² se verkoeling te verskaf en die piekkamer temperatuur te verminder met 1.4 ºC. Aktiewe massa verkoeling is gesimuleer deur water teen ‘n konstante temperatuur van 15 ºC te verskaf aan ‘n pypnetwerk, geïnstalleer in the beton dak, van die een-kamer gebou. Geboue geleë aan die kus kan tipies seewater oorweeg as ‘n bron van koue water. Aktiewe massa verkoeling het die piekverkoelingslas van die een-kamer gebou verminder met 50% deur 37.2 W/m² se verkoeling te verskaf en die piekkamer temperatuur te verminder met 6.7 ºC. Wanneer die dakspuit- en dakwaterstelsel aangewend is op die een-kamer gebou as enkel staande stelsels, is die piekverkoelingslas verminder met 30% en 51% onderskeidelik. Dit is ekwivalent aan 22.3 W/m² se verkoeling vir die dakspuitstelsel en 38 W/m² se verkoeling vir die dakwaterstelsel. Die dakspuitstelsel het die piekkamer temperatuur verminder met 3.71 ºC terwyl die dakwaterstelsel ‘n 5.9 ºC verlaging in piekkamer temperatuur tot gevolg gehad het. Die dakverkoelingstelsel het 46 W/m² se piekverkoeling verskaf wat ‘n 61.1% vermindering in piekverkoelingslas tot gevolg gehad het. Die ooreenstemmende piek temperatuur vermindering is 8 ºC. Deur die verskeie volhoubare verkoelingsalternatiewe met mekaar te vergelyk, word getoon dat die dakverkoelingstelsel die mees effektiefste manier is om die een- kamer se piekverkoelingslas te verminder. Oor ‘n tydperk van 24 uur het die dakverkoelingstelsel die totale energievloei na die een-kamer gebou met 57.3% verminder. In ‘n verdere poging om die piekverkoelingslas te verminder, is die volhoubare verkoelingsalternatiewe toegepas in kombinasies op die een-kamer gebou. Die kombinasie van nagventilasie met die dakspuitstelsel het die piekverkoelingslas met 36% verminder, terwyl ‘n kombinasie van nagventilasie en aktiewe massa verkoeling ‘n 55% vermindering in piekverkoelingslas tot gevolg gehad het. Die kombinasie van dakwater en nagventilasie het ook ‘n piekverkoelingslas vermindering van 55% teweeggebring. Die kombinasie van dakwater, aktiewe massa verkoeling en nagventilasie het 51 W/m² se verkoeling veskaf, wat ooreenstem met ‘n 68% vermindering in piekverkoelingslas. Deur die volhoubare verkoelingsalternatiewe in kombinasies toe te pas op die een-kamer gebou, kon beter resultate verkry word toe dit vergelyk is met die geval waar die volhoubare verkoelingsalternatiewe as enkelstaande stelsels toegepas is. Dit is geïllustreer deur middel van ‘n sensitiwiteitsanalise dat die vermoë van die dakverkoelingstelsel om koue water te produseer, beïnvloed word deur buitelug kondisies, waterdruppel deursnee en dakspuit massa vloeitempo. Onder die oop hemelruimteomstandighede, ‘n buitelug temperatuur van 15 ºC, ‘n relatiewe humiditeit van 80%, ‘n dakspuit massa vloeitempo van 0.02 kg/sm² en dakwatervlak van 100 mm, kon water verkoel word teen ‘n tempo van 113 W/m². Die dakspuit gedeelte het 28 W/m² bygedra terwyl die nagruim radiasie sowat 85 W/m² se verkoeling verskaf het. Daar moet egter kennis geneem word dat die water temperatuur van die dakverkoelingstelsel nooit verminder kan word tot onder die buitelug doupunttemperatuur nie.

Made available in DSpace on 2014-06-11T19:27:14Z (GMT). No. of bitstreams: 0 Previous issue date: 2008-02-21Bitstream added on 2014-06-13T20:55:56Z : No. of bitstreams: 1 santos_rb_me_ilha.pdf: 887891 bytes, checksum: 9cff877681cee249ea6c3466ef38a6ed (MD5) / Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP) / Este trabalho tem como propósito projetar controladores para aplicação em tempo real em uma estrutura flexível, objetivando a redução de vibração estrutural. Os controladores são projetados segundo o enfoque de otimização convexa, com formulações envolvendo desigualdades matriciais lineares (LMIs). Duas diferentes sínteses de realimentação são consideradas. A primeira é o projeto de controladores por realimentação de estados, estimados por um observador. A segunda metodologia é baseada no controle H∞ via realimentação do sinal de saída. O modelo matemático da estrutura, usado no projeto dos controladores, foi obtido utilizando o método de Lagrange. A estrutura considerada representa um modelo de um edifício flexível controlado por uma massa móvel (Active Mass Damper -AMD) localizada no topo. A estrutura é submetida a dois tipos de excitações, sísmica e senoidal. Uma mesa de vibração (Shake Table) foi usada para aplicar as excitações. Para rodar o experimento de controle foi usado uma placa de aquisição (MultiQ - PCI) e o software de controle Wincon. Os controladores foram desenvolvidos usando o Simulink e executado em tempo real usando o Wincon. Testes experimentais foram realizados para comprovação e avaliação das metodologias propostas. / The proposal of this work is to design real time controllers for application in flexible structure, aiming the structural vibration reduction. The controllers are designed by convex optimization involving linear matrix inequalities (LMIs) approaches. Two different methodologies to feedback the system are explained. The first one is the design controller by state feedback based on observer. The second one is based on H∞ output feedback control. The mathematical model of the structure, used in the controller design, was obtained by Lagrange’s method. The structure can represent a flexible building, and it is controlled by a driving mass located at the top. The structure is submitted to seismic and sinusoidal excitations. A vibration table (Shake Table) was used to apply the excitations. The experimental tests were realized using an acquisition board (MultiQ - PCI) and the Wincon control software. The controllers were developed using Simulink, and it run in real time using the Wincon software. Experimental tests were accomplished to validate and evaluate the proposal methodologies.

Lead-acid batteries are most used secondary electrochemical power sources. Their basic principle has remained the same for several years; only the operating parameters are in development. Lead-acid batteries are used in hybrid electric vehicles (HEV), which operates in the partial charge PSoC. Sulphation is one of the possible failures lead-acid batteries in the HEV, especially the negative electrode. By adding additives to the negative active mass can reduce the rate of sulphation and increase ability to accept an electrical charge by negative electrode.